Materials Literature
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Polymer brush layers based on block copolymers of poly(oligo(ethylene glycol) methacrylate) (POEGMA) and poly(glycidyl methacrylate) (PGMA) were formed on silicon wafers by activators generated by electron transfer atom transfer radical polymerization (AGET ATRP). Different types of biomolecule can be conjugated to th…
Avadhesh Kumar Yadava, C.R. Gautama*, Arvind Gautamb & Vijay Kumar Mishrac a Department of Physics , University of Lucknow , Lucknow 226007 , Uttar Pradesh , India b North East Institute of Science and Technology , Jorhat 785006 , Assam , India c Department of Physics , Banaras Hindu University , Varanasi 221005 , Utt…
We demonstrated Schottky-barrier solar cell using layer-structured semiconductor tungsten disulfide (WS2) nanofilm (NF) as the photo-active material. WS2 NFs were synthesized by chemical-vapor-deposition initiated on the surface of tungsten. The growth of WS2 NF was confirmed by Raman signature peaks representing acti…
We have developed a facile approach to synthesize anisotropic Janus hybrid particles by selective modification of bulgy patches on the composite spheres, which are in situ grown by phase separation during seeded emulsion polymerization. Janus particles are achieved by dissolution of the seed polymer particles. It is t…
Abstract Plasmonic metal nanoparticles absorb and scatter visible light due to localized surface plasmon resonance (LSPR). The optical properties including resonance wavelength and absorption intensity depend on particle size, shape, orientation, spacing, and dielectric environments. If silver nanoparticles are placed…
Three complexes of Mn(III) with "scorpionate" type ligands have been investigated by a variety of physical techniques. The complexes are [Tp(2)Mn]SbF(6) (1), [Tp(2)*Mn]SbF(6) (2), and [{PhB(MeIm)(3)}(2)Mn](CF(3)SO(3)) (3a), where Tp(-) = hydrotris(pyrazolyl)borate anion, Tp*(-) = hydrotris(3,5-dimethylpyrazolyl)borate…
In this work, we present the third order nonlinear optical investigation of two gold complexes, which differ by the nature of the counter cations. The impact of the different design in the architecture through a set of hydrogen bonds in the case of Au-Mel of the systems on the nonlinearity has been studied by means of…
A novel low cost polymer composite using brown grass flower broom reinforcement is prepared. The prepared polymer composite has the lowest porosity, homogeneous surface structure, and the greatest interface bonding. From the physico-mechanical characterization such as: hardness measurement, density measurement, void f…
AIM: The development of novel silk/nano-sized calcium phosphate (silk/nano-CaP) scaffolds with highly dispersed CaP nanoparticles in the silk fibroin (SF) matrix for bone tissue engineering. MATERIALS & METHODS: Nano-CaP was incorporated in a concentrated aqueous SF solution (16 wt.%) by using an in situ synthesis met…
A family of high-nuclearity [Ln(III)(6)Mn(III)(12)] (Ln = Gd, Tb) nanomagnets has been synthesized, of which two are in D(2) molecular symmetry and the other two are in C(1) symmetry. X-ray crystallography shows that each of them contains a similar {Mn(III)(8)O(13)} unit, four marginal Mn(III) ions, and two linear {Ln…
We introduce a novel method to produce macroporous ceramics by capillary suspensions. Adding a small amount (~1 vol%) of an immiscible secondary phase to a low concentration (~20 vol%) suspension can increase the yield stress by several orders of magnitude. This drastic change in flow behavior is induced by the creati…
We present an in situ hydrophobic salt forming technique for the encapsulation of weakly hydrophobic, ionizable active pharmaceutical ingredients (API) into stable nanocarriers (NCs) formed via a rapid precipitation process. Traditionally, NC formation via rapid precipitation has been difficult with APIs in this class…
High quality, vertically aligned ZnO nanorods were grown on a silicon substrate, using microwave-assisted chemical bath deposition with poly (vinyl alcohol)-Zn(OH)2 nanocomposites as seed layer. The structure and surface morphology of the prepared ZnO nanorod arrays were characterized using X-ray diffraction and scann…
Continuous-Time Quantum Monte Carlo (CT-QMC) method combined with Dynamical Mean Field Theory (DMFT) is used to calculate both Periodic Anderson Model (PAM) and Kondo Lattice Model (KLM). Different parameter sets of both models are connected by the Schrieffer-Wolff transformation. For degeneracy N=2, a special particl…
The epitaxial stabilization of a single layer or superlattice structures composed of complex oxide materials on polar (111) surfaces is severely burdened by the reconstructions at the interface that commonly arise to neutralize the polarity. We report on the synthesis of high quality LaNiO3/mLaAlO3 pseudo cubic (111)…
Two dimensional crystal heterostructures are shown to possess a unique opportunity for nonlinear THz devices. In contrast to the oxide tunneling barrier, the uniformity of layered crystal insulators provides an ideal condition for tunneling barriers in the atomic scale. Numerical calculations based on a first-principl…
Single-molecule (SM) spectroscopy has been an exciting area of research offering significant promise and hope in the field of sensor development to detect targets at ultra-low levels down to SM resolution. To the experts and developers in the field of surface-enhanced Raman spectroscopy (SERS), this has often been a c…
AgInS 2 –ZnS (AIZS) nanocrystals (NCs) were synthesized using a simple one-step approach by heating a Ag/In/Zn/S solution to 210 °C providing highly tunable photoluminescence (PL). The incorporation of Zn even at low temperatures (∼150 °C) and the increased cation exchange of silver by zinc at higher temperatures stro…
We report on domain formation and magnetization reversal in epitaxial Fe films on ferroelectric BaTiO3 substrates with ferroelastic a–c stripe domains. The Fe films exhibit biaxial magnetic anisotropy on top of c domains with out-of-plane polarization, whereas the in-plane lattice elongation of a domains induces uniax…
The self-assembly of abnormally folded proteins into amyloid fibrils is a hallmark of many debilitating diseases, from Alzheimer's and Parkinson diseases to prion-related disorders and diabetes type II. However, the fundamental mechanism of amyloid aggregation remains poorly understood. Core sequences of four to seven…