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Effect of Cellulose Suspension Agent Structure on the Particle Morphology of PVC. Part II. Interfacial Properties

John Cheng、Michael Langsam1984-04-01Journal of Macromolecular Science Part A - Chemistry

The particle structure of polyvinyl chloride is controlled by the shear field imposed on the monomer droplet and the interfacial behavior of the vinyl chloride/water phases during polymerization. The inter facial tension in the presence of hydroxypropyl methylcellulose (HPMC) was measured as a function of concentratio…

Advanced Polymer Synthesis and CharacterizationAdvanced Cellulose Research StudiesPolymer Science and PVC

Transformation of quercetin by singlet oxygen generated by a photosensitized reaction

Umeo Takahama、Richard J. Youngman、Erich F. Elstner1984-04-01Photobiochemistry and photobiophysics.

Quercetin suppressed singlet molecular oxygen-dependent photobleaching of crocin in the presence of rose bengal as a photosensitizer. The suppression by quercetin concurred the transformation of quercetin to a compound which had an absorption maximum at about 330 nm. The rate of the transformation was slowed down by a…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesOxidative Organic Chemistry Reactions

Photoelectrochemistry of Lamellar n‐ and p‐Type InSe in Aqueous Solution

Claude Lévy‐Clément、N. Le Nagard、O. Gorochov 等 4 位作者1984-04-01Journal of The Electrochemical Society

n‐ and p‐type single crystals have been grown by the Bridgman‐Stockbarger method and characterized by their electronic transport properties. A photoelectrochemical study in aqueous media using the cleavage surface shows rectifying behavior in the dark, confirming diode behavior for both. electrodes exhibit anodic and…

Chalcogenide Semiconductor Thin FilmsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Some effects of ionizing radiation on tetrafluoroethylene copolymers

Ronald E. Uschold1984-04-01Journal of Applied Polymer Science

The effect of high energy electron radiation on TFE copolymers of perfluoro(methyl vinyl ether) (PMVE) and perfluoro-3,6-dioxa-4-methyl-7-octene sulfonyl fluoride (PSEPVE) was studied. The PMVE copolymers were found to crosslink when irradiated as either a gum or as a compounded elastomer. Attempts to graft vinyl mono…

Fiber-reinforced polymer compositesPolymer Nanocomposite Synthesis and IrradiationSilicone and Siloxane Chemistry

Nonisothermal Crystallization of Poly(tetrafluoroethylene)

Takeo Ozawa1984-04-01Bulletin of the Chemical Society of Japan

Abstract Crystallization of poly(tetrafluoroethylene) was observed by differential scanning calorimetry at constant cooling rates. A method for kinetic analysis of thermoanalytical data of nonisothermal crystallization was applied to analyze the data, and it was elucidated that poly(tetrafluoroethylene) crystallizes o…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Duality in Major Ampullate Silk and Precursive Material from Orb-Web-Building Spiders (Araneae)

Robert W. Work1984-04-01Transactions of the American Microscopical Society

Robert W. Work, Duality in Major Ampullate Silk and Precursive Material from Orb-Web-Building Spiders (Araneae), Transactions of the American Microscopical Society, Vol. 103, No. 2 (Apr., 1984), pp. 113-121

Silk-based biomaterials and applicationsMetal Alloys Wear and PropertiesLaser and Thermal Forming Techniques

Atmospheric Corrosion of Steel in a Humid Tropical Climate—Influence of Pollution, Humidity, Temperature, Solar Radiation and Rainfall

Francisco Corvo Pérez1984-04-01CORROSION

Soviet carbon steel CT-3 plates were exposed in five different places in Havana and the city of Havana (rural, industrial-marine and marine stations). Weight loss was evaluated in periods of six and twelve months at different starting times. Salinity and SO2 concentration in the atmosphere were determined. Relative hu…

Corrosion Behavior and InhibitionConcrete Corrosion and Durability

Aluminate sodalite Sr8[Al12O24](CrO4)2-a new ferroelectric material

N. Setter、M.E. Mendoza、Wulf Depmeier 等 4 位作者1984-04-01Ferroelectrics

On flux grown polydomain single crystals of Sr8[Al12O24] (CrO4)2 exploratory domain studies and measurements of birefringence, polarization, dielectric constant and transition enthalpy demonstrate the existence of a first order ferroelectric phase transition at about 2954↓-299↑K.

Glass properties and applicationsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

UPS investigation of poorly crystallized MoS2

K. S. Liang、G. Hughes、R. R. Chianelli1984-04-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

We have performed photoemission studies on samples of poorly crystallized MoS2 prepared in situ by thermal decomposition of (NH4)2MoS4 in a UHV-compatible chamber under mixed H2S/H2 gas conditions. The results reveal new electronic states which are not present on crystalline MoS2. These states are observed as a band t…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metals

Marine tube-dwelling diatoms of eastern Canada: descriptions, checklist, and illustrated key

Christopher S. Lobban1984-04-01Canadian Journal of Botany

From a study of living materials and specimens in several regional herbaria, a list has been drawn up of all the common and several of the rarer tube-dwelling diatoms of eastern Canada. Descriptions, illustrations of living material and acid-cleaned valves, and a key to the species are provided. Most specimens were fr…

Diatoms and Algae ResearchAquatic Invertebrate Ecology and BehaviorInvertebrate Taxonomy and Ecology

The Crystal Structure and Magnetic Behavior of [Cu2(dien)2CI2](CIO4)2

S. K. Hoffmann、Debra K. Towle、William E. Hatfield 等 6 位作者1984-04-01Molecular crystals and liquid crystals

The compound [Cu2(dien)2Cl2](C1O4)2 crystallizes in the orthorhombic system, space group Pbn21, with unit cell dimensions: a = 7.637(1) A, b = 13.549(3) A, and c = 20.866(4) A, with four molecules in the unit cell (Z = 4). The structure consists of dimeric [Cu2(dien)2C12]2+ units in which the coordination about copper…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesInorganic Chemistry and Materials

HIGH CATALYTIC ACTIVITIES OF SPECIALLY TREATED MgO and Na/MgO FOR DECOMPOSITION OF METHYL FORMATE

Takashi Ushikubo、Hideshi Hattori、Kozo Tanabe1984-04-01Chemistry Letters

Abstract The decomposition of methyl formate to methanol and carbon monoxide was carried out in gaseous phase at 50–300 °C over alkaline earth metal oxides, Na/MgO, Al2O3, SrO/Al2O3, K/active carbon, and 13X-molecular sieves. The MgO catalyst pretreated at 1000 °C exhibited a high activity, the selectivity being 100%.…

Zeolite Catalysis and SynthesisCatalysis and Oxidation ReactionsMagnesium Oxide Properties and Applications

Disclinations Observed During the Shear of MBBA

D. J. Graziano、M. R. Mackley1984-04-01Molecular crystals and liquid crystals

We describe observations made with an optical microscope of the formation of two distinct types of disclinations during the shear of a small molecule nematic, MBBA. Once formed, these disclinations grow and deform in the shear field. We also report observations of the relaxation of these defects after the cessation of…

Liquid Crystal Research AdvancementsForce Microscopy Techniques and ApplicationsAdvanced Materials and Mechanics

Dielectric properties and phase transitions in PbZrO3with oxygen vacancies

Z. Ujma1984-04-01Phase Transitions

The influence of oxygen vacancies in PbZrO3 on the dielectric properties and phase transitions between the antiferroelectric, ferroelectric and paraelectric states has been investigated. Marked changes in dielectric parameters and in phase transition temperatures were found for the deficient samples. With increasing n…

Ferroelectric and Piezoelectric MaterialsSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

A quantitative description for the optical properties of crystalline polymers applied to polyethylene

Alan R. Wedgewood、James C. Seferis1984-04-01Polymer Engineering and Science

Abstract A quantitative model which described the microscopic and macroscopic refractive index properties of uniaxially oriented crystalline polymers has been extended in relation to molecular bond polarizabilities in this work. Application of this extended modeling methodology in analyzing measured refractive index d…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

The dependence of H2O adsorption and reaction on the structure of the carbon substrate

S. R. Kelemen、H. Freund、Charles A. Mims1984-04-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

We have examined the interaction of H2O vapor with three structurally different carbon surfaces. The edge and basal surface of crystalline graphite as well as a ‘‘paracrystalline’’ glassy carbon were characterized with LEED, UPS, and AES. Structural characterization by LEED showed the typical ‘‘ring’’ pattern for the…

Advanced Chemical Physics StudiesGraphene research and applicationsCatalytic Processes in Materials Science

Polarization Studies of Brass-Steel Galvanic Couples

D. A. Jones1984-04-01CORROSION

Electrochemical polarization methods were utilized to study the galvanic corrosion of steel coupled to brass. Polarization of a 70Cu-30Zn brass cathode controlled galvanic corrosion rate (galvanic current) of the steel anode in the couple. The effect of cathode/anode surface area ratio was predicted successfully from…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Characterisation of some magnetic and magnetoelectric properties of ferroelectric Pb(Fe1/2Nb1/2)O3

Barry D. Howes、Marco Pelizzone、Peter Fischer 等 6 位作者1984-04-01Ferroelectrics

The magnetic properties of Pb(Fe1/2Nb1/2)O3 have been studied by neutron diffraction on a polydomain single crystal and susceptibility measurements on a single ferroelectric domain. A Néel temperature of $$ 160K was found but no further anomalies were indicated by the susceptibility data. No evidence of a spontaneous…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsSolid-state spectroscopy and crystallography

Synthesis of oxaloacetate in Bacillus subtilis mutants lacking the 2-ketoglutarate dehydrogenase enzymatic complex

Susan H. Fisher、Boris Magasanik1984-04-01Journal of Bacteriology

Bacillus subtilis mutants deficient in the 2-ketoglutarate dehydrogenase enzymatic complex required aspartate for growth at wild-type rates on carbon sources for which synthesis of the degradative enzymes is sensitive to catabolite repression (e.g., poor carbon sources), but did not require aspartate for growth on car…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismBiochemical and Molecular Research

Photolytic oxidative demethylation of aqueous dimethylsiloxanols

Robert R. Buch、T. H. Lane、Ronald B. Annelin 等 4 位作者1984-04-01Environmental Toxicology and Chemistry

Abstract Dimethylsilanediol and other water-soluble dimethysiloxanols undergo aqueous photolytic oxidative demethylation with tropospheric ultraviolet radiation in the presence of suitable chromophores, such as nitrogen oxides, to give silicic acid and carbon dioxide. The “biosuitability” of the resulting silicic acid…

Analytical Chemistry and SensorsDiatoms and Algae ResearchMarine Biology and Environmental Chemistry