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The adsorption of hydrogen on the rutile TiO 2 (110) surface

M. Kunat、U. Burghaus、Christof Wöll2004-01-01Physical Chemistry Chemical Physics

The adsorption of hydrogen on a well defined single crystal rutile TiO2(110) surface has been investigated using helium atom scattering (HAS). Whereas the adsorption probability of molecular hydrogen was below the detection limit (S < 2 × 10−7), the hydrogen adlayers were prepared by exposing the clean surface to atom…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceGas Sensing Nanomaterials and Sensors

Optimization of parameters for the synthesis of nano-sized Co 1−x Zn x Fe 2 O 4 , (0 ≤ x ≤ 0.8) by microwave refluxing

Jyotsnendu Giri、T. Sriharsha、D. Bahadur2004-01-01Journal of Materials Chemistry

An optimization study of different parameters for the synthesis of well dispersed nanoparticles (5–30 nm) of the system Co1−xZnxFe2O4, (0 ≤ x ≤ 0.8) has been carried out using a novel microwave refluxing method. Ethylene glycol has been used as the medium which serves as the solvent as well as a complexing and capping…

Magnetic Properties and Synthesis of FerritesNanomaterials for catalytic reactionsMicrowave-Assisted Synthesis and Applications

Synthesis, structure, and phase relationship in lithium manganese oxide spinelElectronic supplementary information (ESI) available: neutron and X-ray Rietveld refinement results of LiMn2O4. See http://www.rsc.org/suppdata/jm/b3/b314810f/

Masao Yonemura、Atsuo Yamada、H. Kobayashi 等 7 位作者2004-01-01Journal of Materials Chemistry

Phase relationships, structures, magnetic properties, and phase transitions in the lithium manganese oxide spinel were studied based on a wide variety of samples synthesized at temperatures over a range of 750 ≤ t ≤ 900 °C with Li/Mn ratios between 0.5 and 0.55 and various starting materials. The system was divided in…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

Ferromagnetic Co-Ni-Al Shape Memory Alloys with β+γ Two-Phase Structure

Yuuki Tanaka、Toshihiro Ohmori、Katsunari Oikawa 等 5 位作者2004-01-01MATERIALS TRANSACTIONS

The effects of the introduction of the γ (A1) phase into the β (B2) phase on the mechanical and shape memory properties in ferromagnetic Co-Ni-Al shape memory alloys with the β+γ two-phase structure were investigated by cold-rolling, tensile tests, and bending tests. The mechanical properties were found to be improved…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsMagnetic Properties of Alloys

Performance of GDC-Impregnated Ni Anodes of SOFCs

San Ping Jiang、Sam Zhang、Y. D. Zhen 等 4 位作者2004-01-01Electrochemical and Solid-State Letters

Ni electrodes impregnated with nanosized electrocatalytic active (GDC) particles were fabricated and investigated as anodes for oxidation reaction in solid oxide fuel cells (SOFCs). Incorporation of nanosized ionic conducting GDC particles significantly reduced the electrode interface resistance and polarization poten…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Artificial double negative (DNG) media composed by two different dielectric sphere lattices embedded in a dielectric matrix

O. G. Vendik、Marina Gashinova2004-01-01European Microwave Conference

The periodic composite medium consisting of two lattices of different dielectric spherical particles bas been investigated analytically and numerically. It is shown that effective isotropic double negative media (DNG) can be realized in the frequency region where resonance of TM mode in one kind of particles and TE mo…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Langmuir–Blodgett and layer-by-layer films of photoactive fullerene–porphyrin dyads

Dirk M. Guldi、Israel Zilbermann、Gregory Anderson 等 7 位作者2004-01-01Journal of Materials Chemistry

The fabrication of high quality, robust and photoactive ITO electrodes—in the form of well-defined two- and three-dimensional films—is reported following the Langmuir–Schäfer (LS) and the layer-by-layer (LBL) methods. In the LS approach C60-NiP multilayers were transferred from the air–water interface, while the LBL a…

Graphene research and applicationsPorphyrin and Phthalocyanine ChemistryFullerene Chemistry and Applications

A simple low-temperature growth of ZnO nanowhiskers directly from aqueous solution containing Zn(OH)42? ions

Ping Li、Yu Wei、Hui Liu 等 4 位作者2004-01-01Chemical Communications

One-dimensional (1D) needle-like ZnO nanowhiskers have been grown directly from aqueous solution containing Zn(OH)(4)(2-) ions produced by zinc chloride and sodium hydroxide, in the presence of sodium dodecyl sulfate (SDS).

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Preparation of indium nitride micro- and nanostructures by ammonolysis of indium oxide

Birgit Schwenzer、Lars Loeffler、Ram Seshadri 等 7 位作者2004-01-01Journal of Materials Chemistry

Indium nitride micro- and nanostructures have been prepared by the reaction of indium oxide and ammonia in the temperature range 600–730 °C. Depending on the reaction temperature, nanoparticles with a diameter of 50–100 nm, nanowires with a diameter of ∼100 nm and of varying length, hollow microtubes or two-dimensiona…

ZnO doping and propertiesGaN-based semiconductor devices and materialsNanowire Synthesis and Applications

Water Vapor Transfer and Condensation Effects in Multilayer Textile Combinations

René M. Rossi、R. Gross、H. S. May2004-01-01Textile Research Journal

In cold environments, the moisture produced by the human body will partly condense within the layers of an ensemble. Water vapor transfer and moisture accumulation in the layers of different four-layer combinations are analyzed at several moderately cold temperatures with a sweating arm, which simulates the thermophys…

Mechanical Behavior of CompositesThermoregulation and physiological responsesTextile materials and evaluations

Brittle‐Ductile Transition and Toughening Mechanism in POM/TPU/CaCO3 Ternary Composites

Xiaoling Gao、Cheng Qu、Qin Zhang 等 5 位作者2004-01-01Macromolecular Materials and Engineering

Abstract Summary: Polyoxymethylene (POM)/elastomer/filler ternary composites were prepared, in which thermoplastic polyurethane(TPU) and an inorganic filler, CaCO 3 , were used to achieve balanced mechanical properties of POM. A two‐step processing method, in which the elastomer and the filler were mixed to a masterba…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Synthesis and optical properties of PbSe and CdSe colloidal quantum dots capped with oleic acid

Roman B. Vasiliev、Sergey G. Dorofeev、Dmitry N. Dirin 等 5 位作者2004-01-01Mendeleev Communications

PbSe and CdSe nanocrystals capped with oleic acid have been synthesised starting from metal oleates and investigated by X-ray diffraction, transmission electron microscopy and optical spectroscopy.

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Formation of dimers of inclusion cryptand/paraquat complexes driven by dipole–dipole and face-to-face π-stacking interactions

Feihe Huang、Liang Zhou、Jason W. Jones 等 5 位作者2004-01-01Chemical Communications

Dimers of inclusion complexes were formed from a new cryptand and viologens (paraquats) driven by dipole-dipole and face-to-face pi-stacking interactions as shown by mass spectrometric characterization and X-ray analysis.

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsLanthanide and Transition Metal Complexes

Combinatorial Investigations of the Si-Al-Mn System for Li-Ion Battery Applications

Michael D. Fleischauer、J. R. Dahn2004-01-01Journal of The Electrochemical Society

Combinatorial sputtering methods were used to produce thin films of amorphous Si-Al-Mn whose composition varied in a linear and orthogonal manner. Electrochemical investigations were performed on over 200 compositions of Si-Al-Mn with either standard coin-type test cell hardware or a 64-channel combinatorial electroch…

Metallic Glasses and Amorphous AlloysSemiconductor materials and interfacesQuasicrystal Structures and Properties

Sandwich Fe2O3@SiO2@PPy ellipsoidal spheres and four types of hollow capsules by hematite olivary particles

Lingyun Hao、Chunling Zhu、Wanquan Jiang 等 6 位作者2004-01-01Journal of Materials Chemistry

Hematite@silica@polypyrrole (Fe2O3@SiO2@PPy) ellipsoidal sandwich composite spheres as well as SiO2, SiO2/PPy, PPy hollow capsules and PPy ellipsoidal hollow capsules with movable hematite cores were successfully fabricated by hematite (α-Fe2O3) olivary particles. Monodispersed α-Fe2O3 olivary particles were firstly p…

Pickering emulsions and particle stabilizationLayered Double Hydroxides Synthesis and ApplicationsCovalent Organic Framework Applications

Phase Transformation of &alpha;&Prime; Martensite Structure by Aging in Ti-8 mass%Mo Alloy

Yoshikazu Mantani、Yoshito Takemoto、Moritaka Hida 等 5 位作者2004-01-01MATERIALS TRANSACTIONS

The orthorhombic α″ martensite was formed in Ti-8 mass%Mo alloy by quenching from 1223 K. The purpose of this study was to investigate phase transformation of the α″ martensite structure by isothermal aging. In differential scanning calorimetry curve of the quenched specimen, an exothermic peak that indicated decompos…

Metal and Thin Film MechanicsIntermetallics and Advanced Alloy PropertiesTitanium Alloys Microstructure and Properties

Effect of Morphology on the Response of Polyaniline-based Conductometric Gas Sensors: Nanofibers vs. Thin Films

Guofeng Li、Carlos J. Martinez、Jiřı́ Janata 等 6 位作者2004-01-01Electrochemical and Solid-State Letters

Mixtures of methanol with increasing fractions of formic acid were used to progressively transform the morphology of polyaniline starting from nanofibers to compact conventional films. It was demonstrated that the methanol/formic acid mixture could be used as a viable solvent system for nanostructured polyaniline to a…

Advanced Sensor and Energy Harvesting MaterialsGas Sensing Nanomaterials and SensorsConducting polymers and applications

Ester type banana-shaped liquid crystalline monomers: synthesis and physical properties

Katalin Fodor‐Csorba、Á. Vajda、Antal Jákli 等 9 位作者2004-01-01Journal of Materials Chemistry

New ester-type banana (bent-shaped) monomers, 1,3-phenylene bis[4′-(alken-1-yloxy)-biphenyl-4-carboxylate]s Ia–Vb, with different substituent(s) on the central phenyl ring (H, CH3, Cl or NO2) and alkenyl tails in the side arms (decenyl or undecenyl) were prepared. The analogues IIIa–IVb with 4-chloro- or 4,6-dichloro-…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsPhotochromic and Fluorescence Chemistry

Scanning Kelvin Probe Force Microscopy

D. Bengtsson Blücher、J.-E. Svensson、Lars‐Gunnar Johansson 等 5 位作者2004-01-01Journal of The Electrochemical Society

Scanning Kelvin probe force microscopy (SKPFM) is used to study the initial stages of atmospheric corrosion of an AlMg alloy and of physical vapor deposition (PVD) deposited 2 μm Al dots on pure Mg. The latter system is used as a model of a two-phase AlMg alloy. The influence of was studied in situ in humid air using…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsMagnesium Alloys: Properties and Applications