Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Despite four additional electron-withdrawing substituents, the octahalogenated porphyrins 2 are more easily oxidized than their tetra-halogenated counterparts 1. This apparent paradox can be explained by the structures of the molecules: porphyrins 2 are almost planar, whereas in 1 steric interactions are minimized by…
A hollow sphere, constructed from VO5 square pyramids and PhPO3 tetrahedra, which encapsulates a chlorine atom—this is an apt description of the anion in 1 (structure shown on the right). At first glance this anion, with its spheroidal structure, appears similar to known polyoxoanions; however, closer inspection revea…
Der Entwurf neuartiger magnetischer Materialien auf molekularer Basis , die für eine Vielzahl von Anwendungen von Interesse sind, ist immer noch eine Kunst. Um ein makroskopisches ferro‐oder ferrimagnetisches Verhalten zu erzielen, ist es erforderlich‐unter Zugrundelegung von Modellen zur Spin‐Spin‐Kopplung‐, Material…
The Rayleigh scattering coefficients of fluorine (F) and GeO2 codoped silica glasses are investigated experimentally. It is found that the Rayleigh scattering coefficients of F and GeO2 codoped silica glasses increase linearly with GeO2 dopant concentration and parabolically with F dopant concentration.
Microstructure and domain structure of sintered Nd14DyFe69.5Co5AlCr2B7.5 magnets with different grain sizes are analysed. The domain structure observed is typical for materials with high uniaxial magnetocrystalline anisotropy. Moreover, the changes in the value of coercivity μ0JHC connected with the different grain si…
Li2B4O7 is a low-Z, tissue-equivalent material and several phosphors based on this material are proposed for use in dosimetry of ionizing radiations using thermoluminescence. The synthesis of this phosphor using boric acid is a bit tricky as the stoichiometry and the crystallinity of the product depend on several fact…
A new laser crystal Lu3Sc2Ga3O12:Nd3+ with ordered garnet structure is developed. Its stimulated emission at 1.0622 μm wavelength (4F3/2 → 4I11/2 generating channel) with laser-diode and Xe-flashlamp pumping at room temperature is excited. For prospecting spectroscopic and laser investigations with Nd3+ -ion doped cry…
The electronic and transport properties of a perfect amorphous graphitic carbon model constructed by Townsend et al. [Phys. Rev. Lett. 69, 921 (1992)] are studied by first-principles calculations within the local-density approximation. It is shown that such a random system with two-dimensional interaction in a three-d…
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” opt…
In order to determine the origin of the long-wavelength photoluminescence spectra of CdS-doped glasses, luminescence spectra from glasses doped with CdSx having various Cd to S ratios were examined. The intensity of the luminescence peak decreased with increasing sulfur content, which indicates that the luminescence c…
Two bimolecular layers forming a double-layered polytypic structure exist in a repeating unit along the stacking direction. The acyl chain inclines toward the ab plane by 27 o and the direction of the inclination is turned by 180 o at every stacking of bimolecular layers. One bimolecular layer has essentially the same…
Structures of the mutant p-hydroxybenzoate hydroxylases, Tyr201Phe, Tyr385Phe, and Asn300Asp, each complexed with the substrate p-OHB have been determined by X-ray crystallography. Crystals of these three mutants of the Pseudomonas aeruginosa enzyme, which differs from the wild-type Pseudomonas fluorescens enzyme at t…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheoretical and experimental investigation of internal reflection at thin copper films exposed to aqueous solutionsKenneth P. Ishida and Peter R. GriffithsCite this: Anal. Chem. 1994, 66, 4, 522–530Publication Date (Print):February 15, 1994Publication History Published onlin…
We report transport and magnetic properties for single-crystalline CaVO 3 , which are seriously affected by oxygen off-stoichiometry. The electrical resistivity of a stoichiometric sample is well fit by the relation ρ=ρ 0 + A T 2 in an extremely wide temperature range. Oxygen off-stoichiometry causes the systematic in…
High-energy ion-scattering spectroscopy, x-ray-photoemission spectroscopy, and low-energy electron diffraction (LEED) were used to study the growth of very thin Ti films on Al(110) surfaces at room temperature. The Al surface peak areas in the backscattering spectra of 0.96-MeV ${\mathrm{He}}^{+}$ ions, incident along…
Abstract A diatomic charge density distribution function may be partitioned into free atom and delocalization components. Integrating the electrostatic force on one of the nuclei as the atoms join to bond yields a repulsive atom superposition energy E r ( R ) and an attractive delocalization energy E d ( R ) which, wh…
We propose a model for porous silicon, an irregular structure obtained by removing some silicon atoms randomly from a perfect silicon crystal. It is shown by using two-dimensional clusters with a tight-binding model that this model exhibits the energy-gap widening and the nonexponential decay of the photoluminescence…
Classical trajectory calculations were employed to study diamond (100) surface reconstructions. Atomic forces were computed from two types of potential-energy functions. A quantum mechanical potential based on the semiempirical PM3 (parametric method number three) Hamiltonian was used to describe the central core of t…
Using a micro-Raman setup, in-plane Raman scattering was performed on short-period (001)-Si/Ge superlattices, and the complete phonon spectrum (longitudinal and transverse, optical and acoustic modes) could be studied. In the relevant wave-vector range, the in-plane dispersion was found to affect the frequencies of fo…
Single crystals of barium zirconium sulfide, Ba 3 Zr 2 S 7 , were prepared from BaS, Zr and S at 1323 K by using a BaCl 2 flux. The compound belongs to the Ruddlesden-Popper (A n+1 B n X 3n+1 ) family with A=Ba, B=Zr, X=S and n=2. It is isostructural to Sr 3 Ti 2 O 7 and crystallizes in alternately stacked double pero…