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A new configurational transition in inhomogeneous nematics

Peter Palffy‐Muhoray、Eugene C Gartland、Jack Kelly1994-04-01Liquid Crystals

At the wall in a hybrid cell with strong anchoring, the nematic director is parallel to one wall and perpendicular to the other. Usually, the free energy is minimized by a configuration where the director orientation changes continuously with position across the cell. The boundary conditions can also be satisfied, how…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationAdvanced Materials and Mechanics

Stability and kinetics of step motion on crystal surfaces

Fong Liu、Horia Metiu1994-04-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The kinetics of monoatomic steps in diffusion-controlled crystal growth and evaporation processes are investigated analytically using a Green's function approach. Integro-differential equations of motion for the steps are derived; a systematic linear stability analysis is carried out treating simultaneously perturbati…

Solidification and crystal growth phenomenaNonlinear Dynamics and Pattern Formationnanoparticles nucleation surface interactions

Mechanism of Diffuse Phase Transition in Relaxor Ferroelectrics

Takaaki Tsurumi、Kouji Soejima、Toshio Kamiya 等 4 位作者1994-04-01Japanese Journal of Applied Physics

Dielectric properties of lead magnesium niobate (PMN) and Ta-bearing strontium barium niobate (SBNT) were measured as a function of temperature, and the crystal structure of PMN was refined by the Rietveld analysis method. The results of structure refinement indicate that the volume of polar microregions (PMR) increas…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Polymerization of .epsilon.-Caprolactone by Divalent Samarium Complexes

William J. Evans、Hideo Katsumata1994-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolymerization of .epsilon.-Caprolactone by Divalent Samarium ComplexesWilliam J. Evans and Hideo KatsumataCite this: Macromolecules 1994, 27, 8, 2330–2332Publication Date (Print):April 1, 1994Publication History Published online1 May 2002Published inissue 1 April 1994https:…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Molecular Modeling of Polycarbonate. 1. Force Field, Static Structure, and Mechanical Properties

Cun Feng Fan、Tahir Çağın、Zhuo Min Chen 等 4 位作者1994-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolecular Modeling of Polycarbonate. 1. Force Field, Static Structure, and Mechanical PropertiesCun Feng Fan, Tahir Cagin, Zhuo Min Chen, and Kennith A. SmithCite this: Macromolecules 1994, 27, 9, 2383–2391Publication Date (Print):April 1, 1994Publication History Published o…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Amorphous, biomimetic granules of polyhydroxybutyrate: preparation, characterization, and biological implications

Daniel Horowitz、Jeremy K. M. Sanders1994-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAmorphous, biomimetic granules of polyhydroxybutyrate: preparation, characterization, and biological implicationsDaniel M. Horowitz and Jeremy K. M. SandersCite this: J. Am. Chem. Soc. 1994, 116, 7, 2695–2702Publication Date (Print):April 1, 1994Publication History Published…

Parkinson's Disease Mechanisms and Treatmentsbiodegradable polymer synthesis and properties

Modification of surface band bending of diamond by low energy argon and carbon ion bombardment

W. M. Lau、L. J. Huang、I. Bello 等 5 位作者1994-04-01Journal of Applied Physics

Argon and carbon ion bombardment of p-diamond at 500–5000 eV in ultrahigh vacuum were studied by in situ x-ray photoelectron spectroscopy (XPS) and low energy electron diffraction analysis. Both argon and carbon ion bombardment at room temperature in the present energy range created a defective surface layer. The radi…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Hysteresis in the Binary Exchange of Cations on 2:1 Clay Minerals: A Critical Review

Kirsten Verburg、Philippe C. Baveye1994-04-01Clays and Clay Minerals

Abstract The binary exchange of cations on clays and soils is generally regarded as a thermodynamically reversible process. The literature on soil chemistry and geochemistry, however, abounds with reports on cation exchange reactions that appear to have only limited reversibility, i.e., that exhibit hysteresis. A sati…

Adsorption and biosorption for pollutant removalSoil and Unsaturated FlowClay minerals and soil interactions

The two-winding transformer: an experimental method to obtain a wide frequency range equivalent circuit

B. Cogitore、J.P. Keradec、J. Barbaroux1994-04-01IEEE Transactions on Instrumentation and Measurement

A lumped-component equivalent circuit has been developed by our team to model the electric behavior of any two-winding transformer. This circuit is general: its topology is independent of shape, sizes, and technology chosen. Changing the sample results only in a change of numerical values. Moreover, this circuit is su…

Advanced DC-DC ConvertersHigh voltage insulation and dielectric phenomenaMagnetic Properties and Applications

Crevice Corrosion of Alloy 625 in Chlorinated ASTM Artificial Ocean Water

R. S. Lillard、M. P. Jurinski、John R. Scully1994-04-01CORROSION

Factors controlling the initiation and propagation of crevice corrosion on alloy 625 (UNS N06625) in ocean water of ambient temperature were explored within the contexts of the Oldfield-Sutton model for critical crevice corrosion solution (CCS) development and the ohmic criterion for crevice corrosion initiation. Data…

Corrosion Behavior and InhibitionHigh-Temperature Coating BehaviorsHydrogen embrittlement and corrosion behaviors in metals

Production of polyhydroxyalkanoates in sucrose-utilizing recombinant Escherichia coli and Klebsiella strains

Hu Zhang、V Obias、K Gonyer 等 4 位作者1994-04-01Applied and Environmental Microbiology

The cloned poly-3-hydroxybutyrate (PHB) synthesis pathway from Alcaligenes eutrophus has been introduced into sucrose-utilizing strains of Escherichia coli, Klebsiella aerogenes, and Klebsiella oxytoca. The plasmid-borne genes were well expressed in these environments and were able to mediate the production of signifi…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Application of nonlinear dynamics and chaos to ferroresonance in distribution systems

Bruce A. Mork、D. L. Stuehm1994-04-01IEEE Transactions on Power Delivery

Ferroresonant overvoltages or undervoltages can occur in cable-fed power transformer installations when single phase switching or interrupting is practiced. This paper identifies the ferroresonant circuit as a nonlinear dynamical system. Analysis and classification methods are presented which provide new insight into…

Chaos control and synchronizationMagnetic Properties and ApplicationsPower Transformer Diagnostics and Insulation

Grain Growth Kinetics in Alumina–Zirconia (CeZTA) Composites

K.B. Alexander、Paul Becher、Shirley B. Waters 等 4 位作者1994-04-01Journal of the American Ceramic Society

Grain growth kinetics in alumina‐rich, zirconia–alumina composites have been examined as a function of volume fraction of zirconia. Both he microstructural scale and character alter during grain growth. Grain growth exponents between n = 3 and 4 were observed and have been rationalized in terms of current models for g…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesBauxite Residue and Utilization

New Perspectives in Polyoxometalate Chemistry by isolation of compounds containing very large moieties as transferable building blocks: (NMe4)5[As2Mo8V4AsO40] · 3H2O, (NH4)21[H3Mo57V6(NO)6O183(H2O)18] · 65 H2O, (NH2Me2)18(NH4)6[Mo57V6(NO)6O183(H2O)18] · 14 H2O, and (NH4)12[Mo36(NO)4O108(H2O)16] · 33 H2O

Achim Müller、Erich Krickemeyer、Stephan Dillinger 等 10 位作者1994-04-01Zeitschrift für anorganische und allgemeine Chemie

Abstract The compounds (NMe 4 ) 5 [As 2 Mo 8 V 4 AsO 40 ] · 3 H 2 O 2a , (NH 4 ) 21 [H 3 Mo 57 V 6 (NO) 6 O 183 (H 2 O) 18 ] · 65 H 2 O 3a , (NH 2 Me 2 ) 18 (NH 4 ) 6 [Mo 57 V 6 (NO) 6 O 183 (H 2 O) 18 ] · 14 H 2 O 3b and (NH 4 ) 12 [Mo 36 (NO) 4 O 108 (H 2 O) 16 ] · 33 H 2 O 4a ( 3a and 4a were not correctly reported…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Off-lattice Monte Carlo simulation of polymer brushes in good solvents

Mohamed Laradji、Guo Hong、Martin J. Zuckermann1994-04-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We report an off-lattice Monte Carlo calculation of the equilibrium properties of a monodisperse polymer brush in a good solvent. We find that the density profile, in general, is in agreement with the results of self-consistent field theory, with some discrepancies observed near the wall and at the tail of the profile…

Polymer Surface Interaction StudiesAdhesion, Friction, and Surface InteractionsPickering emulsions and particle stabilization

Effects of the addition of small amounts of Al to copper: Corrosion, resistivity, adhesion, morphology, and diffusion

Peng Ding、W. A. Lanford、S. Hymes 等 4 位作者1994-04-01Journal of Applied Physics

The properties of thin films of Cu with 1 at. % Al are explored. As-deposited films of Cu(1 at. % Al) oxidize orders of magnitude more slowly than do those of pure Cu. After Cu(1 at. % Al) films are annealed in Ar at 400 °C for 30 min, very thin protective layers of aluminum oxide form on the surface. These thin oxide…

Semiconductor materials and devicesCopper Interconnects and ReliabilityAnodic Oxide Films and Nanostructures

Interactions of soft atomic potentials and universality of low-temperature properties of glasses

Д. А. Паршин1994-04-01Physical review. B, Condensed matter

It is shown that the interaction between soft atomic potentials in glasses leads to a density of the low-energy tunneling states, P\ifmmode\bar\else\textasciimacron\fi{}, which does not depend on the concentration of defects. The dimensionless parameter P\ifmmode\bar\else\textasciimacron\fi{}${\ensuremath{\gamma}}^{2}…

High-pressure geophysics and materialsMaterial Dynamics and PropertiesGlass properties and applications

Syntheses of Mixed-Metal Sulfide Cubane-Type Clusters with the Novel PdMo3S4 Core and Reactivities of the Unique Tetrahedral Pd Site Surrounded by Sulfide Ligands toward Alkenes, CO, tBuNC, and Alkynes

Takashi Murata、Y. Mizobe、Hong Gao 等 12 位作者1994-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSyntheses of Mixed-Metal Sulfide Cubane-Type Clusters with the Novel PdMo3S4 Core and Reactivities of the Unique Tetrahedral Pd Site Surrounded by Sulfide Ligands toward Alkenes, CO, tBuNC, and AlkynesTakashi MurataTakashi MurataMore by Takashi Murata, Yasushi MizobeYasushi…

Carbon dioxide utilization in catalysisNanocluster Synthesis and ApplicationsInorganic Chemistry and Materials

An experimental analysis of DC excitation of transformers by geomagnetically induced currents

N. Takasu、T. Oshi、F. Miyawaki 等 5 位作者1994-04-01IEEE Transactions on Power Delivery

DC excitation of transformers due to geomagnetically induced currents was studied by model experiments. First, differences in the DC excitation phenomenon due to the iron core structure were studied using three typical small-scale models. The results verified that single-phase three-legged cores were most susceptible…

Lightning and Electromagnetic PhenomenaMagnetic Properties and ApplicationsHigh-Voltage Power Transmission Systems

Structural Predictions in the ABO3 Phase Diagram

Daniel M. Giaquinta、Hans‐Conrad zur Loye1994-04-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructural Predictions in the ABO3 Phase DiagramDaniel M. Giaquinta and Hans-Conrad zur LoyeCite this: Chem. Mater. 1994, 6, 4, 365–372Publication Date (Print):April 1, 1994Publication History Published online1 May 2002Published inissue 1 April 1994https://pubs.acs.org/doi/1…

Inertial Sensor and NavigationSolid-state spectroscopy and crystallographyMarine and Coastal Research