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Photochromism of 4‘-Methoxyflavylium Perchlorate. A “Write−Lock−Read−Unlock−Erase” Molecular Switching System

Fernando Piña、Maria João Melo、Mauro Maestri 等 5 位作者1997-06-01Journal of the American Chemical Society

In aqueous solution (2 < pH < 8) the thermodynamically stable form of the 4‘-methoxyflavylium ion ( AH + ) is its hydrated derivative trans -4‘-methoxychalcone, C t . The C t compound shows a broad absorption band with λ max = 350 nm. In acid medium, irradiation of C t with near-UV light causes strong spectral changes…

Luminescence and Fluorescent MaterialsPhotoreceptor and optogenetics researchPhotochromic and Fluorescence Chemistry

A Surface Sol−Gel Process of TiO2 and Other Metal Oxide Films with Molecular Precision

Izumi Ichinose、Hiroyuki Senzu、Toyoki Kunitake1997-06-01Chemistry of Materials

Fabrication of metal oxide thin films with thickness control of nanometer precision is an important technology that leads to wide practical applications. The present study demonstrates that a surface sol−gel process, composed of chemisorption of alkoxide, rinsing, hydrolysis, and drying, is a superior technique for th…

Electronic and Structural Properties of OxidesSemiconductor materials and devicesGas Sensing Nanomaterials and Sensors

Asymptotic laws and preasymptotic correction formulas for the relaxation near glass-transition singularities

Thomas Franosch、Matthias Fuchs、W. Götze 等 5 位作者1997-06-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Within the mode-coupling theory (MCT) for the dynamics of simple liquids, the leading corrections to the asymptotic solutions for the relaxation in the vicinity of an ideal glass transition are derived. The formulas are used to determine the range of validity of the scaling-law description of the MCT results for the \…

Theoretical and Computational PhysicsMaterial Dynamics and Properties

Capillary Critical Point of Argon, Nitrogen, Oxygen, Ethylene, and Carbon Dioxide in MCM-41

Kunimitsu Morishige、Hiroyuki Fujii、M. Uga 等 4 位作者1997-06-01Langmuir

The effect of temperature on adsorption isotherms of Ar, N 2, O 2, C 2 H 4, and CO 2 on mesoporous MCM-41 molecular sieves with different pore sizes (pore radius r p = 1.2, 1.4, 1.8, 2.1 nm) has been measured. The occurrence of adsorption hysteresis upon capillary condensation of these molecules in mesopores depends o…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPhase Equilibria and Thermodynamics

Preisach modeling of piezoceramic and shape memory alloy hysteresis

Declan Hughes、John T. Wen1997-06-01Smart Materials and Structures

Smart materials such as piezoceramics, magnetostrictive materials, and shape memory alloys exhibit hysteresis, and the larger the input signal the larger the effect. Hysteresis can lead to unwanted harmonics, inaccuracy in open loop control, and instability in closed loop control. The Preisach independent domain hyste…

Magnetic Properties and ApplicationsShape Memory Alloy TransformationsPiezoelectric Actuators and Control

Stability of the Perforated Layer (PL) Phase in Diblock Copolymer Melts

Damian A. Hajduk、Hiroshi Takenouchi、Marc A. Hillmyer 等 6 位作者1997-06-01Macromolecules

We reexamine the stability of hexagonally modulated layer (HML) and hexagonally perforated layer (HPL) morphologies in a number of block copolymer systems of low to moderate molecular weight. Using small-angle X-ray scattering and dynamic mechanical spectroscopy, we show that these structures are long-lived nonequilib…

Advanced Polymer Synthesis and CharacterizationMachine Learning in Materials ScienceBlock Copolymer Self-Assembly

Photosensitized Near Infrared Luminescence of Ytterbium(III) in Proteins and Complexes Occurs via an Internal Redox Process

William DeW. Horrocks、James P. Bolender、Wendy D. Smith 等 4 位作者1997-06-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTPhotosensitized Near Infrared Luminescence of Ytterbium(III) in Proteins and Complexes Occurs via an Internal Redox ProcessWilliam D. Horrocks,, James P. Bolender, Wendy D. Smith, and Ronald M. SupkowskiView Author Information Department of Chemistry The Pennsylvania S…

Luminescence and Fluorescent MaterialsElectron Spin Resonance StudiesLanthanide and Transition Metal Complexes

Creep of MDF panels under constant load and cyclic environmental conditions. Influence of surface coating

J. I. Fernández-Golfín Seco、M. Rafael Díez Barra1997-06-01Materiales de Construccion

Four different strategies of surface coating (based on 80 g m2 melamin impregnated papers) were used on 19 mm thick commercial MDF panels to assess its reological behaviour under cyclic humidity conditions (20ºC 30 % rh-20ºC 90 % rh). Three different levels of stress (20 %, 30 % and 40 %), based on the ultimate load i…

Morteros de albañilería con escombros de demolición

J. L. Álvarez Cabrera、F. Urrutia、D. Lecusay 等 4 位作者1997-06-01Materiales de Construccion

The possibility of recycling construction rubble, its technical and economic effectiveness, and the social and ecological impact they provide for our society is the reason and the starting point for an optimal exploitation of this aggregate in the manufacture of masonry mortar, since it has the same inherent propertie…