Materials Literature
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Time-resolved photoluminescence spectra after nonresonant excitation show a distinct 1s resonance, independent of the existence of bound excitons. A microscopic analysis identifies exciton and electron-hole plasma contributions. For low temperatures and low densities, the excitonic emission is extremely sensitive to d…
La(Fe x Si 1−x ) 13 and their hydrides exhibit large magnetocaloric effects due to the itinerant-electron metamagnetic transitions in a wide temperature range covering room temperature. Thermal conductivity and diffusivity of La(Fe0.88Si0.12)13 and La(Fe0.88Si0.12)13H1.0 have been investigated, together with those of…
We have succeeded in growing epitaxial films of rocksalt ${\mathrm{VO}}_{x}$ on MgO(001) substrates. The oxygen content as a function of oxygen flux was determined using ${}^{18}{\mathrm{O}}_{2}$-Rutherford backscattering spectrometry and the vanadium valence using x-ray-absorption spectroscopy. The upper and lower st…
We present one-dimensional KKR method with the aim to elucidate its linear features, particularly important in optimizing the numerical algorithms in energy bands computations. The conventional KKR equations based on the multiple scattering theory as well as novel forms of the secular matrix with nearly linear energy…
The mechanisms involved in the polarization switching process in soft and hard Pb(Zr53,Ti47)O3 (PZT) bulk ceramics were investigated through the dependency of the hysteresis loop on the frequency. In order to determine the influence of the defects on the domain switching dynamics, the samples were characterized in the…
Magnetostrictive and piezoelectric laminate composites of terfenol-D and Pb(Zr1−xTix)O3 have been studied. The magnetoelectric (ME) coefficients have been characterized for the different operational modes: (i) a longitudinally magnetized and transversely polarized longitudinal transverse (LT) mode, and (ii) a transver…
We investigate the high temperature decagonal quasicrystalline phase of Al$_{72}$Ni$_{20}$Co$_8$ using a quasilattice gas Monte-Carlo simulation. To avoid biasing towards a specific model we use an over-dense site list with a large fraction of free sites, permitting the simulation to explore an extended region of perp…
Recent experiments discovered an order-disorder transition occuring at low temperatures in large unit 1/1 cell cubic approximants of the stable Cd-based binary alloy quasicrystals. The transition is related to correlations among orientational degrees of freedom whose separations are around 12 Å. We analyze the interac…
We identify several new quasicrystal approximants in alloy systems in which quasicrystals have not been previously reported. Some occur in alloys with large size contrast between the constituent elements, either containing small Boron atoms, or large Ca/Eu atoms, leading to quasicrystal structures quite different from…
Structural and magnetic properties have been studied for polycrystalline Zn1−xTMxO, where TM (transition metal ions)=Mn, Fe, and Co. No bulk ferromagnetism was observed for single-phase materials, contrary to the existing theories. Single-phase samples demonstrate paramagnetic Curie–Weiss behavior with antiferromagnet…
Catalytic palladium (Pd) nanoparticles on electrospun copolymers of acrylonitrile and acrylic acid (PAN-AA) mats were produced via reduction of PdCl 2 with hydrazine. Fiber mats were electrospun from homogeneous solutions of PAN-AA and PdCl 2 in dimethylformamide (DMF). Pd cations were reduced to Pd metals when fiber…
Depolymerization of poly(butylene terephthalate) (PBT) waste sample was undertaken with aqueous as well as alcoholic (methanolic and ethanolic) solutions of potassium hydroxide at various temperatures (35–98°C) for various time periods (0.5–60 min) at atmospheric pressure in a batch operation. Methanolic alkaline solu…
Laboratory scale tests were developed to study the high consumption of water in a tannery in Toluca City, Mexico, needed to decrease the biological oxygen demand (BOD) in the wastewater. Biological oxygen demand is generally reduced by reducing the organic material with sodium hypochlorite. However, Cr(VI) is formed i…
We describe lithography-free fabrication of sub-micron surface features on quartz substrates by the reactive ion etching (RIE) in a CF4/Ar atmosphere. These submicron glass columns are well defined, have a high aspect ratio, with the underlying substrate being very flat. The geometry of the fabricated surface columns…
High nitrogen contents in solid solution as well as appropriate strengthening mechanisms in austenitic stainless steels can result in very high corrosion resistance. This is true in both air environment and in simulated human body fluids (corrosion fatigue). High cycle corrosion fatigue data are listed and compared wi…
Depolymerization of waste poly (ethylene terephthalate) and poly (butylene terephthalate) were undertaken in various alkaline solutions at different reaction parameters at 1 atm in a batch operation. Results were evaluated in terms of weight loss of both the waste polyesters as well as products obtained during depolym…
Blends of styrene butadiene rubber (SBR) with maleic anhydride grafted whole tire reclaim (MA-g-WTR) have been prepared and the cure and mechanical properties have been studied with respect to the reclaim content. The grafting was carried out in the presence of dicumylperoxide (DCP) in a Brabender Plasticorder at 150°…
Charge redistribution in organic/inorganic heterojunction between poly(3,4-ethylenedioxy thiophene)/poly(styrenesulfonate) polymer (PEDOT/PSS) is observed contact-less by infrared spectroscopic ellipsometry. Hole accumulation or depletion layer formation is detected according to the different work functions of n- and…
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTTemperature Dependence of the Structure and Interaction of Starlike PEG-Based Block Copolymer MicellesCornelia Sommer and Jan Skov PedersenView Author Information Department of Chemistry and iNANO Interdisciplinary Nanoscience Cente…
The electrical assisted laser floating zone (EALFZ) solidification process makes the tailoring of fibre microstructures possible. The application of a dc electrical current of during the solidification process of Bi2Sr2Ca2Cu4O11 nominal composition fibres strongly modified phase development, crystal shapes and effecti…