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Corrosion of Zircaloy in the Presence of LiOH

RA Perkins、RA Busch1991-01-01OpenAlex

The corrosion of Zircaloy-4 is accelerated in water or steam above about 350°C when LiOH is present in sufficient concentrations. A short-term test (16 h) to predict inreactor corrosion behavior has been developed based on this accelerated corrosion. A group of claddings with a range of in-reactor corrosion behavior h…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

In-situ analysis of passive films on high purity Fe-Cr alloys using ellipsometry and potential-modulated reflection spectroscopy.

Nobuyoshi Hara、Shiro Matsuda、Katsuhisa Sugimoto1991-01-01ISIJ International

Passive films on high purity Fe-Cr alloys (13-24 mass% Cr), which were prepared by an Ar plasma melting method using high purity Fe produced by a method combining anion exchange and zone-refining processes and high purity Cr produced by an iodide process, have been investigated in-situ in pH 6.0, 1 kmol·m–3 Na2SO4 usi…

Hydrogen embrittlement and corrosion behaviors in metalsIon-surface interactions and analysis

Diamond and diamond‐like carbon

Peter K. Bachmann、Ute Linz1991-01-01Advanced Materials

Research News/Diamond Thin Film Technology IIb : The second part of this article continues the description of work presented at a two‐week Advanced Study Institute held in the mountains of Tuscany. Topics under discussion were deposition methods, deposition parameters, and applications, including cutting tool inserts,…

Diamond and Carbon-based Materials Research

Blends of sulphonated polystyrene and polystyrene: Morphology and deformation modes

M. Hara、M. A. Bellinger、J. A. Sauer1991-01-01Polymer International

Abstract Blends of sulphonated polystyrene, neutralized with metal ions, have been prepared in various proportions with polystyrene homopolymer. Morphology, microstructure, and deformation modes of strained, cast thin films have been examined by transmission electron microscopy. Variables studied include blend composi…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Diffusion in a continuous medium with space-correlated disorder

Á. Valle、Miguel A. Rodríguez、L. Pesquera1991-01-01Physical Review A

We analyze the effect of space-correlated disorder on diffusion in a one-dimensional continuous disordered medium. We calculate the frequency-dependent diffusion coefficient using a method based on a perturbative treatment around an effective homogeneous medium. Exact results for disorder modeled by a two-level proces…

Material Dynamics and PropertiesTheoretical and Computational PhysicsAdvanced Mathematical Modeling in Engineering

A Mössbauer spectroscopy study of the system ZrNi – H and ZrCo – H

Stephen J.H. Yang、F. Aubertin、Peter Rehbein 等 4 位作者1991-01-01Zeitschrift für Kristallographie

ZrNi, ZrCo and their hydrides doped with 57 Fe are investigated using Mössbauer spectroscopy. Hydrogenation of ZrNi results first in ZrNiH and then in ZrNiH 3 , whereas only ZrCoH 3 is produced in the case of ZrCo. At low hydrogen concentrations hydrogen atoms enter mainly 4 c 1 interstitial sites, but 8 f 1 , 8 g 2 a…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsNuclear Materials and Properties

Critical evaluation of liquid crystal transition temperatures I: 4,4′-alkyl/alkoxyphenylbenzoates

Terence T. Blair、Mary E. Neubert、Mitchell Tsai 等 4 位作者1991-01-01Journal of Physical and Chemical Reference Data

Transition temperatures for 367 straight chain 4,4′-alkyl/alkoxyphenylbenzoates (through Nov. 1990) have been compiled and critically evaluated. Information was obtained wherever possible, with the exception of the patent literature, and examined for editorial coherency. Line graphs of the melting and clearing tempera…

Liquid Crystal Research AdvancementsCrystallization and Solubility StudiesMolecular spectroscopy and chirality

Structure of a 50 mol kg –1 aqueous solution of ammonium nitrate at 373 K by the isotopic difference method of neutron diffraction

Ashok K. Adya、George W. Neilson1991-01-01Journal of the Chemical Society Faraday Transactions

A neutron diffraction study of a 50 mol kg–1 aqueous solution of deuterated ammonium nitrate [ca. 1 : 1 molecular ratio of D2O : N(1)D4N(2)O3 which is the saturation solubility at ca. 70 °C] was carried out at 100 °C. The first- and second-order isotopic difference methods of neutron diffraction were applied to the ni…

Spectroscopy and Quantum Chemical StudiesSolid-state spectroscopy and crystallographyChemical and Physical Properties in Aqueous Solutions

Electron‐count imaging in SEM

S. Yamada、Tsuyoshi Ito、K. Gouhara 等 4 位作者1991-01-01Scanning

Abstract We propose a method and a system for counting secondary electrons and for displaying micrographs from the SEM in real time. Evaluating the images obtained by the new system, we confirm that electron counting images have a higher signal to noise ratio than analogue images. This tendency is remarkable when the…

Advanced Electron Microscopy Techniques and ApplicationsAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

Impact of Polarization Relaxation on Ferroelectric Memory Performance

R. Moazzami、Norman Abt、Y. Nissan‐Cohen 等 6 位作者1991-01-01OpenAlex

Ferroelectric materials such as lead zirconate titanate (PZT) possess several characteristics which are desirable for high density volatile and nonvolatile memories including a high dielectric constant, high speed read/write capability, large remanent polarization, and long term data retention.

Ferroelectric and Piezoelectric MaterialsPhase-change materials and chalcogenidesFerroelectric and Negative Capacitance Devices

Observations of Fatigue Crack Initiation and Damage Growth in Notched Titanium Matrix Composites

RA Naik、WS Johnson1991-01-01OpenAlex

The purpose of this study was to characterize crack initiation and growth in notched titanium matrix composites at room temperature. Double-edge-notched or center-open-hole SCS-6/Ti-15-3 specimens containing 0° or both 0° and 90° plies were fatigued. The specimens were tested in the as-fabricated (ASF) and in heat-tre…

Metal Forming Simulation TechniquesAdvanced Welding Techniques AnalysisTitanium Alloys Microstructure and Properties

Phase Microidentification from Selected Area Electron Diffraction (SAED) and Energy Dispersive Spectroscopy (EDS) Data

J. Macíček1991-01-01Advances in X-ray Analysis

Abstract Two-dimensional geometry information contained in SAED spot patterns augmented with EDS elemental data is employed in a computerized phase identification of microcrystalline particles. The initial chemistry screening of a laboratory managed database using the 'bitmap' concept is followed by a geometry search/…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesX-ray Diffraction in Crystallography

Multi-Winding Milti-Phase Transformer Model with Saturable Core

H. Mohseni1991-01-01IEEE Power Engineering Review

A model is presented for a multiwinding multiphase transformer developed by the nodal inverse inductance matrix (NIIM). To obtain the NIIM the inverse of the inductance matrix is needed. Due to the strong magnetic coupling among the windings, the inductance matrix of a transformer is ill-conditioned. A new way is desc…

Magnetic Properties and ApplicationsElectromagnetic Simulation and Numerical MethodsMagneto-Optical Properties and Applications

Ionic Double Layers at the Surface of Magnesium‐Doped Aluminum Oxide: Effect on Segregation Properties

Sharmila M. Mukhopadhyay、J. M. Blakely1991-01-01Journal of the American Ceramic Society

A model involving ionic double layers at the surface has been constructed for magnesia‐doped sapphire based on earlier models which were developed for cubic halides. The model takes into account the presence of electrostatic potentials, isolated point defects, defect complexes, and special surface sites which can act…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisMagnesium Oxide Properties and Applications

Dynamic Characteristics of Externally Pressurized, Double-Pad, Circular Thrust Bearings With Membrane Restrictors

C. Wang、C. Cusano1991-01-01Journal of Tribology

The dynamic characteristics of externally pressurized, double-pad, circular thrust bearings with membrane variable flow compensation are analytically studied. Under static loads or load composed of a static and cyclic component, membrane compensation gives better overall performance characteristics than capillary (fix…

Tribology and Lubrication EngineeringSilicone and Siloxane Chemistry

Plasticization of bacterial polyester by the addition of acylglycerols and its enzymatic degradability.

Kenji Ishikawa、Yasushi Kawaguchi、Yoshiharu Doi1991-01-01KOBUNSHI RONBUNSHU

ある種のアシルグリセロールは微生物産生ポリ (3-ヒドロキシブチレート) (PHB) の優れた可塑剤として作用し, PHBのガラス転移温度 (Tg) を低下させ, 破断伸びを増加させた. 可塑剤として働く脂質は, アルキル鎖長の短い (炭素数5以下) トリアシルグリセロールやアルキル鎖長の長い (炭素数17程度) モノアシルグリセロールであった. 特に, グリセロールトリアセテートは優れた可塑剤であり, PHBに30wt%混合すると, ヤング率を1620MPaから280MPaまで低下させ, 破断伸びをS%から130%まで増加させた. その時, 脂質はPHBと相容し, 非晶部のPHB分子鎖の運動性を上げることを固体13C NMR解析…

Advanced Cellulose Research Studiesbiodegradable polymer synthesis and propertiesMicrobial Metabolism and Applications

Factors affecting the accuracy of elemental analysis by transmission EELS

Raymond F. Egerton1991-01-01Microscopy Microanalysis Microstructures

The accuracy of elemental analysis by electron energy-loss spectroscopy depends on many factors, such as the concentration of the elements being analysed and the energies of the corre- sponding ionization edges. We discuss sources of inaccuracy in the acquisition and analysis of spectra, in the quantification procedur…

Atomic and Molecular PhysicsLaser-induced spectroscopy and plasmaElectron and X-Ray Spectroscopy Techniques

Kinetics of Non‐isothermal Overall Crystallization in Polymer Melts

A. Dobreva、I. Gutzow1991-01-01Crystal Research and Technology

Abstract A simple formalism describing the non‐isothermal crystallization kinetics in cooling runs at small undercoolings is suggested. A general mathematical method for analyzing processes of non‐isothermal phase formation, accounting for the proper temperature course of the nucleation rate and of the linear growth v…

Polymer crystallization and propertiesThermal and Kinetic AnalysisPolymer Science and PVC

Gas-phase silver chalcogenide ions investigated by laser-ablation Fourier transform ion cyclotron resonance mass spectrometry

John Ei-Nakat、Ian Dance、Keith J. Fisher 等 4 位作者1991-01-01Journal of the Chemical Society Chemical Communications

When laser-ablated and monitored by FTICR mass spectrometry, silver sulphide, selenide and telluride, and elemental mixtures of silver with selenium or tellurium, yield large silver chalcogenide cluster anions, including the series [Ag2n– 1En]–(E = S, Se, Te) with n⩽ 14.

Advanced Chemical Physics StudiesCrystal Structures and PropertiesInorganic Chemistry and Materials

Active Corrosion Rate for Ti-based Alloys in Aqueous Corrosion and Its Correlation with the Bond Order Obtained by Electron Theory.

Masao Morishita、Yoshio Ashida、Masahiro Chikuda 等 6 位作者1991-01-01ISIJ International

In order to understand alloying effects on the corrosion resistance of titanium, polarization curve were measured at 343 K in both 10 mass% HCl and 10 mass% H2SO4 solutions with various Ti-M binary alloys (M=Al, Nb, Ta, Zr, Hf, Fe, V, Cr, Mo, Co and Ni). The results were interpreted by using the bond order (Bo) obtain…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsTitanium Alloys Microstructure and Properties