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Accurate Determination of Optical Functions of Ge – As – Te Glasses via Spectroscopic Ellipsometry

Petra Hawlová、Frédéric Verger、Virginie Nazabal 等 5 位作者2014-08-26Journal of the American Ceramic Society

Variable angle spectroscopic ellipsometry technique was used to characterize optical functions of chalcogenide glasses from Ge – As – Te system in broad spectral range (300 nm–20 μm). Measured real and imaginary parts of pseudodielectric function were modeled with Cody–Lorentz approach and Sellmeier equation. Very goo…

Glass properties and applicationsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Theoretical investigation of La monopnictides: Electronic properties and pressure-induced phase transition

Xingchen Yan、Y. M. Chen、Xueheng Kuang 等 4 位作者2014-08-26Journal of Applied Physics

The NaCl-type La monopnictides are proper reference materials for the study of strongly correlated rare-earth pnictides. Yet, despite the simple crystal structure of this system, traditional density functional theory (DFT) calculations have dramatic failures in describing their electronic properties: DFT severely unde…

Rare-earth and actinide compoundsIron-based superconductors researchSuperconductivity in MgB2 and Alloys

Facile synthesis of polymer and carbon spheres decorated with highly dispersed metal nanoparticles

Nilantha P. Wickramaratne、Mietek Jaroniec2014-08-26Chemical Communications

Metal nanoparticle-decorated carbon spheres (mn-CSs) are prepared by combining one-pot hydrothermal synthesis and post-synthesis modification. The former sol-gel type process is employed to obtain heteroatom-containing polymer spheres (PSs), which easily attract metal species that, during thermal treatment, are initia…

Supercapacitor Materials and FabricationCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

Selective area deposition of diamond films on AlGaN/GaN heterostructures

Tibor Ižák、Oleg Babchenko、Vı́t Jirásek 等 7 位作者2014-08-26physica status solidi (b)

Diamond‐on‐GaN heterostructure is a promising hybrid material system with a variety of applications such as heat spreaders, high‐temperature, and high‐power devices. From a practical point of view, polycrystalline diamond is shown to be an attractive solution to the limited use of the expensive monocrystalline diamond…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Characterization of Functionalized Multiwalled Carbon Nanotubes for Use in an Enzymatic Sensor

Leonor Guadarrama-Fernández、José Jorge Chanona‐Pérez、A. Manzo‐Robledo 等 7 位作者2014-08-26Microscopy and Microanalysis

Carbon nanotubes (CNT) have proven to be materials with great potential for the construction of biosensors. Development of fast, simple, and low cost biosensors to follow reactions in bioprocesses, or to detect food contaminants such as toxins, chemical compounds, and microorganisms, is presently an important research…

Carbon Nanotubes in CompositesElectrochemical sensors and biosensorsNeuroscience and Neural Engineering

Critical slowing down and elastic anomaly of uniaxial ferroelectricCa0.28Ba0.72Nb2O6crystals with tungsten bronze structure

Kenji Suzuki、Kazuya Matsumoto、J. Dec 等 6 位作者2014-08-26Physical Review B

The ferroelectric phase transition of uniaxial ${\mathrm{Ca}}_{0.28}{\mathrm{Ba}}_{0.72}{\mathrm{Nb}}_{2}{\mathrm{O}}_{6}$ single crystals with a moderate effective charge disorder was investigated by Brillouin scattering to clarify the dynamic properties. In the tetragonal paraelectric phase a remarkable softening of…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Synergistic Effects in Reduced-Activation Martensitic Steel Under Single and Sequential Helium/Hydrogen Ion Irradiation

Jihong Chen、Liping Guo、Fengfeng Luo 等 6 位作者2014-08-26Fusion Science & Technology

Single-beam (He+ or H+) and sequential-beam (He+/H+ or H+/He+) irradiation of reduced-activation martensitic steels at 450°C was carried out to investigate helium/hydrogen synergistic effects on the microstructure of the steels. After helium implantation, a very low density of helium bubbles was observed. No void was…

Fusion materials and technologiesHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

A Lightweight Polymer Solar Cell Textile that Functions when Illuminated from Either Side

Zhitao Zhang、Xueyi Li、Guozhen Guan 等 7 位作者2014-08-26Angewandte Chemie

Abstract An all‐solid‐state, lightweight, flexible, and wearable polymer solar cell (PSC) textile with reasonable photovoltaic performance has been developed. A metal textile electrode made from micrometer‐sized metal wires is used as the cathode, and the surfaces of the metal wires are dip‐coated with the photoactive…

Organic Electronics and PhotovoltaicsQuantum Dots Synthesis And PropertiesConducting polymers and applications

Evaluation of Agave Fiber Delignification by Means of Microscopy Techniques and Image Analysis

Hilda María Hernández‐Hernández、José Jorge Chanona‐Pérez、Georgina Calderón‐Domínguez 等 9 位作者2014-08-26Microscopy and Microanalysis

Recently, the use of different types of natural fibers to produce paper and textiles from agave plants has been proposed. Agave atrovirens can be a good source of cellulose and lignin; nevertheless, the microstructural changes that happen during delignification have scarcely been studied. The aim of this work was to s…

Advanced Cellulose Research StudiesLignin and Wood ChemistryBotanical Research and Applications

Effect of Conformation on the Photodegradation of Trp- And Cystine-Containing Cyclic Peptides: Octreotide and Somatostatin

Olivier Mozziconacci、Christian Schöneich2014-08-26Molecular Pharmaceutics

The synthetic cyclic octapeptide octreotide is less stable under UV and fluorescent lights than its naturally occurring derivative somatostatin. Upon irradiation at λ > 290 nm, and in the presence of oxygen, octreotide is quickly transformed into a photoproduct showing an increase of mass of 16 Da. The increase of 16…

Molecular Sensors and Ion DetectionPhotochromic and Fluorescence ChemistryAmino Acid Enzymes and Metabolism

Biomimetic star-shaped poly(ε-caprolactone)-b-glycopolymer block copolymers with porphyrin-core for targeted photodynamic therapy

Xiaohui Dai、Zhiming Wang、Yafei Huang 等 7 位作者2014-08-26RSC Advances

In this study, star-shaped porphyrin-cored poly(ε-caprolactone)-b-poly(gluconamidoethyl methacrylate) block copolymers (SPPCL-PGAMA) were successfully obtained. The synthetic route was via the ring-opening polymerization (ROP) of ε-caprolactone using a tetra-hydroxyethyl terminated porphyrin as a core initiator follow…

Advanced Polymer Synthesis and CharacterizationPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

In situObservation of Defect Annihilation in Kr Ion-Irradiated Bulk Fe/Amorphous-Fe2Zr Nanocomposite Alloy

Kaiyuan Yu、Zhe Fan、Y. Chen 等 9 位作者2014-08-26Materials Research Letters

Enhanced irradiation tolerance in crystalline multilayers has received significant attention lately. However, little is known on the irradiation response of crystal/amorphous nanolayers. We report on in situ Kr ion irradiation studies of a bulk Fe96Zr4 nanocomposite alloy. Irradiation resulted in amorphization of Fe2Z…

Fusion materials and technologiesIon-surface interactions and analysisNuclear materials and radiation effects

Anion-Dependent Assembly of Four Sensitized Near-Infrared Luminescent Heteronuclear ZnII–YbIII Schiff Base Complexes from a Trinuclear ZnII Complex

Zhi-Peng Zheng、Yan-Jun Ou、Xu‐Jia Hong 等 8 位作者2014-08-26Inorganic Chemistry

Four anion-dependent 0D Zn(II)-Yb(III) heterometallic Schiff base complexes, [YbZn2L2(OAc)4]·ClO4 (2), YbZnL2(NO3)3 (3), [(YbL)2(H2O)Cl(OAc)]2·[ZnCl4]2 (4), and YbZnL(OAc)4 (5), were assembled through central metal substitution or reconstruction from homotrinuclear Zn(II) complex {[(Zn(OAc)(H2O)L]2Zn}(ClO4)2·4H2O [1;…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Influences of polyhedral oligomeric silsesquioxanes (POSSs) containing different functional groups on crystallization and melting behaviors of POSS/polydimethylsiloxane rubber composites

Dian Zhang、Yunhui Shi、Yufeng Liu 等 4 位作者2014-08-26RSC Advances

In this article, three kinds of polyhedral oligomeric silsesquioxanes (POSSs)—octamethylsilsesquioxane (OMS), octaphenylsilsesquioxane (OPS) and heptaphenylhydrogensilsesquioxane (H-POSS)—were successfully synthesized. Then, POSSs were incorporated into polydimethylsiloxane (PDMS) rubber through solution blending foll…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Influence of boundary conditions on the existence and stability of minimal surfaces of revolution made of soap films

Louis Salkin、Alexandre Schmit、Pascal Panizza 等 4 位作者2014-08-26American Journal of Physics

Because of surface tension, soap films seek the shape that minimizes their surface energy and thus their surface area. This mathematical postulate allows one to predict the existence and stability of simple minimal surfaces. After briefly recalling classical results obtained in the case of symmetric catenoids that spa…

Material Dynamics and PropertiesPickering emulsions and particle stabilizationnanoparticles nucleation surface interactions

Raman mapping investigation of chemical vapor deposition-fabricated twisted bilayer graphene with irregular grains

Yuming Chen、Lijuan Meng、Weiwei Zhao 等 11 位作者2014-08-26Physical Chemistry Chemical Physics

Bilayer graphene as a prototype of two-dimensional stacked material has recently attracted great attention. The twist angle between graphene layers adds another dimension to control its properties. In this study, we used Raman mapping to investigate the twist angle dependence of properties of twisted bilayer graphene…

Graphene research and applications2D Materials and ApplicationsNanowire Synthesis and Applications

Re‐Appearance of Cooperativity in Ultra‐Small Spin‐Crossover [Fe(pz){Ni(CN)4}] Nanoparticles

Haonan Peng、Simon Tricard、Gautier Félix≠ 等 7 位作者2014-08-26Angewandte Chemie

Abstract A reverse nanoemulsion technique was used for the elaboration of [Fe(pz){Ni(CN) 4 }] nanoparticles. Low‐temperature micellar exchange made it possible to elaborate ultra‐small nanoparticles with sizes down to 2 nm. When decreasing the size of the particles from 110 to 12 nm the spin transition shifts to lower…

Magnetic properties of thin filmsMagnetism in coordination complexesElectron Spin Resonance Studies

Circuit-tunable sub-wavelength THz resonators: hybridizing optical cavities and loop antennas

Bruno Paulillo、Jean‐Michel Manceau、Aloyse Degiron 等 7 位作者2014-08-26Optics Express

We demonstrate subwavelength electromagnetic resonators operating in the THz spectral range, whose spectral properties and spatial/angular patterns can be engineered in a similar way to an electronic circuit. We discuss the device concept, and we experimentally study the tuning of the resonant frequency as a function…

Metamaterials and Metasurfaces ApplicationsPhotonic and Optical DevicesTerahertz technology and applications

Perfect dual-band circular polarizer based on twisted split-ring structure asymmetric chiral metamaterial

Yongzhi Cheng、Rongzhou Gong、Zhengze Cheng 等 4 位作者2014-08-26Applied Optics

A near-perfect dual-band circular polarizer based on bilayer twisted, single split-ring resonator structure asymmetric chiral metamaterial was proposed and investigated. The simple bilayer structure with a 90° twisted angle allows for equalizing the orthogonal components of the electric field at the output interface w…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Microcrystalline Cellulose from Plant Wastes through Sodium Hydroxide-Anthraquinone-Ethanol Pulping

Olugbenga Oludayo Oluwasina、Labunmi Lajide、Bodunde Joseph Owolabi2014-08-26BioResources

Microcrystalline cellulose was prepared from wastes of Tithonia diversifolia, inflorescence stems of Musa sapientum, and Musa paradisiaca by soda-anthraquinone-ethanol pulping method. They were bleached by sodium chlorite and then alpha-cellulose was isolated, followed by preparation of microcrystalline cellulose. The…

Advanced Cellulose Research Studiesbiodegradable polymer synthesis and propertiesLignin and Wood Chemistry