Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInterlamellar covalent grafting of organic units on kaoliniteJames J. Tunney and Christian DetellierCite this: Chem. Mater. 1993, 5, 6, 747–748Publication Date (Print):June 1, 1993Publication History Published online1 May 2002Published inissue 1 June 1993https://doi.org/10.1…
Numerical evidence is presented that shows that, for metallic lamellar gratings in TM polarization, the coupled-wave method formulated by Moharam and Gaylord [ J. Opt. Soc. Am. A3, 1780 ( 1986)] converges slowly. (In some cases, for achieving a relative error of less than 1% in diffraction efficiencies, the number of…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrochemical applications of the bending beam method. 2. Electroshrinking and slow relaxation in polypyrroleQibing Pei and Olle InganaesCite this: J. Phys. Chem. 1993, 97, 22, 6034–6041Publication Date (Print):June 1, 1993Publication History Published online1 May 2002Publ…
Solid nematic liquids, formed by cross-linking polymer liquid crystals into elastomers, are shown to display novel and complex elasticity. The internal (nematic) direction suffers a barrier to its rotation and this couples to standard elasticity. By considering imposed strains we illuminate this elasticity and also de…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation and characterization of ceria under an oxidizing atmosphere. Thermal analysis, XPS, and EPR studyEdmond Abi-aad, Rafeh Bechara, Jean Grimblot, and Antoine AboukaisCite this: Chem. Mater. 1993, 5, 6, 793–797Publication Date (Print):June 1, 1993Publication History…
Abstract Among the nonmetal nitrides, the polymeric binary compounds BN and Si 3 N 4 are of particular interest for the development of materials for high‐performance applications. The outstanding features of both substances are their thermal, mechanical, and chemical stability, coupled with their low density. Because…
Acetoin is a major extracellular product of Bacillus subtilis grown on glucose and other fermentable carbon sources. The enzymes responsible for the formation of acetoin, acetolactate synthase, and acetolactate decarboxylase are synthesized in detectable amounts only in cells that have reached stationary phase. We hav…
A method to determine the absorption coefficient near the onset of core-electron transitions for concentrated samples using fluorescence-yield (FY) detection is presented. Measuring the FY signal for different experimental geometries, we are able to calculate the true absorption coefficient. Thus we are able to correc…
ceramics were synthesized and their ionic conduction was investigated. These ceramics showed protonic and oxide ionic mixed conduction under fuel cell condition. While protonic conduction was predominant below 1027 K, oxide ionic conduction became significant as the temperature increased. Using these oxides as solid e…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructural, thermal, and electrical characterization of layered nanocomposites derived from sodium-montmorillonite and polyethersJinghe Wu and Michael M. LernerCite this: Chem. Mater. 1993, 5, 6, 835–838Publication Date (Print):June 1, 1993Publication History Published onlin…
Measurements on the thermal conductivity of natural and synthetic single-crystal diamond are presented over a wide temperature range. The large isotope effect reported previously has been confirmed. The data have been analyzed using both the Debye model of thermal conductivity, which ignores the N processes, and the C…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTXPS studies of the oxygen 1s and 2s levels in a wide range of functional polymersDavid. Briggs and Graham. BeamsonCite this: Anal. Chem. 1993, 65, 11, 1517–1523Publication Date (Print):June 1, 1993Publication History Published online1 May 2002Published inissue 1 June 1993htt…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure of grafted polymeric brushes in solvents of varying quality: a molecular dynamics studyGary S. Grest and Michael MuratCite this: Macromolecules 1993, 26, 12, 3108–3117Publication Date (Print):June 1, 1993Publication History Published online1 May 2002Published iniss…
CeO 2 powders have been prepared by aging a cerium(III) nitrate solution in the presence of hexamethylenetetramine. Oxidation of Ce 3+ occurs in the precipitate and the wet precipitate is identified as crystallized CeO 2 before any heat treatment. The cold‐pressed powders can be sintered to full density at temperature…
We cloned an operon, copAB, from Enterococcus hirae encoding two P-type ATPases of 727 and 745 amino acids, respectively. Both enzymes display heavy metal ion binding motifs in their polar N-terminal region. With an antibody against CopB, we showed on Western blots that expression of the operon is induced by either lo…
Local icosahedral order is found to increase as random hard-sphere packings (one- and two-component) generated on the computer are densified from the (recently established) ``loose random-packing'' limit to the ``dense random-packing'' limit. While icosahedral ordering in ``atomic'' systems is frequently ascribed to t…
Abstract Nylon 6–clay hybrid is a molecular composite of nylon 6 and uniformly dispersed silicate layers of montmorillonite. One‐pot synthesis of the hybrid was carried out by the following procedures. Montmorillonite was dispersed in water, and then ε‐caprolactam, acid (phosphoric acid, hydrochloric acid, benzenesulf…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHydrolysis of tri-tert-butylaluminum: the first structural characterization of alkylalumoxanes [(R2Al)2O]n and (RAlO)nMark R. Mason, Janna M. Smith, Simon G. Bott, and Andrew R. BarronCite this: J. Am. Chem. Soc. 1993, 115, 12, 4971–4984Publication Date (Print):June 1, 1993P…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSelf-aggregates of hydrophobized polysaccharides in water. Formation and characteristics of nanoparticlesKazunari Akiyoshi, Shigeru Deguchi, Nobuhiro Moriguchi, Shigehiko Yamaguchi, and Junzo SunamotoCite this: Macromolecules 1993, 26, 12, 3062–3068Publication Date (Print):J…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSelf-orienting head-to-tail poly(3-alkylthiophenes): new insights on structure-property relationships in conducting polymersRichard D. McCullough, Stephanie Tristram-Nagle, Shawn P. Williams, Renae D. Lowe, and Manikandan JayaramanCite this: J. Am. Chem. Soc. 1993, 115, 11,…