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第 194587 / 197913 页 · 当前展示 3,891,721–3,891,740 / 3,958,245 条匹配结果 · 摘要仅作预览

Anodic Behavior of Iron in Ammoniacal Carbonate Solution: I . Steady‐State Polarization and Cyclic Voltammetry

Y. T. Kho、K. Osseo‐Asare、H. W. Pickering1992-01-01Journal of The Electrochemical Society

Two distinct Tafel regions are observed in the active region of the anodic polarization curve of iron in ammoniacal carbonate solution. A prepassive layer may form in the Tafel region at the higher overpotentials. A hydrogen oxidation peak is proposed to occur in the lower overpotential Tafel region. Anodic dissolutio…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsElectrochemical Analysis and Applications

Molecular Dynamics Study of Li2SiO3in the Liquid and Glassy States

Junko Habasaki、Isao Okada1992-01-01Molecular Simulation

Molecular dynamics simulation (MD) has been carried out for Li2SiO3 in the molten and glassy states. The parameters of the pair potential functions were determined by a trial and error method so that the results of X-ray diffraction analysis could be well reproduced. The changes in the structure and dynamic properties…

Glass properties and applicationsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Hydrated rare-earth-metal ion-exchanged zeolite a : characterization by luminescence spectroscopy. Part 1.—The Gd 3+ ion

M.F. Hazenkamp、Adriaan M. H. van der Veen、G. Blasse1992-01-01Journal of the Chemical Society Faraday Transactions

The luminescence properties under high-resolution excitation and emission conditions at 4.2 K of hydrated Gd3+ion-exchanged zeolite A are reported. From these luminescence measurements it is found that in a sample containing 0.8 wt.% Gd3+, only one site appears to be occupied by Gd3+. In a freshly prepared sample cont…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsLanthanide and Transition Metal Complexes

High Temperature Strength of SiC-AlN Solid Solutions and Composites as Evaluated by Small Punch Tests

Jing‐Feng Li、Akira Kawasaki、Ryuzo Watanabe1992-01-01Journal of the Japan Institute of Metals and Materials

Fully dense compacts of SiC-AlN solid solution and composite were fabricated by the combination of reaction synthesis and hot isostatic pressing (HIP). Their strength and deformation behavior were investigated from room temperature to 1773 K by a Modified Small Punch (MSP) test which has been found to be suitable for…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Static disorder of dodecasil 3C. A single-crystal study with synchrotron radiation

Mark Könnecke、G. Miehe、H. Fueß1992-01-01Zeitschrift für Kristallographie

A crystal of dodecasil 3C (ZSM-49, 136 SiO 2 ) was prepared and heat treated to expel the enclathrated guest species. The structure of this sample was refined [space group Fd [unk] m , a = 19.369(6) Å] to R w = 0.057 from 1068 reflections collected at 573 K with synchrotron radiation at λ = 0.593 Å. Anisotropic refine…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchX-ray Diffraction in Crystallography

Properties of a semi‐crystalline and an amorphous thermotropic liquid crystalline polymer

Douglas E. Turek、George P. Simon1992-01-01Polymer International

Abstract The physical properties, thermal stability, rheology and tensile properties of a commercial semi‐crystalline and an amorphous thermotropic liquid crystalline polymer (TLCP) have been investigated. Analysis by differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMTA) confirm the pr…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Effect of Purity on Diffusivity and Solubility of Hydrogen in Aluminum

Minoru Ichimura、Yasushi Sasajima、Mamoru Imabayashi1992-01-01Materials Transactions JIM

Diffusion coefficient and solubility of hydrogen in commercial pure solid aluminum of 2N(99.7 mass%) were measured by means of the ordinary desorption method, and they were compared with those of high-purity 4N aluminum. A variety of distribution of intermetallic compound particles did not essentially influence the hy…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesHigh Temperature Alloys and Creep

The structure and magnetism of a trimetallic µ-oxo ruthenium( IV ) porphyrin–iron( III ) salicylideneamine complex containing the Fe–O–Ru–O–Fe system

Lewis D. Schulz、Gary D. Fallon、Boujemaa Moubaraki 等 5 位作者1992-01-01Journal of the Chemical Society Chemical Communications

The redox reaction between trans-dioxotetraphenylporphyrinruthenium(VI) and two equivalents of the five-coordinate iron(II) salicylideneamine complex Fe(salmah) in toluene results in the transfer of two electrons and formation of the novel bis-µ-oxo trimetallic complex [RuIV(tpp){OFeIII(salmah)}2] containing first and…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Friction welding of shape memory alloy

Takeshi Shinoda、T. Tsuchiya、Hiroki Takahashi1992-01-01Welding International

(1992). Friction welding of shape memory alloy. Welding International: Vol. 6, No. 1, pp. 20-25.

Welding Techniques and Residual StressesShape Memory Alloy TransformationsLaser and Thermal Forming Techniques

Lariat ether bola-amphiphiles: formation of crown ether based bola-amphisomes

Servando Muñoz、Jesus Mallen、Akio Nakano 等 7 位作者1992-01-01Journal of the Chemical Society Chemical Communications

The first crown ether-based bola-amphiphiles are prepared and are shown to aggregate into a previously unknown type of niosome.

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesSupramolecular Self-Assembly in Materials

Radiation-Induced Segregation in 20Cr/25Ni/Nb Stainless Steel

D.I.R. Norris、Charley Baker、Christopher D. Taylor 等 4 位作者1992-01-01OpenAlex

Intergranular corrosion of irradiated austenitic steels has been attributed to compositional changes produced by radiation-induced segregation at grain boundaries, and the effect has been investigated for the 20Cr/25Ni/Nb stainless steel employed as fuel cladding in advanced gas-cooled reactors. Analytical electron mi…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Formation process of kaolinite from the amorphous mixture of silica and alumina

Ritsuro Miyawaki、Shinji Tomura、Keiichi Inukai 等 7 位作者1992-01-01Clay science/Clay Science

The formation process of kaolinite from the amorphous mixture of silica and alumina by hydrothermal reaction was studied by XRD, IR, DTA-TG, TEM, and high-resolution solid state 29 Si- and 27 Al-MAS/NMR. The amorphous mixture of the starting material prepared with commercially available silica-sol and alumina-sol was…

Glass properties and applicationsArsenic contamination and mitigationClay minerals and soil interactions

Reduction of Platinum Corrosion in Molten Glass

Bernd Fischer1992-01-01Platinum Metals Review

In order to ensure the high quality necessary for use in scientific instruments, most high-technology optical glasses are melted in platinum containers. In general, this noble metal has excellent corrosion and erosion resistance, as well as low solubility, when in contact with molten glass. Therefore the dangers of di…

Material Properties and Applications

Wear Testing of Advanced Materials

R Divakar、P.J. Blau1992-01-01OpenAlex

Description STP 1167 addresses special problems engineers encounter when developing and using wear tests for ceramics and other advanced materials.

Metal and Thin Film MechanicsTribology and Wear AnalysisMetal Alloys Wear and Properties

Performance of Protective Clothing: Fourth Volume

JP McBriarty、NW Henry1992-01-01OpenAlex

Description 80 peer-reviewed papers address these issues: • Hazards and Methods (including aerosols, physical resistance, biological, chemical, pesticides, and thermal and heat) • Field tests, New tests, Evaluations, Design, Physiological, Performance (including field tests, new and improved tests, evaluations, physio…

Textile materials and evaluationsFashion and Cultural Textiles

Development of 800 kV gas-insulated switchgear

H. Toda、Y. Ozaki、Isao Miwa 等 6 位作者1992-01-01IEEE Transactions on Power Delivery

An 800 kV gas-insulated switchgear, with a capacity level recognized as the largest in the world, was developed as the first development of UHV gas-insulated switchgear, and good results were obtained in the type tests for this switchgear. With the gas circuit breaker and the disconnector used in this gas-insulated sw…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaThermal Analysis in Power Transmission

A Mathematical Model for the Influence of Deep‐Level Electronic States on Photoelectrochemical Impedance Spectroscopy: II . Assessment of Characterization Methods Based on Mott‐Schottky Theory

D. Bivings Bonham、Mark E. Orazem1992-01-01Journal of The Electrochemical Society

The impact of the assumptions inherent in using the Mott‐Schottky theory to identify deep‐level electronic states in semiconductors was assessed by comparison to the results of a less restrictive mathematical model. The model, developed in another paper, treated the transport and recombination reactions involving elec…

Transition Metal Oxide NanomaterialsElectrochemical Analysis and ApplicationsElectron and X-Ray Spectroscopy Techniques

Reactivation of poly(3-methylthiophene) following overoxidation in the presence of chloride

Zhigang Qi、Peter G. Pickup1992-01-01Journal of the Chemical Society Chemical Communications

Poly(3-methylthiophene) films made electrochemically inactive by overoxidation in the presence of Cl– can be reactivated both electrochemically and chemically to produce a partially chlorinated conducting polymer.

Organic Electronics and PhotovoltaicsConducting polymers and applicationsElectrochemical Analysis and Applications

Poly(rA) ioinos poly(rG) poly(rC) to form a tripie helix

Michael Chastain、Ignacio Tinoco1992-01-01Nucleic Acids Research

Poly(rA) binds poly(rG).poly(rC) to form a triple helix. Evidence for this structure includes ultraviolet absorbance mixing curves and melting curves, and circular dichroism spectroscopy. The formation of the triple helix depends on the length of the poly(rC) strand. Triple helix forms when the average length is aroun…

Mesoporous Materials and CatalysisPorphyrin and Phthalocyanine ChemistryCovalent Organic Framework Applications

Microstructured fluids: Structure, diffusion and rheology of colloidal dispersions

Thanh Huy Phung、John F. Brady1992-01-01AIP conference proceedings

The behavior of concentrated Brownian suspensions in a linear shear flow is studied numerically. Particle trajectories are calculated by Stokesian dynamics, a molecular‐dynamics‐like method that accurately represents the suspension hydrodynamics, including both many‐body interactions and lubrication. The simulations a…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsRheology and Fluid Dynamics Studies