Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTransparent metals preparation and characterization of light-transmitting platinum filmsA. Heller, D. E. Aspnes, J. D. Porter, T. T. Sheng, and R. G. VadimskyCite this: J. Phys. Chem. 1985, 89, 21, 4444–4452Publication Date (Print):October 1, 1985Publication History Publishe…
The measurement of volume charges within insulators has been attempted by various methods, including thermal, optical, mechanical, and electrical stimulation of the sample. A new method incorporating pulse electrical stimulation and pulsed acoustic detection is reported here. This technique is an extension of a previo…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTetrakis(1,3-dithiol-2-ylidene)cyclobutane: a novel and promising electron donor for organic metalsToyonari Sugimoto, Hiroshi Awaji, Yohji Misaki, Zenichi Yoshida, Yasushi Kai, Hajime Nakagawa, and Nobutami KasaiCite this: J. Am. Chem. Soc. 1985, 107, 20, 5792–5793Publicatio…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPseudorotational mechanism for the inversion of 10-Si-5 siliconates: ligand structure and reactivityWilliam H. Stevenson III, Scott Wilson, J. C. Martin, and William B. FarnhamCite this: J. Am. Chem. Soc. 1985, 107, 22, 6340–6352Publication Date (Print):October 1, 1985Public…
PROLOGUE Computers influence our lives in more ways than we care to admit, and simulation or modeling is just one facet of a vast activity that will inevitably continue to grow even larger. Nowadays, computer simulation is used routinely in fields as diverse as econometrics and meteorology. The successes that have bee…
Abstract Cellulose fibers treated with different coupling agents based on trichloro‐ s ‐triazine have been evaluated in terms of their reinforcement effect on unsaturated polyesters. The treatment with coupling agents containing double bonds resulted in what we believe to be the formation of covalent bonds between fib…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMorphology and ionic conductivity of polymer complexes formed by segmented polyether poly(urethane urea) and lithium perchlorateMasayoshi Watanabe, Shinichiro Oohashi, Kohei Sanui, Naoya Ogata, Tadahiko Kobayashi, and Zentaro OhtakiCite this: Macromolecules 1985, 18, 10, 194…
Machine simulations and effective-medium theories are used to examine the influence of transverse (i.e., noncentral) forces on the elastic percolation transition in two dimensions. We consider models in which the transverse forces arise from (1) contact interactions between pairs of macroscopic particles and (2) bond-…
Thermodynamic calculations have been used to construct time temperature sensitization (TTS) diagrams for AISI 304 stainless steels (SS). The quantitative Stawstrom and Hillert model, which is based on chromium diffusion control of sensitization, was used to calculate the TTS diagrams. Electrochemical potentiokinetic r…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNovel structural modulation in the ambient-pressure sulfur-based organic superconductor .beta.-(BEDT-TTF)2I3: origin and effects on its electrical conductivityPeter C. W. Leung, Thomas J. Emge, Mark A. Beno, Hau H. Wang, Jack M. Williams, Vaclav Petricek, and Philip CoppensC…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTriangular platinum and nickel clusters: the "tinker-toy" construction of chains with high nuclearityDennis J. Underwood, Roald Hoffmann, Kazuyuki Tatsumi, Akira Nakamura, and Yasuhiro YamamotoCite this: J. Am. Chem. Soc. 1985, 107, 21, 5968–5980Publication Date (Print):Octo…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRole of the intermolecular interactions in the two-dimensional ambient-pressure organic superconductors .beta.-(ET)2I3 and .beta.-(ET)2IBr2Myung Hwan Whangbo, Jack M. Williams, Peter C. W. Leung, Mark A. Beno, Thomas J. Emge, and Hau H. WangCite this: Inorg. Chem. 1985, 24,…
The coupled-cluster or exp S formalism, where the wave operator is expressed in exponential form, is treated for a general, multi-Configurational model space. It is shown that the cluster operator, S , is rigorously connected when the model space is complete or "quasi-complete" in the sense that it contains all config…
The following is a discussion of the article entitled “The Existence of Imidazoline Corrosion Inhibitors,” by J. A. Martin and F. W. Valone, published in Corrosion, Vol. 41, No. 5, p. 281, 1985.
Breakdown of SF6is of commercial interest as a result of the large amounts of SF6-insulated switchgear installed world wide and is of technical interest as a result of the excellent dielectric strength of the gas caused by its high electronegativity. Previous studies in the area of positive surge breakdown area have c…
ADVERTISEMENT RETURN TO ISSUEPREVArticleVibrational study of the dynamics of n-alkylammonium chains in the perovskite-type layer compounds (CnH2n+1NH3)2CdCl4 (n = 8, 12, 16)L. Ricard, R. Cavagnat, and M. Rey-LafonCite this: J. Phys. Chem. 1985, 89, 22, 4887–4894Publication Date (Print):October 1, 1985Publication Histo…
Abstract Studies on the effect of nitrogen plasma on morphology and textile properties of mulberry silk fibers and fabrics have been conducted. The changes in the morphological structure have been monitored by transmission electron microscopy, X‐ray diffraction, and internal reflection infrared spectroscopy. The chang…
Single-crystal neutron diffraction has been used to observe the interactions between deuterated ethanol (CD3CD2OH) and lysozyme in triclinic crystals of hen egg white lysozyme soaked in 25% (v/v) ethanol solutions. A total of 6047 observed reflections to a resolution of 2 A were used, and 13 possible ethanol sites wer…
Abstract The complex degradation behavior of a poly(vinyl chloride) (PVC) cable jacketing material in combined radiation/temperature/air aging environments is experimentally separated into two dominant radiation dose‐rate effect mechanisms. The first, operative at high dose rates, involves diffusion‐limited oxidation,…
Ultrasonic determinations were made of facial tissue thicknesses in 50 healthy American caucasoid children, ranging in age from 4 to 15. Twenty measurements were taken at sites along the median, right sagittal, and right lateral planes. A static scanner was used in the B-mode. Three measurements significantly increase…