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Microwave‐assisted synthesis and characterization of biodegradable block copolyesters based on poly(3‐hydroxyalkanoate)s and poly(D,L‐lactide)

Julien Ramier、Estelle Renard、Daniel Grande2012-01-28Journal of Polymer Science Part A Polymer Chemistry

Abstract Microwave (MW)‐assisted ring‐opening polymerization (ROP) provides a rapid and straightforward method for engineering a wide array of well‐defined poly(3‐hydroxyalkanoate)‐ b ‐poly( D,L ‐lactide) (PHA‐ b ‐PLA) diblock copolymers. On MW irradiation, the bulk ROP of D,L ‐lactide (LA) could be efficiently trigge…

biodegradable polymer synthesis and propertiesPolyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysis

Surface properties and biocompatibility of cellulose acetates

Adina Maria Dobos、Iuliana Stoica、Niculae Olaru 等 6 位作者2012-01-28Journal of Applied Polymer Science

Abstract The article describes some properties of cellulose acetates (CAs) with different substitution degrees. The hydrophilic/hydrophobic properties, morphological aspects, and interface properties with red blood cells and platelets are affected by the substitution degree, synthesis conditions, history of the formed…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Single-component Layered Molecular Conductor, [Au(ptdt)2]

Biao Zhou、Hiroyuki Yajima、Yuki Idobata 等 8 位作者2012-01-28Chemistry Letters

Abstract A single-component layered molecular conductor, [Au(ptdt)2] (ptdt: propylenedithiotetrathiafulvalenedithiolate) was prepared. Unlike the single-component molecular metal, [Au(tmdt)2] (tmdt: trimethylenetetrathiafulvalenedithiolate) exhibiting three-dimensional compact molecular packing and antiferromagnetic t…

Perovskite Materials and ApplicationsMagnetism in coordination complexesOrganic and Molecular Conductors Research

On a Novel Catalytic System Based on Electrospun Nanofibers and M-POSS

Erika Simona Cozza、Valentina Bruzzo、Fabio Carniato 等 5 位作者2012-01-28ACS Applied Materials & Interfaces

We report on a novel catalytic system based on electrospun polymer nanofibers, which were modified with a metal-containing polyhedral oligomeric silsesquioxanes (M-POSS). In particular, a titanium-based POSS, characterized by an amino group as reactive side, was contacted with poly(styrene-co-maleic anhydride) (PSMA)…

Metal and Thin Film MechanicsElectrospun Nanofibers in Biomedical ApplicationsSilicone and Siloxane Chemistry

Upgrading of Tannery Wastes under Fast and Slow Pyrolysis Conditions

A. Marcilla、Milagros León、A N Jesús García 等 5 位作者2012-01-28Industrial & Engineering Chemistry Research

The pyrolysis of a chromium-tanned waste (bovine split leather) under inert atmosphere has been carried out in a vertical lab scale reactor. The influence of process conditions, such as temperature, residence time, and heating rate on the pyrolytic product distribution has been studied, in order to optimize the liquid…

Dyeing and Modifying Textile FibersCollagen: Extraction and CharacterizationThermal and Kinetic Analysis

Effects of Surface Chemistry of Substrates on Raman Spectra in Graphene

Takahiro Tsukamoto、Kenji Yamazaki、Hiroki Komurasaki 等 4 位作者2012-01-28The Journal of Physical Chemistry C

We investigated the effects of surface chemistry of substrates on the Raman spectra of graphene flakes that come into contact with various insulating substrates, such as quartz and sapphire, under ambient conditions at room temperature. The G-peak positions of graphene flakes on such substrates were investigated, and…

Graphene research and applicationsNanopore and Nanochannel Transport StudiesGraphene and Nanomaterials Applications

Mechanical Property Characterization of Fiber-Reinforced Polymer Wood-Polypropylene Composite Panels Manufactured Using a Double Belt Pressing Technology

Sandeep Tamrakar、Stephen M. Shaler、Roberto Lopez‐Anido 等 7 位作者2012-01-28Journal of Materials in Civil Engineering

A novel manufacturing process for wood-polypropylene composite (WPC) panels reinforced with fiber-reinforced polymer (FRP) sheets was implemented using a double belt pressing technology. FRP sheets were placed on both sides of the WPC agglomerates during fabrication, which resulted in increased productivity and reduce…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesAdditive Manufacturing and 3D Printing Technologies

Strategies of Targeting Tumors and Cancers

Rajesh K. Sain、Raje Chouhan、Laxmi P. Bagri 等 4 位作者2012-01-28Journal of cancer research updates

Targeted cancer therapies use drugs that specially reach at the affected site block the growth and spread of cancer. They interfere with specific molecules involved in carcinogenesis (the process by which normal cells become cancer cells) and tumor growth. By focusing on molecular and cellular changes that are specifi…

Nanoparticle-Based Drug DeliveryComputational Drug Discovery MethodsEnzyme function and inhibition

Poly(L-Lactide)-Degrading Enzyme Production by Actinomadura keratinilytica T16-1 in 3 L Airlift Bioreactor and Its Degradation Ability for Biological Recycle

Sukhumaporn Sukkhum2012-01-28Journal of Microbiology and Biotechnology

The optimal physical factors affecting enzyme production in an airlift fermenter have not been studied so far. Therefore, the physical parameters such as aeration rate, pH, and temperature affecting PLA-degrading enzyme production by Actinomadura keratinilytica strain T16-1 in a 3 l airlift fermenter were investigated…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesEnzyme Production and Characterization

Ultrafast Charge Transfer Dynamics in Polycrystalline CdSe/TiO2 Nanorods Prepared by Oblique Angle Codeposition

Bob C. Fitzmorris、George K. Larsen、Damon A. Wheeler 等 5 位作者2012-01-28The Journal of Physical Chemistry C

Ultrafast exciton dynamics of aligned polycrystalline nanorod arrays composed of CdSe or CdSe/TiO 2 grown on conductive glass substrates using oblique angle deposition/codeposition have been studied using femtosecond transient absorption (TA) spectroscopy. Scanning electron microscopy images show that the morphology o…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Preparation of ultrahigh‐molecular‐weight polyethylene/carbon nanotube nanocomposites with a Ziegler–Natta catalytic system and investigation of their thermal and mechanical properties

Behnam Meschi Amoli、Ahmad Ramazani、Hadi Izadi2012-01-28Journal of Applied Polymer Science

Abstract In this research, ultrahigh‐molecular‐weight polyethylene (UHMWPE)/multiwalled carbon nanotube (MWCNT) nanocomposites with different nanotube concentrations (0.5, 1.5, 2.5, and 3.5 wt %) were prepared via in situ polymerization with a novel, bisupported Ziegler–Natta catalytic system. Magnesium ethoxide [Mg(O…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Characterization of polyhydroxyalkanoates (PHAs) biosynthesis by isolatedNovosphingobiumsp. THA_AIK7 using crude glycerol

Jantima Teeka、Tsuyoshi Imai、Alissara Reungsang 等 12 位作者2012-01-28Journal of Industrial Microbiology & Biotechnology

Biodiesel-contaminated wastewater was used to screen for PHAs-producing bacteria by using crude glycerol as the sole carbon source. A gram-negative THA_AIK7 isolate was chosen as a potential PHAs producer. The 16S rRNA phylogeny indicated that THA_AIK7 isolate is a member of Novosphingobium genus which is supported by…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Analysis of the tensile modulus of polypropylene composites reinforced with stone groundwood fibers

Joan Pere López、Pere Mutjé、M. Àngels Pèlach 等 6 位作者2012-01-28BioResources

One of the most relevant properties of composite materials to be considered is stiffness. Fiberglass has been used traditionally as a fibrous reinforcing element when stiff materials are required. However, natural fibers are been exploited as replacements for synthetic fibers to satisfy environmental concerns. Among t…

Mechanical Behavior of CompositesPolymer crystallization and propertiesNatural Fiber Reinforced Composites

X-ray line profiles analysis of plastically deformed metals

A. Borbély、T. Ungár2012-01-28Comptes Rendus Physique

The theoretical basis of X-ray line profile analysis and its application to microstructural characterization of plastically deformed metallic alloys is presented. The microstructure is described in terms of coherent domain size, planar fault density, dislocation density and a dislocation arrangement parameter. Two eva…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsX-ray Diffraction in Crystallography

First-principles study of structural, magnetic and electronic properties of small FeRh alloy clusters

Junais Habeeb Mokkath、G. M. Pastor2012-01-28arXiv

The structural, electronic and magnetic properties of small ${\rm Fe}_m {\rm Rh}_n$ clusters having $N = m+n \leq 8$ atoms are studied in the framework of a generalized-gradient approximation to density-functional theory. For $N = m+n \leq 6$ a thorough sampling of all cluster topologies has been performed, while for…

Materials Sciencephysics.atm-clus

Temperature evolution of spin accumulation detected electrically in a nondegenerated silicon channel

Y. Ando、K. Kasahara、S. Yamada 等 9 位作者2012-01-28arXiv

We study temperature evolution of spin accumulation signals obtained by the three-terminal Hanle effect measurements in a nondegenerated silicon channel with a Schottky-tunnel-barrier contact. We find the clear difference in the temperature-dependent spin signals between spin-extraction and spin-injection conditions.…

Mesoscale and Nanoscale PhysicsMaterials Science

A review on the synthesis of TiO2 nanoparticles by solution route

Shipra Mital Gupta、Manoj Tripathi2012-01-28Open Chemistry

Abstract TiO2 can be prepared in the form of powder, crystals, or thin films. Liquid-phase processing is one of the most convenient and utilized methods of synthesis. It has the advantage of allowing control over the stoichiometry, production of homogeneous materials, formation of complex shapes, and preparation of co…

TiO2 Photocatalysis and Solar CellsCatalytic Processes in Materials ScienceNanomaterials for catalytic reactions

Reverse-Engineering Evaluation and Monitoring of Nemrut Monuments

Ahmet Türer、Yasemin D. Aktaş、Neriman Şahin Güçhan2012-01-27International Journal of Architectural Heritage

The focus of this study is on the Nemrut Dağ monuments, which were constructed approximately 2000 years ago at the peak of Mount Nemrut, 2206 meters elevation, are among the most valuable historical heritage sites in Turkey. Since the discovery of Nemrut monuments in 1881, many questions are unresolved, such as how th…

Energetic Materials and CombustionBuilding materials and conservationHigh-Velocity Impact and Material Behavior

Evidence Linking Elevated Oxidative Stress and Aseptic Loosening of Hip Arthroplasty

Plamen Kinov、Peter Tivchev2012-01-27InTech eBooks

Next to development of new bearing surfaces, the second line of research focuses on understanding of the underlying mechanisms of the process aseptic loosening of THA. Aseptic loosening is characterized with osteolysis and formation of thick membrane around the prostheses that eventually leads to its loosening. Curren…

Thermal and Kinetic AnalysisChemical Thermodynamics and Molecular StructureFree Radicals and Antioxidants

Electrooptical Behavior of Aqueous (Hydroxypropyl)cellulose Liquid Crystals Containing Imidazolium Salts

Mitsuhiro Ito、Yoshikuni Teramoto、Yoshiyuki Nishio2012-01-27Biomacromolecules

A dynamic control of the cholesteric coloration and optical clarity of aqueous (hydroxypropyl)cellulose (HPC) lyotropics is attainable under a weak electric field by employing a fluctuating ionic additive as P and T(c) shifter (P, cholesteric pitch; T(c), cloud point). The present Article demonstrates some examples of…

Liquid Crystal Research AdvancementsAdvanced Cellulose Research StudiesElectrowetting and Microfluidic Technologies