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A method for the prediction of the crystal structure of ionic organic compounds—the crystal structures of o-toluidinium chloride and bromide and polymorphism of bicifadine hydrochloride

Patrick McArdle、Karen Gilligan、Desmond Cunningham 等 5 位作者2004-01-01CrystEngComm

The crystal structures of o-toluidinium chloride (1), o-toluidinium bromide (2) and two polymorphs of bicifadine hydrochloride (3) have been determined. The polymorphs of 3 differ in their molecular conformation and in their mode of packing. Crystallisation studies and quantum mechanical calculations show that the mor…

Ionic liquids properties and applicationsCrystallography and molecular interactionsCrystallization and Solubility Studies

Quasi-solid-state dye sensitized solar cells with 1,3:2,4-di-O-benzylidene- d -sorbitol derivatives as low molecular weight organic gelators

Nils Mohmeyer、Peng Wang、Hans‐Werner Schmidt 等 5 位作者2004-01-01Journal of Materials Chemistry

1,3:2,4-Di-O-benzylidene-D-sorbitol (DBS) and its derivatives are efficient gelators to solidify organic solvents over a wide range of polarity. In this paper we demonstrate the usefulness of certain DBS derivatives as efficient gelators to form thermoreversible gels in electrolyte solutions which are of particular in…

Supramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

A Study of SOFC Anodes Based on Cu-Ni and Cu-Co Bimetallics in CeO[sub 2]-YSZ

Shung-Ik Lee、John M. Vohs、Raymond J. Gorte2004-01-01Journal of The Electrochemical Society

A series of solid oxide fuel cells (SOFCs) with anodes containing mixtures of either Cu and Ni or Cu and Co, prepared by impregnation of the metal salts into porous yttria-stabilized zirconia (YSZ), were examined for operation with both and n -butane fuels at 973 and 1073 K. The Cu-Ni mixtures formed single-phase allo…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

DEVELOPMENT OF SUSTAINABLE CEMENTITIOUS MATERIALS

Zongjin Li、Zhu Ding、Y Zhang2004-01-01OpenAlex

In this paper, two types of sustainable cementitious composites, geopolymer and magnesium phosphate cement, are introduced. The geopolymer is a type of amorphous alumino-silicate products and magnesium cement is MgO based cementitious material. Geopolymer can be synthesized by polycondensation reaction of geopolymeric…

Concrete and Cement Materials ResearchRecycling and utilization of industrial and municipal waste in materials productionMagnesium Oxide Properties and Applications

Shape Memory Properties of Biomedical Ti-Mo-Ag and Ti-Mo-Sn Alloys

Takashi Maeshima、Minoru Nishida2004-01-01MATERIALS TRANSACTIONS

Shape memory properties of Ti-Mo-Ag and Ti-Mo-Sn alloys consisting of biocompatible elements were investigated. The alloys with appropriate combination of Mo and Ag or Sn showed nearly perfect shape memory effect in convenient bending and heating tests. Recoverable tensile strain is more than 3% in some of Ti-Mo-Ag an…

Bone Tissue Engineering MaterialsShape Memory Alloy TransformationsTitanium Alloys Microstructure and Properties

Effect of molecular symmetry on melting temperature and solubility

Rodolfo Pinal2004-01-01Organic & Biomolecular Chemistry

Molecular symmetry has a pronounced effect on the melting properties and solubility of organic compounds. As a general rule, symmetrical molecules in crystalline form have higher melting temperatures and exhibit lower solubilities compared with molecules of similar structure but with lower symmetry. Symmetry in a mole…

Polymer crystallization and propertiesSynthesis and Properties of Aromatic CompoundsGraph theory and applications

Effect of Stainless Steel-Containing Fabrics on Electromagnetic Shielding Effectiveness

Ching‐Iuan Su、Jin-Tsair Chern2004-01-01Textile Research Journal

In this paper, stainless steel is selected as the conductive filler to produce stainless steel hybrid yams to make woven fabrics. Using coaxial transmission equipment, the electro magnetic shielding effectiveness (EMSE) of these fabrics is measured. The experimental results show that a denser structure has a higher EM…

Electromagnetic wave absorption materialsElectromagnetic Compatibility and Noise SuppressionElectromagnetic Launch and Propulsion Technology

Preparation and Electrochemistry of SWNT/PANI Composite Films for Electrochemical Capacitors

Ying-ke Zhou、Benlin He、Wenjia Zhou 等 4 位作者2004-01-01Journal of The Electrochemical Society

Single-walled carbon nanotube/polyaniline (SWNT/PANI) composite films were prepared by in situ electrochemical polymerization of an aniline solution containing different SWNT contents. Surface morphology and structural properties of these PANI-based films were examined by a scanning electron microscope and X-ray photo…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Toughness of Ultrafine Grained Ferritic Steels Fabricated by ARB and Annealing Process

Nobuhiro Tsuji、Susumu Okuno、Yuichiro Koizumi 等 4 位作者2004-01-01MATERIALS TRANSACTIONS

A plain IF steel and a P-added IF steel having various ultrafine grain sizes from 0.24 to 11 μm were fabricated by the accumulative roll bonding (ARB) process followed by annealing. Dynamic fracture toughness of the ultrafine grained IF steels was investigated as a function of grain size by miniaturized Charpy impact…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMetal Forming Simulation Techniques

A “Nitrate Route” for the low temperature “Fast SCR” reaction over a V 2 O 5 –WO 3 /TiO 2 commercial catalyst

Cristian Ciardelli、Isabella Nova、Enrico Tronconi 等 5 位作者2004-01-01Chemical Communications

A novel mechanism is proposed for the Fast SCR reaction of NH(3), NO and NO(2) at low temperature involving the formation of ammonium nitrate as intermediate and its subsequent reaction with NO as the rate determining step.

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsAmmonia Synthesis and Nitrogen Reduction

Development of apatite‐type oxide ion conductors

Peter R. Slater、Jonathan E.H. Sansom、Julian R. Tolchard2004-01-01The Chemical Record

Research into materials displaying oxide ion conductivity is attracting considerable attention due to their potential technological applications in devices such as Solid Oxide Fuel Cells. In this paper, recent work on apatite-type oxide ion conductors is reviewed, showing that a wide range of cation substitutions are…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Multifunctional Bacterial Cellulose/Chitosan Composite Materials for Medical Applications

D. Ciechańska2004-01-01Fibres and Textiles in Eastern Europe

This paper presents some results concerning the characterisation of the structural parameters of bacterial cellulose/chitosan composite materials with regard to their medical application. Some chemical-physical, mechanical and biological properties of modified bacterial cellulose are presented. The innovatively-modifi…

Advanced Cellulose Research StudiesPolysaccharides Composition and Applications

Inorganic/organic mesostructure directed synthesis of wire/ribbon-like polypyrrole nanostructuresElectronic supplementary information (ESI) available: FT-IR spectra, powder XRD pattern and conductivities of as-made PPy nanostructures. See http://www.rsc.org/suppdata/cc/b4/b405255b/

Xuetong Zhang、Jin Zhang、Zhongfan Liu 等 4 位作者2004-01-01Chemical Communications

We report here a simple strategy for the synthesis of wire/ribbon-like polypyrrole nanostructures using lamellar inorganic/organic mesostructures as templates which were formed during polymerization between surfactant cations and oxidising anions and which were degraded automatically after polymerization.

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Fabrication of Sr-Doped LaFeO[sub 3] YSZ Composite Cathodes

Yingyi Huang、John M. Vohs、Raymond J. Gorte2004-01-01Journal of The Electrochemical Society

Composites of yttria-stabilized zirconia (YSZ) with Sr-doped (LSF) were studied for application as high-performance cathodes for solid oxide fuel cells (SOFCs). The composites were formed by aqueous impregnation of porous YSZ with La, Sr, and Fe salts, followed by calcination at various temperatures. X-ray diffraction…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Switching of molecular second-order polarisability in solution

Inge Asselberghs、Koen Clays、A. Persoons 等 5 位作者2004-01-01Journal of Materials Chemistry

Second-order nonlinear optical (NLO) polarisabilities or first hyperpolarisabilities, β, of molecules may be manipulated by reversibly modifying the properties of specific parts of active molecules, usually by on/off switching. This may involve reducing the donor capacity of the electron-rich fragment of a typical don…

Crystal structures of chemical compoundsNonlinear Optical Materials ResearchMolecular spectroscopy and chirality

The potential of flax fibres as reinforcement for composite materials

Harriëtte Louise Bos2004-01-01OpenAlex

hernieuwbare grondstoffen Subject headings: polymers; mechanical properties / fibre reinforced composite materials; microstructure / plant fibres; flax / reinforced plastics / adhesion / sustainable chemistry; renewable resources

Natural Fiber Reinforced CompositesVaried Academic Research Topics

Quantum chemistry-based interpretations on the lowest triplet state of luminescent lanthanides complexes. Part 1. Relation between the triplet state energy of hydroxamate complexes and their luminescence properties

F.A. Gutierrez、Christine Tedeschi、Laurent Maron 等 8 位作者2004-01-01Dalton Transactions

In this paper, we evaluate the potential use of theoretical calculations to obtain an energy scale of the lowest ligand-centred triplet excited state in luminescent terbium(III) complexes. In these complexes, non-radiative deactivation of the terbium emitting state via a back-energy transfer process (T1<--Tb(5D4)) is…

Advanced MRI Techniques and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Super-hydrophobic tin oxide nanoflowers

Aicheng Chen、Xinsheng Peng、Kallum M. Koczkur 等 4 位作者2004-01-01Chemical Communications

Super-hydrophobic 3D SnO(2) flowers with nanoporous petals were produced from the 3D Sn nanoflowers using a controlled shape-preserving thermal oxidation process.

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Super-hydrophobic and super-wetting surfaces: Analytical potential?

Glen McHale、Neil J. Shirtcliffe、Michael I. Newton2004-01-01The Analyst

Roughening or texturing surfaces provides super-liquid repellent or film forming properties without alteration of the surface chemistry. These surfaces are easy to produce, can amplify wetting properties and can be either “sticky” or “slippy” to liquids. Their use as water-repellent coatings is established, but their…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesAdhesion, Friction, and Surface Interactions

The Effect of Rheological Parameters on the Ballistic Properties of Shear Thickening Fluid (STF)-Kevlar Composites

Eric D. Wetzel2004-01-01AIP conference proceedings

The addition of colloidal shear thickening fluids (STFs) to Kevlar fabrics has been shown to enhance the ballistic penetration resistance of the fabric, under conditions of low velocities and small target sizes. It is believed that this improvement in ballistic properties is related to the resistance of the STF to def…

Textile materials and evaluations