Materials Literature
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${\mathrm{RFe}}_{10}$ ${\mathrm{Mo}}_{2}$ (R=Pr, Sm, Nd, Dy, Ho, Er, Tm) intermetallics were investigated by studying the temperature- or field-induced spin-reorientation transitions (SRT's). The temperature dependence of the magnetic anisotropy field was determined by means of the singular point-detection technique f…
Abstract Soil colour was expressed in terms of chromaticity coordinates instead of traditional Munsell notations which facilitated correlation with the moisture content of soils. Spectral reflectance of twenty‐one soil samples was measured in the visible region from saturation to air‐dryness from which the colour coor…
The formation of epitaxial lead-telluride films on a silicon substrate with a porous-silicon sublayer is investigated. In these structures vertical-type infrared photodiodes were produced using ion doping. Despite a great mismatch in the lattice constants and the temperature expansion coefficients between silicon and…
The crystal structures of [Fe(oep)L 2 ][O 3 SCF 3 ] and [Co(oep)L 2 ][ClO 4 ] [H 2 oep = 2,3,7,8,12,13,17,18-octaethylporphyrin, L = [Fe(C 5 H 5 )(C 4 H 4 N)] have been determined. The azaferrocene ligands L in both compounds are seen to be parallel. The axial M–N (azaferrocene) bonds are longer than those found in an…
Cluster models and the atom superposition and electron delocalization molecular orbital theory calculations lead to an explanation for the ability of nitrogen to cause phosphorous incorporation in low pressure grown diamond films as observed recently by Cao and coworkers. The theory shows that substitutional N compens…
Impedance spectra are obtained in H 2 /H 2 O on Ni/YSZ cermet anodes. These impedance spectra are fitted to the equivalent circuit LR(RQ) 1 (RQ) 2 (RC) 3 . The subcircuit (RC) 3 is found to have a capacitance in the order of 0.1-1.1F only when the current-bearing electrodes are in separate atmospheres. This impedance…
In order to clarify the phase transformation of Fe-15 mass%Cr-C-B alloys, we prepared nine kinds of the alloys with different carbon and boron contents. The phase transformation behavior was examined with thermal expansion test, hardness test and SEM observation. The results obtained are as follows.(1) The transformat…
SiC was bonded to SiC using Ta foils at temperatures from 1673 to 1773 K for 3.6∼144 ks in vacuum. The reaction phase and microstructure formed at the an interfaces between SiC and Ta were investigated. At the initial stage, an hexagonal Ta2C phase is formed at the Ta side of the reaction zone, and the hexagonal Ta5Si…
The influence of oxygen and humidity of inlet gas on the sintering reaction was studied through mathematical model analysis. Then, the change of oxygen and humidity of inlet gas was investigated for the effects on the sintering time, product yield of sinter, heat wave in sintering bed and other parameters in all of th…
The photolysis and photo-oxidation mechanisms of poly(butylene terephthalate) (PBT) and poly(butylene terephthalate)-fibre glass (PBT-FG) irradiated under polychromatic light (λ ≥ 2300 nm) were studied. Derivatisation reactions coupled to FTIR analysis of the exposed samples permitted the identification of the various…
目的 繊維束を薄く, 幅広な状態に, 連続して開繊させるための新しい方法を確立し, 開繊機構およびその加工条件と開繊性の関係を明らかにする.成果 1) ある一定の量だけ撓ませた繊維束に垂直に一様な空気流を連続して作用させる方法により, 繊維束を連続して良好に開繊させることができた. 2) 空気流の作用により繊維束の中央部分と両側部分に圧力差が生じ, 各繊維は繊維束の幅方向へ移動する力を得て開繊が行われるものと考えられる. 3) 繊維束の撓む大きさが適当に小さいとき, 各繊維の動きがある程度規制された状態となり, 開繊時の繊維の分が均一となる. 4) 開繊加工を行う場合の加工速度は開繊幅にほとんど影響しない. 5) 無撚炭素繊維束3…
Friction and wear tests of sintered α-SiC were conducted from room temperature to 1200°C both in air and vacuum. The coefficient of friction was larger in air than that in vacuum but was almost independent of the temperature. The specific wear loss generally increased with an increase of temperature. However, a substa…
We describe the applicability of the imaging plate method for determining stress by x-rays of coarse-grained materials. Three kinds of approach were examined. The first one was the standard type which adopted neither the software oscillation method, which is one of the image processing methods used to improve the accu…
Poly(isobutylene)glycols (PIBGs) were incorporated as soft segments into poly(ether urethanes) (PEUs) prepared with poly(tetramethylene ether)glycol (PTMEG)/1,4-butanediol (BD)/4,4′-methylenebis-(phenyl isocyanate) (MDI) systems. Specifically, three series of PEUs were synthesized containing mixed PIBG/PTMEG soft segm…
The coating wet adhesion stabilities caused by linear conventional polyurethanes and linear liquid crystalline polyurethanes (LC-PUs) were compared. The polyurethanes were used as primer in systems based on steel as substrate and an alkyd melamine resin as coating. The unsegmented main-chain liquid crystalline polyure…
Abstract The multi‐step synthesis of two benzimidazole trimethine cyanines as possible green sensitizing dyes (Gs3‐1, Gs3‐2) is reported. Compounds were characterized from UV‐Vis, mass spectroscopic and NMR data. The charge density distributions of the two compounds, calculated using the semi‐empirical MOPAC 93 packag…
A state variable electromagnetic (EM) analysis technique called rigorous wave coupled theory (RCWT) (used for the EM and optical analysis of planar diffraction gratings) is applied to determine the radiation and scattering that arises from phi-periodic circular cylindrical dielectric systems which have arbitrary radia…
The simultaneous determination in aqueous media of the gadolinium ion (Gd3+) and the macrocyclic chelate Gd–DOTA (DOTA = 1,4,7,10-tetraazacyclododecane- 1,4,7,10-tetraacetic acid) used in magnetic resonance imaging (MRI) is described. The proposed approach combines a reversed-phase high-performance liquid chromatograp…
Abstract Über eine gekoppelte Reaktion konnten aus Aluminiumoxid und Platin im Wasserstoffstrom bei Temperaturen um 1200°C platinreiche Aluminium‐Platin‐Legierungen synthetisiert werden. Als aluminiumreichste Phase wurde die im AuCu 3 ‐Typ kristallisierende Legierung‐ Al 1,16 Pt 2,84 erhalten. Entsprechend der Zusamme…
In the hyperthermophilic bacterium Thermotoga maritima, the two glycolytic enzymes phosphoglycerate kinase (PGK) and triosephosphate isomerase (TIM) are covalently connected forming a tetrameric single-chain PGK-TIM fusion protein. A frameshift allows the translation of PGK alone, whereas TIM activity exclusively resi…