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Water‐soluble metalated and non‐metalated A2B‐ and A3‐corrole/amino acid conjugates: syntheses, characterization and properties

Melanie Schmidlehner、Felix Faschinger、Lorenz Michael Reith 等 5 位作者2013-06-10Applied Organometallic Chemistry

In this study, novel water‐soluble corrole amino acid conjugates were synthesized and characterized. The coupling reaction of A 2 B‐ and A 3 ‐corroles with glycine ethyl ester and taurine under strong basic conditions proved to be successful and yielded di‐ and trifunctionalized corrole amino acid conjugates in good y…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsPorphyrin Metabolism and Disorders

Thermoelectric properties of single walled carbon nanotube networks in polycarbonate matrix

Mingxing Piao、Gyutae Kim、Gary P. Kennedy 等 5 位作者2013-06-10physica status solidi (b)

Abstract We report on single walled carbon nanotubes (SWCNTs) used as a filler material for polycarbonate (PC) composites in this paper. Thin flexible composite films were prepared by solvent casting with a viscous dispersion of SWCNTs in a polymer matrix. The interaction of SWCNTs with PC was studied by Raman spectro…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Terahertz Wave Propagation in a Nanotube Conveying Fluid Taking into Account Surface Effect

Yewei Zhang、Tianzhi Yang、Jian Zang 等 4 位作者2013-06-10Materials

In nanoscale structure sizes, the surface-to-bulk energy ratio is high and the surface effects must be taken into account. Surface effect plays a key role in accurately predicting the vibration behavior of nanostructures. In this paper, the wave behaviors of a single-walled carbon nanotube (CNT) conveying fluid are st…

Acoustic Wave Phenomena ResearchMechanical and Optical ResonatorsNonlocal and gradient elasticity in micro/nano structures

Plasma Electrolytic Oxidation of Valve Metals

Alex Lugovskoy、Michael Zinigr2013-06-10InTech eBooks

Plasma electrolytic oxidation (PEO) is also known as micro-arc oxidation and spark anodizing is often regarded as a version of anodizing of valve metals (Mg, Al, Ti, and several others) and their alloys. Indeed, the essence of both anodizing and PEO is the production of oxide layers on a metal surface by the action of…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsMagnesium Alloys: Properties and Applications

Melting of a confined monolayer of magnetized beads

Julien Schockmel、E. Mersch、Nicolas Vandewalle 等 4 位作者2013-06-10Physical Review E

We present an experimental model system to study two-dimensional phase transitions. This system is composed of a monolayer of millimetric beads interacting through shor range magnetic dipole-dipole interactions. As the system is athermal, a mechanical agitation is used to produce an erratic motion of the beads. The tw…

Material Dynamics and PropertiesTheoretical and Computational PhysicsAdvanced Thermodynamics and Statistical Mechanics

Gadolinia Doped Ceria Thin Films Prepared by Aerosol Assisted Chemical Vapor Deposition and Applications in Intermediate‐Temperature Solid Oxide Fuel Cells

Meike V. F. Schlupp、Alexey Kurlov、Jaeyeon Hwang 等 9 位作者2013-06-10Fuel Cells

Abstract Furthermore, deposition at such low temperatures is promising for processing of thin film assemblies. The preparation of bi‐layer electrolytes of yttria stabilized zirconia and gadolinia doped ceria thin films by aerosol assisted chemical vapor deposition is demonstrated. Gadolinia doped ceria films as thin a…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsElectronic and Structural Properties of Oxides

Mott-type MgxZn1-xO-based visible-blind ultraviolet photodetectors with active anti-reflection layer

Xiuhua Xie、Zhenming Zhang、Bingda Li 等 9 位作者2013-06-10Applied Physics Letters

We report on a vertical geometry Mott-type visible (VIS)-blind Ultraviolet (UV) photodetector which was fabricated based on wurzite MgZnO (W-MgZnO) with a cubic MgZnO (C-MgZnO) anti-reflection layer. The C-MgZnO layer plays two roles in the detector, not only the conventional optical part but also electrical part. Pho…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Simple Technique for Spatially Separated Nanofibers/Nanobeads by Multinozzle Electrospinning toward White-Light Emission

Jong‐Ho Kim、Jaeguk Noh、Seonyoung Jo 等 6 位作者2013-06-10ACS Applied Materials & Interfaces

Electrospun, emission color-tunable nanofibrous sheets were fabricated by multinozzle electrospinning equipped with a secondary electrode for the preparation of white-emissive sheets under a single excitation source, manipulating energy transfer between dyes. By control of the concentration of commercially available r…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Oxidation of nanoscale Au–In alloy particles as a possible route toward stable Au-based catalysts

Eli Sutter、Xiao Tong、Katherine Jungjohann 等 4 位作者2013-06-10Proceedings of the National Academy of Sciences

The oxidation of bimetallic alloy nanoparticles comprising a noble and a nonnoble metal is expected to cause the formation of a single-component surface oxide of the nonnoble metal, surrounding a core enriched with the noble metal. Studying the room temperature oxidation of Au-In nanoparticles, we show that this simpl…

Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions

Use of particle-in-cell simulations to improve the actinometry technique for determination of absolute atomic oxygen density

Jim Conway、S Kechkar、N O' Connor 等 6 位作者2013-06-10Plasma Sources Science and Technology

Actinometry is a non-invasive optical technique that can be used to quantitatively monitor atomic oxygen number densities [O] in gas discharges under certain operating conditions. However, careless application of the technique can lead to erroneous conclusions regarding the behaviour of atomic oxygen in plasma. One li…

Diamond and Carbon-based Materials ResearchPlasma Applications and DiagnosticsPlasma Diagnostics and Applications

Surface-based manipulation of point defects in rutile TiO2

Alice G. Hollister、Prashun Gorai、Edmund G. Seebauer2013-06-10Applied Physics Letters

Through isotopic self-diffusion measurements, the present work resolves a discrepancy in the literature about the primary oxygen-related point defect in rutile TiO2 by showing that suitably prepared surfaces can controllably inject large numbers of an exceptionally mobile defect. Results strongly suggest that this def…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsElectronic and Structural Properties of Oxides

Dynamic Heterogeneity in Random and Gradient Copolymers: A Computational Investigation

Mohammed Zakaria Slimani、Angel J. Moreno、Giulia Rossi 等 4 位作者2013-06-10Macromolecules

By means of molecular dynamics simulations, we investigate the structural relaxation in disordered random copolymers and lamellar phases of gradient copolymers, containing chemical species of very different mobilities. Two models have been investigated: a generic bead–spring system and a MARTINI coarse-grained model o…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesBlock Copolymer Self-Assembly

Characteristics of the Anodic Films on an AZ91D Mg Alloy Prepared by Plasma Electrolytic Oxidation and Burning Surface Treatment

Yu Jae-In、Joo-Sik Yoon、Jae-Gon Yoon 等 8 位作者2013-06-10대한금속재료학회지

유재인 ・윤주식1 ・윤재곤1 ・김진희1 ・최순돈2,* ・장호경3 ・유재용4 ・배인호5,* (주)위스코하이텍 기업부설연구소 영남대학교 신소재공학부 대구한의대학교 의공학과 영남대학교 응용전자공학 영남대학교 물리학과 Characteristics of the Anodic Films on an AZ91D Mg Alloy Prepared by Plasma Electrolytic Oxidation and Burning Surface Treatment Jae-In Yu, Joo-Sik Yoon, Jae-Gon Yoon, Jin-Hi Kim, Soon-Don Choi*, Ho-Ky…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Electronic structure and magnetic symmetry in MnTiO3analyzed by second harmonic generation

Judy Cherian、T. Tokumoto、Haidong Zhou 等 5 位作者2013-06-10Physical Review B

Second harmonic generation (SHG) and linear absorbance spectra of MnTiO${}_{3}$ were measured and the 1.88, 2.41, 2.63, and 3.06 eV SHG features were identified as $d\ensuremath{-}d$ optical transitions from ${}^{6}{A}_{1g}$ to ${}^{4}{T}_{1g}{(}^{4}G)$, ${}^{4}{T}_{2g}{(}^{4}G)$, ${{}^{4}{E}_{g}$,${}^{4}{A}_{1g}{(}^{…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsElectronic and Structural Properties of Oxides

Highly Transmissive Carbon Nanotube Forests Grown at Low Substrate Temperature

José V. Anguita、David Cox、Muhammad Ahmad 等 6 位作者2013-06-10Advanced Functional Materials

Abstract Despite the “darker than black” association attributed to carbon nanotube forests, here is shown that it is also possible to grow these structures, over heat‐sensitive substrates, featuring highly transmissive characteristics from the UV to infrared wavelengths, for forest heights as high as 20 μm. The optica…

Carbon Nanotubes in CompositesPhotonic Crystals and ApplicationsMechanical and Optical Resonators

Quantum metamaterial without local control

А. В. Швецов、A. M. Satanin、Franco Nori 等 5 位作者2013-06-10Physical Review B

A quantum metamaterial can be implemented as a quantum coherent one-dimensional array of qubits placed in a transmission line. The properties of quantum metamaterials are determined by the local quantum state of the system. Here we show that a spatially periodic quantum state of such a system can be realized without d…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Superconductivity in Bismuth Oxysulfide Bi4O4S3

CI Sathish、Hai L. Feng、Youguo Shi 等 4 位作者2013-06-10Journal of the Physical Society of Japan

Bismuth oxysulfide Bi4O4S3, which has recently been claimed to be an exotic superconductor (\(T_{\text{c}} = 4.5\) K), was investigated by magnetic susceptibility and electrical resistivity measurements as well as by electron probe microanalysis. Single-phase Bi4O4S3 was successfully prepared by a high-pressure method…

Physics of Superconductivity and MagnetismIron-based superconductors researchSuperconductivity in MgB2 and Alloys

TcEnhancement by Aliovalent Anionic Substitution in Superconducting BaTi2(Sb1-xSnx)2O

Kousuke Nakano、Takeshi Yajima、Fumitaka Takeiri 等 7 位作者2013-06-10Journal of the Physical Society of Japan

BaTi2Sb2O is a T-c = 1.2 K superconductor with a d(1) square lattice, and isovalent Bi substitution for Sb can increase its T-c to 4.6 K (BaTi2Bi2O), accompanied by the complete suppression of charge density wave (CDW) or spin density wave (SDW) transition. In the present study, we demonstrate that aliovalent Sn subst…

Physics of Superconductivity and MagnetismIron-based superconductors researchSuperconductivity in MgB2 and Alloys

Enhanced photocurrent from generated photothermal heat in indium nanoparticles embedded TiO2 film

Bijit Choudhuri、Aniruddha Mondal、Jay Chandra Dhar 等 6 位作者2013-06-10Applied Physics Letters

We have demonstrated the synthesis of indium (In) nanoparticle (NP) arrays on TiO2 thin film (TF) using glancing angle deposition technique. The deposited In NPs are of the order of 4–10 nm in size. Optical absorption measurements depict 2.5 times enhanced absorption for In-NPs/TiO2-TF compared to TiO2 TF. The plasmon…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchOptical Coatings and Gratings

Effects of extraneous surface charges on the enhanced Raman scattering from metallic nanoparticles

H. Y. Chung、Paul Leung、Din Ping Tsai2013-06-10The Journal of Chemical Physics

Motivating by recent experiments on surface enhanced Raman scattering (SERS) from colloidal solutions, we present here a simple model to elucidate the effects of extraneous surface charges on the enhanced Raman signal. The model is based on the well-established Gersten-Nitzan model coupled to the modified Mie scatteri…

Gold and Silver Nanoparticles Synthesis and ApplicationsElectrochemical Analysis and ApplicationsProtein Interaction Studies and Fluorescence Analysis