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Crystal optical studies of precursor and spontaneous polarization inPbTiO3

W. Kleemann、F. J. Schäfer、Daniel Rytz1986-12-01Physical review. B, Condensed matter

High-resolution measurements of the cubic refractive index (RI) of ${\mathrm{PbTiO}}_{3}$ reveal contributions due to the fluctuating polarization, which attains about 14% of the spontaneous polarization at ${T}_{c}$=769 K. In the tetragonal phase the anomalies of both RI's are shown to be negative with nearly equal a…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsOptical and Acousto-Optic Technologies

Crystal structure and cation distribution in freibergite and tetrahedrite

R. C. Peterson、I. J. Miller1986-12-01Mineralogical Magazine

Abstract The crystal structure of a freibergite (Ag-tetrahedrite) from Keno Hill, Yukon, Canada, and a tetrahedrite from Turquetil Lake, NWT, Canada, have been refined. The freibergite, Cu 5.84 Ag 4.22 Fe 1.59 Zn 0.43 Sb 4.10 AS 0.13 S 13 , a = 10.610(2) Å, and the tetrahedrite, Cu 10.24 Fe 1.03 Zn 0.97 Ag 0.05 Sb 3.6…

Crystal Structures and PropertiesX-ray Diffraction in CrystallographyMineralogy and Gemology Studies

Benzyl esters of optically active malic acid stereocopolymers as obtained by ring‐opening polymerization of (R)‐(+) and (S)‐(‐)‐benzyl malolactonates

Ph. Guérin、J. Francillette、Christian Braud 等 4 位作者1986-12-01Makromolekulare Chemie Macromolecular Symposia

Abstract (R)‐(+) and (S)‐(‐)‐benzyl malolactonates were copolymerized anionically by using triethylamine and aluminum porphyrin as initiators. Configurational composition of resulting optically active poly(benzyl β‐malate) stereocopolymers depends on the enantiomeric purity in the monomer feed. Stereochemistry during…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistrySynthetic Organic Chemistry Methods

Synthesis and x-ray structure of the [HNi38(CO)42C6]5- cluster: an extended fragment of the Cr23C6 lattice stabilized in a molecular carbonyl nickel cluster

Alessandro Ceriotti、Anna Fait、Giuliano Longoni 等 8 位作者1986-12-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and x-ray structure of the [HNi38(CO)42C6]5- cluster: an extended fragment of the Cr23C6 lattice stabilized in a molecular carbonyl nickel clusterAlessandro. Ceriotti, Anna. Fait, Giuliano. Longoni, Giampietro. Piro, Francesco. Demartin, Mario. Manassero, Norberto.…

Organometallic Complex Synthesis and CatalysisNanocluster Synthesis and ApplicationsInorganic Chemistry and Materials

Diffusion of Hydrogen Defects in BaTiO3 Ceramics and SrTiO3 Single Crystals

Rainer Waser1986-12-01Berichte der Bunsengesellschaft für physikalische Chemie

Abstract The deuteron diffusion in acceptor‐doped barium titanate ceramics is studied as a function of the dopant concentration (0 to 1.0 mol% Ni) using a thermal desorption technique. The 0.1 mol% Ni‐doped sample shows a diffusion coefficient D = 290 cm 2 s −1 · exp(‐151 kj mol −1 / RT ). The dopant concentration has…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Measurement of the surface free energy of calcium-montmorillonite

P. Chassin、C. Jounay、Hervé Quiquampoix1986-12-01Clay Minerals

Abstract The surface free energy of Ca-montmorillonite has been determined from measurement of the contact angle of water on an oriented deposit immersed in n -alkanes; the oriented deposits were equilibrated at different relative humidities. These experiments provided the polar, γ S P , and dispersive, γ S D , compon…

Surface Modification and SuperhydrophobicityPolymer Nanocomposites and PropertiesSoil and Unsaturated Flow

Memory of spin polarization in triplet-doublet systems

Takashi Imamura、Osamu Onitsuka、Kinichi Obi1986-12-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEArticleNEXTMemory of spin polarization in triplet-doublet systemsTakashi Imamura, Osamu Onitsuka, and Kinichi ObiCite this: J. Phys. Chem. 1986, 90, 26, 6741–6744Publication Date (Print):December 1, 1986Publication History Published online1 May 2002Published inissue 1 December 1986https://…

Advanced Chemical Physics StudiesQuantum and electron transport phenomenaMagnetism in coordination complexes

Physical Properties of Some Chiral Smectic Liquid Crystals Having 1-Methyl-Alkoxy-Phenyl Group

T. Inukai、Shinichi Saitoh、H. Inoue 等 6 位作者1986-12-01Molecular crystals and liquid crystals

The liquid crystalline compounds having an optically active 1-methyl-alkoxy-phenyl group were synthesized. They show some abnormality, i.e., firstly rather high value of spontaneous polarization for the structural feature lacking a strongly polar group, in the vicinity of the chiral center, and secondly the sense of t…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesMolecular spectroscopy and chirality

Influence of nitrogen addition on microstructure and pitting corrosion resistance of austenitic weld metals

U. Kamachi Mudali、R.K. Dayal、T. P. S. Gill 等 4 位作者1986-12-01Materials and Corrosion

Abstract A study to investigate the role of nitrogen in improving the pitting corrosion resistance of types 316 and 304 stainless steel weld metals has been attempted. Weld metals were prepared by autogenous TIG welding process with argon‐nitrogen mixture as the shielding gas. Delta‐ferrite measurements, made with Mag…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

Evidence that heme d1 is a 1,3-porphyrindione

Chi K. Chang、R. Timkovich、Weishih Wu1986-12-01Biochemistry

Heme d1 is the noncovalently associated heme prosthetic group of the bacterial nitrite reductase known as cytochrome cd1. Additional evidence has been obtained in support of a dioxoisobacteriochlorin, or 1,3-porphyrindione, skeleton for this heme. The new data include the natural abundance 13C NMR spectrum of the free…

Porphyrin and Phthalocyanine ChemistryHeme Oxygenase-1 and Carbon MonoxideNeonatal Health and Biochemistry

Heterolytic and homolytic oxygen-oxygen bond cleavage reactions of acylperoxomanganese(III) porphyrins

John T. Groves、Yoshihito Watanabe1986-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHeterolytic and homolytic oxygen-oxygen bond cleavage reactions of acylperoxomanganese(III) porphyrinsJohn T. Groves and Yoshihito WatanabeCite this: Inorg. Chem. 1986, 25, 27, 4808–4810Publication Date (Print):December 1, 1986Publication History Published online1 May 2002Pu…

Porphyrin and Phthalocyanine ChemistryOxidative Organic Chemistry ReactionsOrganic Chemistry Cycloaddition Reactions

Lyotropic mesophase of imogolite, 1. Effect of polydispersity on phase diagram

Kanji Kajiwara、Nobuo Donkai、Yuzuru Hiragi 等 4 位作者1986-12-01Die Makromolekulare Chemie

Abstract The acidic aqueous solution of imogolite is proposed to be an ideal lyotropic system. No temperature dependence was marked on the two phase boundary concentrations (A and B points) of imogolite solutions as predicted by the theories of Flory and Onsager. A satisfactory quantitative agreement was observed with…

Soil and Unsaturated FlowClay minerals and soil interactionsAdsorption, diffusion, and thermodynamic properties of materials

Effect of Fiber Anisotropy on Thermal Stresses in Fibrous Composites

William B. Avery、Carl T. Herakovich1986-12-01Journal of Applied Mechanics

An elasticity solution is utilized to analyze an orthotropic fiber in an isotropic matrix under uniform thermal load. The analysis reveals that stress distributions in the fiber are singular in the radial coordinate when the radial fiber stiffness (Crr) is greater than the hoop stiffness (Cθθ). Conversely, if Crr <…

Mechanical Behavior of CompositesTextile materials and evaluationsVibration and Dynamic Analysis

The Nature of the Oil Phase and the Release of Solutes from Multiple (w/o/w) Emulsions

James A Omotosho、Tony L. Whateley、T.K. Law 等 4 位作者1986-12-01Journal of Pharmacy and Pharmacology

The effect of the nature of the oil phase of w/o/w emulsions stabilized by interfacial complexation between span 80 (sorbitan mono-oleate) and albumin has been studied. The long-term stability of the systems has been assessed by photomicrography and by measuring the quantity of an internal marker (NaCl) remaining entr…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Tilt-angle, polarization, and heat-capacity measurements near the smectic-A–chiral-smectic-Cphase transition ofp-(n-decyloxybenzylidene)-p-amino-(2-methylbutyl)cinnamate (DOBAMBC)

S. Dumrongrattana、C. C. Huang、George Nounesis 等 5 位作者1986-12-01Physical Review A

High-resolution heat-capacity, tilt-angle, and polarization measurements have been carried out in the vicinity of the smectic-A (SmA) --chiral-smectic-C (Sm${C}^{\mathrm{*}}$) phase transition of p-(n-decyloxybenzylidene)-p-amino-(2-methylbutyl)cinnamate (DOBAMBC). Heat-capacity studies were done on two different samp…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesMolecular spectroscopy and chirality

A Mechanical Model for the Lateral Compression of Woven Fabrics

S. De Jong、J.W. Snaith、N. A. Michie1986-12-01Textile Research Journal

A mechanical model for the lateral compression of woven fabrics is derived from Van Wyk's compression law for fiber assemblies. The pressure ( P) and thickness (v) relationship is P = a/( v - v')3. The parameter v' refers to the core of the fabric, which is incompressible over the pressure range 2-5000 gf/cm 2 . The p…

Mechanical Behavior of CompositesTextile materials and evaluationsStructural Analysis and Optimization

Computer simulation of twin boundaries in the h.c.p. metals

A. Serra、David Bacon1986-12-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

The energy and atomic structure of {1121}, {1122) and {1012} twin boundaries in the hexagonal-close-packed (h.c.p.) metals have been investigated using computer simulation. Three distinctly different interatomic potential functions have been used in either equilibrium or non-equilibrium form. It is predicted that only…

Magnesium Alloys: Properties and ApplicationsIntermetallics and Advanced Alloy PropertiesQuasicrystal Structures and Properties

Comparison of the contrast-enhancing properties of albumin-(Gd-DTPA) and Gd-DTPA at 2.0 T: and experimental study in rats

Udo P. Schmiedl、M. Ogan、M. P. Moseley 等 4 位作者1986-12-01American Journal of Roentgenology

Albumin-(gadolinium-diethylenetriaminepentaacetic acid), albumin-(Gd-DTPA), a macromolecular MR contrast agent designed for intravascular distribution, was compared with gadolinium-diethylenetriaminepentaacetic acid (Gd-DTPA), an extracellular fluid agent, for imaging characteristics in normal rats at 2.0 T. Albumin-(…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

An Introduction to Nuclear Reactor Theory

Efstathios E. Michaelides1986-12-01Nuclear Technology

"An Introduction to Nuclear Reactor Theory." Nuclear Technology, 75(3), p. 378

Nuclear reactor physics and engineeringGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies