Materials Literature
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We demonstrate a surface enhanced Raman scattering (SERS) substrate by integrating plasmonic-active SiO(2) nanotubes into Si(3)N(4) gratings. First, the dielectric grating that is working under guided mode resonance (GMR) provides enhanced electric field for localized surface plasmon polaritons on the surface of metal…
[Dy(III)(HBpz(3))(2)](2+) moieties (HBpz(3)(-) = hydrotris(pyrazolyl)borate) and a 3d transition-metal ion (Fe(III) or Co(III)) have been rationally assembled using an dithiooxalato dianion ligand into 3d-4f [MDy(3)(HBpz(3))(6)(dto)(3)]·4CH(3)CN·2CH(2)Cl(2) (M = Fe (1), Co (2) complexes. Single-crystal X-ray studies r…
Thermal conduction in periodic multilayer composites can be strongly influenced by nonequilibrium electron-phonon scattering for periods shorter than the relevant free paths. Here we argue that two additional mechanisms-quasiballistic phonon transport normal to the metal film and inelastic electron-interface scatterin…
Interfacial polymerization (IP) is widely used in the synthesis of thin film composite membranes and encapsulation of active ingredients. However, there are few reports on the observation of film formation by IP. In the present work, a visualized technology was developed for studying film formation by interfacial poly…
Hollow mesoporous silica nanoparticles (HMSNs) are considered a potential drug delivery system owing to their recognized advantages in drug loading and releasing. However, whether HMSN could be degraded inside the cells remains unknown. In this study, based on the observations by transmission electron microscopy, fluo…
Abstract This work presents a comprehensive investigation of the piezoresistive response of a composite material based on conductive nickel filler in a silicone‐insulating matrix. In the absence of a deformation, the prepared composite shows no electric conductivity, even though the metal particle content is well abov…
One phenazopyridine monohydrate ( 1 ·H 2 O), one cocrystal of phenazopyridine with phthalimide ( 2 ), and three salts of phenazopyridine with benzoic acid ( 3 ), 4-hydroxyphenylacetic acid ( 4 ), and scaaharin ( 5 ) were synthesized, and their structures were determined by single crystal X-ray diffraction. The results…
Pure mesoporous nanosized ZnO samples have been synthesized by combustion synthesis method using different type of fuels such as citric acid, dextrose, glycine, oxalyl dihydrazide, oxalic acid, and urea. All these samples were found to have the standard hexagonal wurtzite structure with the lattice constants a and c h…
Atomic carbon on Co(0001), deposited by ethylene decomposition, forms islands with a (√3 × √3)R30° structure at low C coverage (∼0.2 ML), whereas a high C coverage (0.5 ML, saturation) induces a reconstruction of the cobalt surface. Atomic carbon weakens the adsorption of CO and H 2, but even a saturated atomic carbon…
Glycerol is considered as an ideal feedstock for producing bioplastics via bacterial fermentation due to its ubiquity, low price, and high degree of reduction substrate. In this work, we study the yield and cause of limitation in poly(3-hydroxybutyrate) (PHB) production from glycerol. Compared to glucose-based PHB pro…
Structure-adjustable capsules are fabricated from inorganic components by using a self-template dissolution-regrowth mechanism to give flake-shell silica microcapsules. The capsules shrink under thermal stimulus and their structures can be adjusted by treatment at different pH values. Tuning of shell pore diameters le…
Pristine, single-crystalline graphene displays a unique collection of remarkable electronic properties that arise from its two-dimensional, honeycomb structure. Using in situ low-energy electron microscopy, we show that when deposited on the (111) surface of Au carbon forms such a structure. The resulting monolayer, e…
We have measured the intrinsic exciton dephasing in high-quality zinc blende CdSe/CdS colloidal quantum dots in the temperature range from 5 to 170 K using a sensitive three-beam photon echo technique in heterodyne detection, which is not affected by spectral diffusion. Pure dephasing via acoustic phonons dominates th…
We study experimentally and theoretically a dense ensemble of negatively charged nitrogen-vacancy centers in diamond coupled to a high-$Q$ superconducting coplanar waveguide cavity mode at low temperature. The nitrogen-vacancy centers are modeled as effective spin-one defects with inhomogeneous frequency distribution.…
Using neutron reflectometry and resonant x-ray techniques we studied the magnetic proximity effect (MPE) in superlattices composed of superconducting ${\mathrm{YBa}}_{2}{\mathrm{Cu}}_{3}{\mathrm{O}}_{7}$ and ferromagnetic-metallic ${\mathrm{La}}_{0.67}{\mathrm{Ca}}_{0.33}{\mathrm{MnO}}_{3}$ or ferromagnetic-insulating…
Epitaxial thin films of titanium perovskite oxyhydride ATiO(3-x)H(x) (A = Ba, Sr, Ca) were prepared by CaH(2) reduction of epitaxial ATiO(3) thin films deposited on a (LaAlO(3))(0.3)(SrAl(0.5)Ta(0.5)O(3))(0.7) substrate. Secondary ion mass spectroscopy detected a substantial amount and uniform distribution of hydride…
[001]-textured Pb(Mg1/3Nb2/3)O3-PbTiO3 (PMN-PT) ceramics were synthesized by using templated grain growth method. Significantly high [001] texture degree corresponding to 0.98 Lotgering factor was achieved at 1 vol. % BaTiO3 template. Electromechanical properties for [001]-textured PMN-PT ceramics with 1 vol. % BaTiO3…
In this work, we investigated the temperature-dependent luminescence of bovine serum albumin-protected Au 25 nanoclusters and the correlation with their structure. Our experiments reveal that the red luminescence consists of two bands, namely, band I at 710 nm and band II at 640 nm. The temperature dependence of band…
The electromagnetic enhancement for surface enhanced Raman spectroscopy (SERS) of graphene is studied by inserting a layer of Al2O3 between epitaxial graphene and Au nanoparticles. Different excitation lasers are utilized to study the relationship between laser wavelength and SERS. The theoretical calculation shows th…
NiO6-octahedral tilts in ultrathin LaNiO3 films were studied using position averaged convergent beam electron diffraction (PACBED) in scanning transmission electron microscopy. Both the type and magnitude of the octahedral tilts were determined by comparing PACBED experiments to frozen phonon multislice simulations. I…