Materials Literature
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Pests, including insects, mites, nematodes and pathogens, are the major limiting factor in profitable crop production. Frequent application of pesticides has resulted in development of pest and disease resistance, accumulating residues in produce and environmental pollution. So there is a need for alternative approach…
In the present work, nano scaled zero valent irons (nZVI) were synthesized from the plant extract of under atmospheric conditions. The obtained iron nanoparticles are mainly in zero valent oxidation state. A systematic characterization of nZVI was performed using UV, XRD and SEM studies. The diameter of iron nanoparti…
We describe the fabrication of porous foams with shape memory triggering at body temperature. Employing a modified porogen-leaching technique, functionalized poly(ε-caprolactone) (PCL) and poly(ethylene glycol) (PEG) macromers are crosslinked via thiol-ene chemistry to generate highly porous foam scaffolds with shape…
Flexible and transparent electronic and optoelectronic devices have attracted more and more research interest due to their potential applications in developing portable, wearable, low-cost, and implantable devices. We have fabricated and studied high-performance flexible and transparent CdSe nanobelt (NB)/graphene Sch…
There has been a huge expansion in the laying of pipelines for the transmission of fossil fuels over large distances and in dire environments. Large diameter pipes can be manufactured by welding spirals of hot–rolled linepipe steels. This process has a cost advantage relative to one in which the steel is seam welded a…
Partially reduced graphene oxide (pRGO) was coated on carbon fibers by an anodic electrophoretic deposition (EPD). Coated-pRGO increased surface energy and wettability of carbon fiber. As a multi-functional sizing agent, pRGO enhanced both mechanical and electrical properties of the carbon fiber composite in spite of…
We study both the static properties and dynamic behavior of liquid water marbles coated with silica nanoparticles of varied hydrophobicity. The static properties are characterized by the variation of marble height and diameter with increasing marble volume, such that the effective surface tension γeff of the marble ca…
We report the fabrication of Resistor-Capacitor (RC) filters and field effect transistors (FETs) based on pencil drawings on paper, which contain turbostratic graphite crystallites as evidenced from Raman analysis. Pencil drawings have been employed as resistor and an ion gel, 1-butyl-3-methylimidazolium octyl sulfate…
Two major complications generally occur in blood-contacting devices, namely thrombus formation and microbial invasion and infection. Therefore, hemocompatible and antibiofouling surfaces, which function as barriers to bacterial and cell adhesion, are essential. Herein, we report the successful grafting of zwitterionic…
Nanofiber based scaffolds offer great promise in regeneration of various tissues including esophagus. Diseases of the esophagus such as malignancy and strictures require surgical intervention to repair the affected region using an appropriate substitute. Long gap esophageal atresia poses a clinical challenge to bridge…
The first examples of air-stable Co(II) paraCEST MRI contrast agents are reported. Amide NH protons on the complexes give rise to CEST peaks that are shifted up to 112 ppm from the bulk water resonance. One complex has multiple CEST peaks that may be useful for ratiometric mapping of pH.
Building on established supramolecular chemistry, metal coordination and organometallic chemistry have been widely explored for supramolecular polymers and nanostructures. Increasingly, research has demonstrated that this approach is promising for the synthesis of novel materials with functions and properties derived…
Ce3+/Mn2+-codoped NaCaBO3 single-phase color-tunable phosphors were synthesized by solid-state reaction, and their photoluminescence properties were investigated in detail. Under UV excitation, two main emission bands peaking at 400 and 610 nm were realized in the NaCa0.89BO3: 0.01Ce3+, 0.10Mn2+ phosphor on the basis…
We have successfully assembled graphene nanosheets into spherical shells using polystyrene spheres as templates. Compared with stacked planar graphene, the as-prepared graphene spherical shells have more free space in between the spheres, which results in a larger accessible surface area for adsorption of electrolyte…
A new composite solid oxide fuel cell anode material, SrTi1−xFexO3−δ mixed with Gd-doped ceria, was tested in La0.9Sr0.1Ga0.8Mg0.2O3−δ electrolyte-supported cells with La0.4Ce0.6O2 barrier layers and La0.6Sr0.4Fe0.8Co0.2O3 cathodes. The x = 0.7 composition had an anode polarization resistance of 0.17 Ω cm2, at 800 °C…
Near-IR (NIR) emitting semiconducting polymer dots (Pdots) with ultrabright fluorescence have been prepared for specific cellular targeting. A series of π-conjugated polymers were synthesized to form water dispersible multicomponent Pdots by an ultrasonication-assisted co-precipitation method. By optimizing cascade en…
We report on a wafer scale fabrication method of a three-dimensional plasmonic metamaterial with strong chiroptical response in the visible region of the electromagnetic spectrum. The system was comprised of metallic nanoparticles arranged in a helical fashion, with high degree of flexibility over the choice of the un…
We present a simple route towards a superhydrophobic graphene surface, which opens up possibilities for transparent flexible graphene-based electrodes with a non-wetting property. By tailoring the surface energy and surface roughness, superhydrophobic properties of graphene with a contact angle greater than 150° at an…
Reduction of VO2 resistance by nearly 3 orders of magnitude through H2 treatment was reported for supercapacitor application. A specific discharge capacitance of 300 F g(-1) and a specific energy density of 17 W h kg(-1) at a rate of 1 A g(-1) are demonstrated with long-term cycling stability, which is 4 times higher…
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