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Preparation and Characterization of a Cocrystalline Suspension of [LysB28,ProB29]-Human Insulin Analogue

Michael R. DeFelippis、Diane L. Bakaysa、Maureen A. Bell 等 9 位作者1998-02-01Journal of Pharmaceutical Sciences

Soluble preparations of [LysB28,ProB29]-human insulin analogue (LysPro) exhibit more rapid absorption than human insulin upon subcutaneous injection. Biphasic mixtures of LysPro and intermediate-acting insulin suspensions could provide advantages over current preparations for the treatment of diabetes. To prepare biph…

Protein Structure and DynamicsEnzyme Structure and FunctionHemoglobin structure and function

A new recycling system for expanded polystyrene using a natural solvent. Part 2. Development of a prototype production system

Tsutomu Noguchi、Yasuhito Inagaki、Mayumi Miyashita 等 4 位作者1998-02-01Packaging Technology and Science

A prototype production system for recycling expanded polystyrene (EPS), which uses an orange oil, d-limonene, as the EPS shrinking agent, has been developed. This system consists of an apparatus to dissolve EPS and a recycling plant to separate the limonene solution. The recycling plant can mass reproduce polystyrene…

biodegradable polymer synthesis and properties

Electrokinetic Behavior and Stability of Silicon Carbide Nanoparticulate Dispersions

Pedro Tartaj、Michael J. Reece、José S. Moya1998-02-01Journal of the American Ceramic Society

The stability of aqueous suspensions containing SiC nanoparticles prepared by inductively coupled plasma has been studied. Physicochemical analyses indicated that the as‐prepared samples consisted of monocrystalline spherical particles of the 3C‐SiC polytype with a mean diameter of about 40 nm. HRTEM clearly showed th…

Advanced ceramic materials synthesisDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Three solutions of the protein solubility problem

W. Terry Jenkins1998-02-01Protein Science

Three simple equations are presented, which describe the variation of protein solubility (S) with changes in salt concentration, in terms of either the salt molality (M), the salt activity (ax), or the water activity (aw). Each equation yields, essentially independent, estimates of the numbers of salt ions (delta vx)…

Analytical Chemistry and ChromatographyProtein purification and stabilityCrystallization and Solubility Studies

Monte Carlo simulation of the kinetics of protein adsorption

Vladimir P. Zhdanov、B. Kasemo1998-02-01Proteins Structure Function and Bioinformatics

Adsorption of proteins occurs via diffusion toward the interface, actual adsorption, and subsequent irreversible conformational changes resulting in denaturation of the native protein structure. The conventional kinetic models describing these steps are based on the assumption that the denaturation transitions obey th…

Protein Structure and DynamicsMaterial Dynamics and PropertiesPolymer Surface Interaction Studies

Piezoelectricity in ferroelectric thin films: Domain and stress issues

Susan Trolier‐McKinstry、J. Shepard、J. Lacey 等 6 位作者1998-02-01Ferroelectrics

As ferroelectric thin films are investigated as alternative sensors and actuators for microelectromechanical systems, it is becoming important to understand which mechanisms control the magnitude of the observed piezoelectric properties. It is well known that in bulk soft lead zirconate titanate actuators, over half t…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

The Transformation of Illite to Muscovite in Pelitic Rocks: Constraints from X-Ray Diffraction

Mohamed Gharrabi、B. Velde、Jean Paul Sagon1998-02-01Clays and Clay Minerals

Abstract The boundary between diagenesis and metamorphism most likely involves the change of illite into mica. Observations of this change can be made using decomposed X-ray diffraction (XRD) spectra of illitic clay mineral assemblages in pelitic sedimentary rocks. XRD analysis of the (003) diffraction peak of diagene…

Geological and Geochemical AnalysisSoil and Unsaturated FlowClay minerals and soil interactions

Twisting power of bridged binaphthol derivatives: comparison of theory and experiment

Alberta Ferrarini、P. L. Nordio、Petr Shibaev 等 4 位作者1998-02-01Liquid Crystals

The twisting ability of a novel series of bridged binaphthol derivatives with substituents of various lengths and chemical nature in the 6,6-positions, recently synthesized and used as dopants in nematic solvents, is investigated with the help of the model based upon surface- helicity tensors. Structures of the low en…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsMolecular spectroscopy and chirality

On the form IV of syndiotactic polypropylene

Finizia Auriemma、Claudio De Rosa、Odda Ruiz de Ballesteros 等 5 位作者1998-02-01Journal of Polymer Science Part B Polymer Physics

The packing of the chains in (T6G2T2G2)n conformation of the form IV of s-PP is revisited on the basis of packing energy and structure factor calculations. According to this analysis, an alternative mode of packing has been suggested. A monoclinic structural model, with the unit cell centered on the C face, is obtaine…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Nature of atomic ordering and mechanism of relaxor ferroelectric phenomena in PMN

T. Egami、Wojciech Dmowski、S. Teslic 等 6 位作者1998-02-01Ferroelectrics

Small angle resonant x-ray scattering measurements were performed for Pb(Mg1/3Nb2/3)O3 (PMN) at the Pb and Nb absorption edges using synchrotron radiation. The results are not consistent with the current model of segregated nano-domains and pose a serious question on the mechanism of the relaxor ferroelectric behavior…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Molecular dynamics simulation of the dynamics of supercooled silica

Jürgen Horbach、Walter Kob、Kurt Binder1998-02-01Philosophical Magazine B

We present the results of a large-scale computer simulation of supercooled silica. We find that at high temperatures the diffusion constants show a non-Arrhenius temperature dependence, whereas at low temperature this dependence is compatible with an Arrhenius law. We demonstrate that at low temperatures the intermedi…

Material Dynamics and PropertiesGlass properties and applicationsTheoretical and Computational Physics

Gastroprotective activity of the stem bark ofAmphipterygium adstringens in rats

Andrés Navarrete、L. S. Martínez-Uribe、Beverly A.S. Reyes1998-02-01Phytotherapy Research

The methanol extract of the stem bark of Amphipterygium adstringens (Julianiaceae) showed a dose-dependent inhibitory effect on ethanol-induced gastric ulcers in rats. Fractionation of this extract, guided by gastroprotective activity in rats, led to four active fractions rich in triterpenoid compounds. These fraction…

Helicobacter pylori-related gastroenterology studiesNatural product bioactivities and synthesisPhytochemistry and Bioactive Compounds

Experimental evidence for a continuous phase transition in a multidimensional ferroelectric

P. Czarnecki、Andrzej Katrusiak、I. Szafraniak 等 4 位作者1998-02-01Physical review. B, Condensed matter

Two phase transitions in ferroelectric crystals of pyridinium tetrafluoroborate ${[\mathrm{C}}_{5}{\mathrm{H}}_{6}{\mathrm{N}]}^{+}{\mathrm{BF}}_{4}^{\mathrm{\ensuremath{-}}}$ have been characterized by x-ray- and neutron-diffraction studies and measurements of permittivity, pyroeffect, and spontaneous polarization. A…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Influence of Thermal and Electrical Histories on Domain Structure and Polarization Switching in Potassium‐Modified Lead Zirconate Titanate Ceramics

Qi Tan、D. Viehland1998-02-01Journal of the American Ceramic Society

The dependence of domain evolution and polarization switching on thermal and electrical histories has been investigated for K 1+ ‐ion‐modified lead zirconate titanate (PZT) ceramics by using hot‐stage transmission electron microscopy and Sawyer—Tower polarization methods. In each case, the domains were very narrow, on…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsPhase-change materials and chalcogenides

Electrical resistivity and Seebeck coefficient of hot-pressed YbAl3 over the temperature range 150-700K

D.M. Rowe、Gao Min、L. Kuznestsov1998-02-01Philosophical Magazine Letters

YbAl specimens were prepared using a hot-pressing technique and the 3 Seebeck coefficient and electrical resistivity measured over the temperature range 150-700 K in order to assess their potential as thermoelectric materials. The preliminary results show that YbAl possesses an electrical power factor 3 double those o…

Physics of Superconductivity and MagnetismAdvanced Thermoelectric Materials and DevicesThermodynamic and Structural Properties of Metals and Alloys

Active/Passive Behavior of Copper in Strong Sulfuric Acid

Desmond Tromans、Tawfik Ahmed1998-02-01Journal of The Electrochemical Society

A combination of thermodynamic analyses and potentiodynamic polarization tests have been used to study the anodic behavior of Cu in strong solutions in the concentration range 1–10 M. The studies were supplemented by chemical analyses of surface films. It was found that concentration‐dependent changes in the activity…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityAnodic Oxide Films and Nanostructures

Lithium Bis[5‐fluoro‐2‐olato‐1‐benzenesulfonato (2‐)‐O,O′]borate(1‐), a New Anodically and Cathodically Stable Salt for Electrolytes of Lithium‐Ion Cells

J. Barthel、Michael Schmidt、H. J. Gores1998-02-01Journal of The Electrochemical Society

Synthesis, characterization, and electrochemical investigations of lithium bis[5‐fluoro‐2‐olato‐1‐benzenesulfonato(2‐)‐O,O′] borate(1‐), a new salt for lithium‐ion cells in ethylene carbonate (EC)‐dimethylcarbonate (DMC) mixtures are presented. At platinum electrodes the anodic oxidation limit is about 4.6 V, in good…

Advanced Battery Materials and TechnologiesConducting polymers and applicationsPolyoxometalates: Synthesis and Applications

DSC studies on the crystallization characteristics of poly(ethylene terephthalate) for blow molding applications

Daw‐Ming Fann、Steve K. Huang、Jiunn‐Yih Lee1998-02-01Polymer Engineering and Science

Abstract The crystallization behavior of blow‐molded PET bottles, which helps determine the product's transparency, was investigated by DSC dynamic cooling experiments that simulated the cooling that occurs in the injection blow‐molding manufacturing process. Dynamic cooling crystallization of PET optimized the condit…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesInjection Molding Process and Properties

Effects of 1,2 Dichloroethane Addition on the Optimal Silver Catalyst Distribution in Pellets for Epoxidation of Ethylene

King Lun Yeung、Asterios Gavriilidis、Arvind Varma 等 4 位作者1998-02-01Journal of Catalysis

The issue of optimal catalyst distribution was studied experimentally for the ethylene epoxidation reaction network on a Ag/α-Al2O3catalyst in the presence of 1,2-dichloroethane (DCE). For a fixed amount of silver, the influence of location and width of the catalytic layer on the conversion of ethylene, and on the sel…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsCatalysis and Oxidation Reactions

Micromechanical deformation processes in toughened PP/PA/SEBS-g-MA blends prepared by reactive processing

Gyeong-Eun Kim、Goerg H. Michler、Joachim Rösch 等 4 位作者1998-02-01Acta Polymerica

Toughening mechanisms occurring in PP/PA6 (70 vol.-%/30 vol.-%) blends containing various amounts of SEBS-g-MA have been studied by in situ straining in a high voltage electron microscope (HVEM). Variation of volume fraction of compatibilizer (SEBS-g-MA) with constant PA6 content and reactive processing conditions giv…

Mechanical Behavior of CompositesPolymer crystallization and propertiesElectronic Packaging and Soldering Technologies