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NrdH‐redoxin of Corynebacterium ammoniagenes forms a domain‐swapped dimer

Matthias Stehr、Ylva Lindqvist2004-04-01Proteins Structure Function and Bioinformatics

NrdH-redoxins constitute a family of small redox proteins, which contain a conserved CXXC sequence motif, and are characterized by a glutaredoxin-like amino acid sequence but a thioredoxin-like activity profile. Here we report the structure of Corynebacterium ammoniagenes NrdH at 2.7 A resolution, determined by molecu…

Protein Structure and DynamicsEnzyme Structure and FunctionRedox biology and oxidative stress

Variscite (AlPO4 2H2O) from Cioclovina Cave (Sureanu Mountains, Romania): a tale of a missing phosphate

Bogdan P. Onac、Joe Kearns、Radu Breban 等 4 位作者2004-04-01Studia Universitatis Babes-Bolyai Geologia

Recent investigations on a phosphatized sediment sequence in the Cioclovina Cave led to the identification of a second occurrence in Romania (first time in the cave environment) of variscite, AlPO4·2H2O. The mineral exists as dull-white, tiny crusts and veinlets within the thick argillaceous material accumulated on th…

Crystal Structures and PropertiesClay minerals and soil interactionsChemical Synthesis and Characterization

Anionic dicyanamide frameworks as possible components of multifunctional materials

John A. Schlueter、U. Geiser、Jamie L. Manson2004-04-01Journal de Physique IV (Proceedings)

The dicyanamide anion, [N(CN) 2 ] - (hereafter abbreviated dca), has been shown to be a versatile building block for the assembly of coordination polymers which are components of molecular superconductors, magnets and conducting/magnetic hybrid materials. Significantly different anion topologies have been observed. We…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesOrganic and Molecular Conductors Research

Anisotropic shear viscosity in nematic liquid crystals: new optical measurement method

S. V. Pasechnik、Vladimir G. Chigrinov、D. V. Shmeliova 等 5 位作者2004-04-01Liquid Crystals

We propose a new optical method and the experimental set-up for measuring the anisotropic shear viscosities of nematic liquid crystals (LCs). LC shear viscosities can be optimized to improve liquid crystal display (LCD) response times, e.g. in vertical aligned nematic (VAN) or bistable nematic displays (BND). In this…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPlant Reproductive Biology

Self‐Propagating High‐Temperature Synthesis of α‐SiAlON Doped by RE (RE=Eu,Pr,Ce) and Codoped by RE and Yttrium

Jiuxin Jiang、Peilin Wang、Wan-Bao He 等 7 位作者2004-04-01Journal of the American Ceramic Society

Self‐propagating high‐temperature synthesis (SHS) was applied to synthesize α‐SiAlON powders doped by RE (RE = Eu,Pr,Ce) and codoped by RE and yttrium. The results showed that the weight ratio of α‐SiAlON to (α‐SiAlON +β‐SiAlON) decreased from 70%, 55%, and 25% for europium‐, praseodymium‐, and cerium‐doped α‐SiAlON c…

Advanced ceramic materials synthesisIntermetallics and Advanced Alloy PropertiesAdvanced materials and composites

Application of ultrafine-dispersed diamonds in electroplating

G. K. Burkat、V. Yu. Dolmatov2004-04-01Physics of the Solid State

The results obtained upon the electrochemical deposition of composite coatings containing ultrafine-dispersed diamonds produced by detonation synthesis are generalized. The main advantages of such coatings over the well-known composite electrochemical coatings are revealed.

Diamond and Carbon-based Materials ResearchLubricants and Their AdditivesAdvanced Materials Characterization Techniques

Unmanned aerial vehicles spur composites use

John K. Borchardt2004-04-01Reinforced Plastics

Unmanned aerial vehicles or UAVs are of growing interest to military operations, but they can also be used in a variety of civilian applications such as monitoring and controlling traffic flow and search/rescue operations. John K. Borchardt reviews some of the latest composites-intensive UAV projects.

Additive Manufacturing and 3D Printing TechnologiesInnovations in Concrete and Construction MaterialsMaterial Properties and Applications

Complex behaviour of a simple partial-discharge model

Hideyuki Suzuki、Kazuyuki Aihara、Tatsuki Okamoto2004-04-01Europhysics Letters (EPL)

We examine the most simple and deterministic model of partial-discharge phenomena, or the three-capacitance equivalent circuit model with fixed parameter values. Although it is an old model proposed more than fifty years ago, here we show that its behaviour should be described with contemporary concepts of nonlinear d…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Influence of charge order on the ground states of TMTTF molecular salts

Weiqiang Yu、F. Zámborszky、B. Alavi 等 6 位作者2004-04-01Journal de Physique IV (Proceedings)

(TMTTF)2AsF6 and (TMTTF)2SbF6 are both known to undergo a charge ordering phase transition, though their ground states are different. The ground state of the first is Spin-Peierls, and the second is an antiferromagnet. We study the effect of pressure on the ground states and the charge-ordering using 13C NMR spectrosc…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchInorganic Fluorides and Related Compounds

Observation in the Growth of Selenium Nanoparticles

Zong‐Hong Lin、Fu‐Chu Lin、C. R. Chris Wang2004-04-01Journal of the Chinese Chemical Society

Abstract A mild chemical reduction method was developed to synthesize selenium nanoparticles. The observation of the particle growth within a five‐minute time frame at an elevated temperature is achieved, and it was evidenced by analyzing the particle sizes from electron micrographs. The samples at individual growth s…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsSelenium in Biological Systems

Waterproof Anti Reflection Films Fabricated by Layer-by-Layer Adsorption Process

Shiro Fujita、Seimei Shiratori2004-04-01Japanese Journal of Applied Physics

To decrease light reflection from the surface of cathode-ray tube (CRT) and liquid crystal display (LCD), anti reflection (AR) technology has been investigated. In this work, we demonstrate the use of high-quality two-layer AR films (luminous reflection under 1.0) using numerous micropores to create a low-refractive-i…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesNanofabrication and Lithography Techniques

Inhibition and Growth Control of Colloidal Silica: Designed Chemical Approaches

Konstantinos D. Demadis、Eleftheria Neofotistou2004-04-01Materials Performance

Colloidal silica (SiO2) is perhaps the most undesirable inorganic deposit formed in process cooling waters, especially on metallic surfaces such as heat exchangers or pipelines. Conventional mineral scale inhibitors do not inhibit its formation. Chemical cleaning is difficult and not free of hazards. Research on silic…

Mesoporous Materials and CatalysisCatalysis and Hydrodesulfurization StudiesDendrimers and Hyperbranched Polymers

Generation of Radiation Pressure in Thermally Induced Ultrasonic Emitter Based on Nanocrystalline Silicon

Jun Hirota、Hiroyuki Shinoda、Nobuyoshi Koshida2004-04-01Japanese Journal of Applied Physics

To confirm the applicability of thermally induced ultrasonic emission from nanocrystalline silicon (nc-Si) devices as radiation pressure generators, the dynamic response has been investigated under a pulse operation mode. The nc-Si emitter is fabricated on a p-type Si wafer by conventional electrochemical anodization…

Silicon Nanostructures and PhotoluminescenceMicrofluidic and Bio-sensing TechnologiesNanowire Synthesis and Applications

Lattice dynamics of Ca4GdO(BO3)3

Mirosław Mączka、J. Hanuza、A. Paja̧czkowska 等 5 位作者2004-04-01Journal of Raman Spectroscopy

Abstract Polarized Raman and IR spectra were obtained for Ca 4 GdO(BO 3 ) 3 crystal at ambient temperature. The assignment of the observed bands to the respective internal and external phonons is proposed on the basis of lattice dynamics calculations. This study also shows that significant LO–TO splitting exists for s…

High-pressure geophysics and materialsCrystal Structures and PropertiesMineralogy and Gemology Studies

Application of the Taguchi Design for Production of Poly(β-hydroxybutyrate) by Ralstonia eutropha

Kianoush Khosravi‐Darani、E Vasheghani Faraahani、S A Shoja Alsadati2004-04-01Iranian Journal of Chemistry & Chemical Engineering-international English Edition

The Taguchi design of experiments was used to test the relative importance of medium components and environmental factors on poly(β-hydroxybutyrate)(PHB) production by Ralstonia eutropha. The optimum condition was obtained as: fructose concentration, 15 g/L; C/N ratio, 7.4; agitation speed 200 rpm; culture time, 40 h;…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Novel CVD Techniques for Micro‐ and IT‐SOFC Fabrication

Guowen Meng、Haiyan Song、Changrong Xia 等 5 位作者2004-04-01Fuel Cells

Abstract At present, there are intensive research efforts towards intermediate temperature solid oxide fuel cells (IT‐SOFCs) with a thin film electrolyte and electrode. In view of the nature of molecular level reaction and the great potential of CVD processes for IT‐SOFCs and even Micro‐SOFC fabrication, various novel…

Advancements in Solid Oxide Fuel CellsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Nonlinear Model Reduction of a Two‐Dimensional MCFC Model with Internal Reforming

M. Mangold、Min Sheng2004-04-01Fuel Cells

Abstract A reduced nonlinear model of a planar molten carbonate fuel cell is presented. The model is derived from a spatially distributed dynamic model of the cell by applying the Karhunen Loève Galerkin procedure. The reduced model is of considerably lower order than the original one and requires much less computatio…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsNonlinear Dynamics and Pattern Formation

Hyperthermophilic dehydrogenase enzymes

Jennifer A. Littlechild、Jodie E. Guy、Michail N. Isupov2004-04-01Biochemical Society Transactions

Archaeal dehydrogenases are often found to be of a specific class of dehydrogenase which has low sequence identity to the equivalent bacterial and eukaryotic counterparts. This paper focuses on two different types of hyperthermophilic dehydrogenase enzyme that have been cloned and over-expressed in Escherichia coli. T…

Genomics and Phylogenetic StudiesEnzyme Catalysis and ImmobilizationEnzyme Structure and Function

Order–disorder transition of anodic alumina nanochannel arrays grown under the guidance of focused-ion-beam patterning

C. Y. Liu、Anindya Datta、N. W. Liu 等 5 位作者2004-04-01Applied Physics Letters

By anodizing an aluminum surface that has been patterned with different guiding lattices using a focused ion beam, the resulting anodic alumina nanochannel arrays exhibit different degree of order arrangement. Long-range order is achieved only when the guiding lattice is carefully matched to that of the self-organized…

Nanopore and Nanochannel Transport StudiesAnodic Oxide Films and NanostructuresSmart Materials for Construction

Effect of Yttria and Yttrium‐Aluminum Garnet on Densification and Grain Growth of Alumina At 1200°–1300°C

Michael K. Cinibulk2004-04-01Journal of the American Ceramic Society

Densification and grain growth of alumina were studied with yttria or yttrium‐aluminum garnet (YAG) additives at the relatively low temperatures of 1200°–1300°C. Yttria doping was found to inhibit densification and grain growth of alumina at 1200°C and, depending on dopant level, had a lesser effect at 1300°C. At 1200…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesMicrowave Dielectric Ceramics Synthesis