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Solid solution of a zeolite and a framework-bound OSDA-containing molecular sieve

Jun Kyu Lee、Jeong Hwan Lee、Nak Ho Ahn 等 5 位作者2016-01-01Chemical Science

, UZM-22 and ECR-40-type FOMS), which has never been recognized or addressed before. The overall characterization results of this work demonstrate that the proportion of the zeolite domain in such solid-solutions varies significantly with the number of OH groups in OSDAs.

Metal-Organic Frameworks: Synthesis and ApplicationsZeolite Catalysis and SynthesisMesoporous Materials and Catalysis

Production and Characterization of Pozzolan with Raw Clay from Burkina Faso

Mohamed Seynou、Younoussa Millogo、Lamine Zerbo 等 7 位作者2016-01-01Journal of Minerals and Materials Characterization and Engineering

Four raw deposits clayey materials in Burkina Faso have been characterized using X-ray diffraction, infrared spectroscopy and ICP-AES to evaluate their suitability to be used as pozzolan in cement. The samples have been activated by thermal treatment at 730°C during 5 hours. The obtained metakaolin was investigated by…

Concrete and Cement Materials ResearchRecycling and utilization of industrial and municipal waste in materials productionClay minerals and soil interactions

Investigation into Drug Solubilisation Potential of Sulfonated Calix[4]Resorcinarenes

Clare Hoskins、A Papachristou2016-01-01Journal of Nanomedicine & Nanotechnology

Increasing importance is being placed on the role of drug solubilisation in the drug development pipeline. In order for drugs to successfully pass through the pre-clinical studies required before clinical trials they often require addition of excipients or solubility modifying agents. This study highlights the use of…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine Chemistry

Dendrimeric Biocides - A Tool for Effective Antimicrobial Therapy

Ramasamy Karthikeyan、Kumar PV2016-01-01Journal of Nanomedicine & Nanotechnology

Agents that are capable of killing pathogenic microorganisms are known as Antimicrobial Substances. These are of low molecular weight and used for the sterilization of water, as antimicrobial drugs, as food preservatives, and for soil sterilization. Due to their potential to provide quality and safety benefits to many…

Click Chemistry and ApplicationsDendrimers and Hyperbranched PolymersAntimicrobial agents and applications

Effect of variations of Cu II X 2 /L, surface area of Cu 0 , solvent, and temperature on atom transfer radical polyaddition of 4-vinylbenzyl 2-bromo-2-isobutyrate inimers

Chih‐Feng Huang、Shiao‐Wei Kuo、Daniela Moravčíková 等 10 位作者2016-01-01RSC Advances

Optimization of atom transfer radical polyadditions using commercially available catalytic systems allowed obtaining control over the polyester architecture and functionality and functional linear polyesters with high molecular weight ( M w = 16 200).

Advanced Polymer Synthesis and CharacterizationFuel Cells and Related MaterialsDendrimers and Hyperbranched Polymers

Excess mixing volume, microstrain, and stability of pyrope-grossular garnets

Wei Du、S. M. Clark、David Walker2016-01-01American Mineralogist

Synchrotron X-ray diffraction (XRD) was used to measure the unit-cell parameters of synthetic pyrope (Mg 3 Al 2 Si 3 O 12 ), grossular (Ca 3 Al 2 Si 3 O 12 ), and four intermediate garnet solid solutions. Garnets synthesized dry in multi-anvil (MA) apparatus at 6 GPa show irregular asymmetric positive quench- able exc…

High-pressure geophysics and materialsGlass properties and applicationsCrystal Structures and Properties

Visualization of High-Speed Impact of Penetrator into Icy Target

Kojiro Suzuki、Kazuya Namba、Yasumasa Watanabe2016-01-01Journal of Flow Control Measurement &amp Visualization

For application to exploration under the surface of icy objects in the solar system, the penetration of an impact probe into an icy target was experimentally simulated by using the ballistic range. Slender projectiles with a cylindrical body and various nose shapes were tested at the impact velocity 130 - 420 m/s. The…

High-Velocity Impact and Material BehaviorElectromagnetic Launch and Propulsion TechnologyGeotechnical and Geomechanical Engineering

Integrating error-prone PCR and DNA shuffling as an effective molecular evolution strategy for the production of α-ketoglutaric acid by l -amino acid deaminase

Gazi Sakir Hossain、Hyun‐Dong Shin、Jianghua Li 等 7 位作者2016-01-01RSC Advances

l -Amino acid deaminases (LAADs; EC 1.4.3.2) belong to a family of amino acid dehydrogenases that catalyze the formation of α-keto acids from l -amino acids.

RNA and protein synthesis mechanismsEnzyme Structure and FunctionBiochemical and Molecular Research

The effect of inorganic/organic dual dielectric layers on the morphology and performance of n-channel OFETs

Anamika Kalita、Anamika Dey、Parameswar Krishnan Iyer2016-01-01Physical Chemistry Chemical Physics

The optimization of dual dielectric layers by incorporating poly(vinyl alcohol) (PVA), poly(methyl methacrylate) (PMMA), polystyrene (PS) or poly(4-vinylphenol) (PVP) in combination with Al2O3 resulted in immensely improved OFET characteristics with N,N'-bis(cyclohexyl)naphthalene diimide (NDI-CY2) as the active mater…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

A comparative study of lysosome-targetable pH probes based on phenoxazinium attached with aliphatic and aromatic amines

Xiuli Wang、Xiaojun Li、Ru Sun 等 5 位作者2016-01-01The Analyst

In this paper, phenoxazinium was used as a fluorophore for the design of pH probes by the photoinduced electron transfer (PET) mechanism. Phenoxazinium with an aliphatic morpholinyl group (probe ) gave increased emission at 665 nm with pH ranging from 7.4 to 4.4; meanwhile, the other one with an aromatic diethylaminop…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsPhenothiazines and Benzothiazines Synthesis and Activities

Theoretical insights on morphology and charge transport properties of two-dimensional N,N′-ditridecylperylene-3,4,9,10-tetra carboxylic diimide aggregates

Andrea Lorenzoni、Federico Gallino、Michele Muccini 等 4 位作者2016-01-01RSC Advances

An integrated computational approach, based on molecular dynamics and density functional theory, reveals an interplay between morphology, processing and charge transport properties in layered aggregates of PTCDI-C13.

Organic Electronics and PhotovoltaicsConducting polymers and applicationsOrganic and Molecular Conductors Research

Stabilisation of an amorphous form of ROY through a predicted co-former interaction

Philip Corner、J. Jonathan Harburn、Jonathan W. Steed 等 5 位作者2016-01-01Chemical Communications

The highly polymorphic compound ROY, notorious for the colour of its crystals, was the subject of an optimised high-throughput ultrasound-based co-crystal screen. This screen involved a computational pre-screen which highlighted an interaction between ROY and the potential co-former pyrogallol. We have shown that the…

Cultural Heritage Materials AnalysisCrystallization and Solubility StudiesPigment Synthesis and Properties

Partial-surface-passivation strategy for transition-metal-based copper–gold nanocage

Shoujie Liu、Xusheng Zheng、Li Song 等 8 位作者2016-01-01Chemical Communications

An effective strategy involving the corrosion of partial-surface-passivated Cu nanoparticles is proposed for synthesizing transition-metal-based Cu-Au alloy nanocages. Time-dependent X-ray absorption spectroscopy demonstrates that the hollow-cage Cu-Au alloy nanostructure is formed by sequential erosion of the partial…

Gold and Silver Nanoparticles Synthesis and ApplicationsMolecular Junctions and NanostructuresNanomaterials for catalytic reactions

Identifying a Stable Counter/Reference Electrode for the Study of Aprotic Na–O2Batteries

Yantao Zhang、Lipo Ma、Lianqi Zhang 等 4 位作者2016-01-01Journal of The Electrochemical Society

The aprotic Na–O 2 battery has attracted significant interest over the past few years because of its high theoretical specific energy and uncompromised round-trip efficiency. So far, most of the Na–O 2 studies, using a cell configuration of Na metal anode, aprotic Na + electrolyte and porous O 2 cathode, focus on the…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic Conductivity

Nonequilibrium processes in condensed media. Part 2. Structural instability induced by shock loading

Т. А. Хантулева、Yu. I. Meshcheryakov2016-01-01Physical Mesomechanics

In the first part of the work, we described our concept of shock wave processes, which is based on nonlocal nonequilibrium transport theory, and an associated mathematical elastoplastic wave model that allows for inertial properties, structural changes, and variation in mechanical properties of solid-state materials u…

High-pressure geophysics and materialsEnergetic Materials and CombustionHigh-Velocity Impact and Material Behavior

Design and development of a poly(acrylonitrile-co-methyl methacrylate) copolymer to improve the viscoelastic and surface properties critical to scratch resistance

Nirav Gupta、Roopali Rai、A. K. Sikder 等 8 位作者2016-01-01RSC Advances

The present paper reports the design, development and evaluation of methyl methacrylate (MMA) and acrylonitrile (AN) copolymers to improve viscoelastic and surface properties critical to scratch resistance.

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchTribology and Wear Analysis