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Origin of the half-metallic band-gap in newly designed quaternary Heusler compounds ZrVTiZ (Z = Al, Ga)

Xiaotian Wang、Zhenxiang Cheng、Jianli Wang 等 8 位作者2016-01-01RSC Advances

In this work, first-principles calculations have been used to investigate the electronic structures, magnetic properties, and half-metallic nature of the newly designed quaternary Heusler compounds ZrVTiAl and ZrVTiGa.

Intermetallics and Advanced Alloy PropertiesMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties

Highly sensitive multifunctional recyclable Ag–TiO 2 nanorod SERS substrates for photocatalytic degradation and detection of dye molecules

Samir Kumar、Devesh K. Lodhi、Jaspal Singh2016-01-01RSC Advances

We report a facile method to fabricate novel and recyclable Ag nanoparticle decorated TiO 2 nanorod array substrates using a glancing angle deposition (GLAD) technique for photocatalysis and surface enhanced Raman scattering (SERS) applications.

Advanced Photocatalysis TechniquesGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Aggregation-induced emission of diarylamino-π-carborane triads: effects of charge transfer and π-conjugation

Yang‐Jin Cho、So‐Yoen Kim、Minji Cho 等 7 位作者2016-01-01Physical Chemistry Chemical Physics

Carborane-based donor-π-acceptor triads (D-π-A-π-D) bearing triarylamine moieties were synthesised. All the monomeric triads showed a blue-green emission in a dilute solution, which was assigned as an intramolecular charge-transfer (CT) emission. The intramolecular CT emission showed large Stokes shifts at a higher so…

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsBoron Compounds in Chemistry

Shape dependence of nanoceria on complete catalytic oxidation of o-xylene

Lian Wang、Yafei Wang、Yan Zhang 等 7 位作者2016-01-01Catalysis Science & Technology

CeO 2 nanorods exhibit the highest concentration of oxygen vacancy clusters for O 2 activation, guaranteeing the highest activity for o -xylene oxidation.

Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsAdvanced Nanomaterials in Catalysis

Photo-induced coupling reactions of tetrazoles with carboxylic acids in aqueous solution: application in protein labelling

Shan Zhao、Jianye Dai、Mo Hu 等 8 位作者2016-01-01Chemical Communications

The photo-induced reactions of diaryltetrazoles with carboxylic acids in aqueous solution were investigated. Besides measuring the apparent second-order rate constant and evaluating the functional group compatibility of these reactions, we further incorporated the tetrazoles into SAHA, leading to a new active-site-dir…

Innovative Microfluidic and Catalytic Techniques InnovationClick Chemistry and ApplicationsPhotochromic and Fluorescence Chemistry

Inhibition and disintegration of insulin amyloid fibrils: a facile supramolecular strategy with p-sulfonatocalixarenes

Meenakshi N. Shinde、N. Barooah、Achikanath C. Bhasikuttan 等 4 位作者2016-01-01Chemical Communications

We reveal the ability of p-sulfonatocalix[4/6]arene to effectively inhibit the fibril formation in human insulin and demonstrate its potential to disintegrate the mature fibrils, a promising supramolecular strategy to combat amyloidosis.

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesSupramolecular Self-Assembly in Materials

Sphere-like CoS with nanostructures as peroxidase mimics for colorimetric determination of H 2 O 2 and mercury ions

Haiguan Yang、Junqi Zha、Peng Zhang 等 6 位作者2016-01-01RSC Advances

CoS, which was prepared using a facile solvothermal method, and characterized using various analytical techniques, was demonstrated for the first time to exhibit intrinsic peroxidase-like activity.

Advanced biosensing and bioanalysis techniquesNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Titanium and Titanium Alloy Applications in Medicine

Mark J. Jackson、Janez Kopač、M. Balažic 等 6 位作者2016-01-01OpenAlex

Titanium is a transition metal. It is present in several minerals including rutile and ilmenite, which are well dispersed over the Earth’s crust. Even though titanium is as strong as some steels, its density is only half of that of steel. Titanium is broadly used in a number of fields, including aerospace, power gener…

Bone Tissue Engineering MaterialsOrthopaedic implants and arthroplastyTitanium Alloys Microstructure and Properties

Periodic micro-patterned VO 2 thermochromic films by mesh printing

Qi Lu、Chang Liu、Ning Wang 等 6 位作者2016-01-01Journal of Materials Chemistry C

This work demonstrates a novel approach that fabricates periodic, micro-patterned structures of VO 2 using a facile screen printing method with enhanced thermochromic properties.

Transition Metal Oxide NanomaterialsPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

The evolution of gadolinium based contrast agents: from single-modality to multi-modality

Li Zhang、Ruiqing Liu、Hui Peng 等 6 位作者2016-01-01Nanoscale

Gadolinium-based contrast agents are extensively used as magnetic resonance imaging (MRI) contrast agents due to their outstanding signal enhancement and ease of chemical modification. However, it is increasingly recognized that information obtained from single modal molecular imaging cannot satisfy the higher require…

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesAtomic and Subatomic Physics Research

A magnetic/fluorometric bimodal sensor based on a carbon dots–MnO 2 platform for glutathione detection

Yang Xu、Xi Chen、Ran Chai 等 6 位作者2016-01-01Nanoscale

A novel magnetic/fluorometric bimodal sensor was built from carbon dots (CDs) and MnO2. The resulting sensor was sensitive to glutathione (GSH), leading to apparent enhancement of magnetic resonance (MR) and fluorescence signals along with visual changes. The bimodal detection strategy is based on the decomposition of…

Advanced biosensing and bioanalysis techniquesCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Multitechnique investigation of Dy 3 – implications for coupled lanthanide clusters

Maren Gysler、Fadi El Hallak、Liviu Ungur 等 15 位作者2016-01-01Chemical Science

calculations is required to arrive at a full understanding of the properties of this complex, and potentially of other magnetically coupled lanthanide complexes.

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesInorganic Chemistry and Materials

Enhancing thermoelectric performance of Bi 2 Te 3 -based nanostructures through rational structure design

Min Hong、Zhi‐Gang Chen、Lei Yang 等 4 位作者2016-01-01Nanoscale

Nanostructuring has been successfully employed to enhance the thermoelectric performance of Bi2Te3 due to its obtained low thermal conductivity. In order to further reduce the thermal conductivity, we designed a hierarchical nanostructure assembled with well-aligned Bi2Te3 nanoplates using Te nanotubes as templates by…

Advanced Thermoelectric Materials and DevicesTopological Materials and PhenomenaAdvanced Thermodynamics and Statistical Mechanics

A new methylviologen-templated zinc gallophosphate zeolite with photo-/thermochromism, fluorescent and photoelectric properties

Chunyao Tao、Junbiao Wu、Yan Yan 等 5 位作者2016-01-01Inorganic Chemistry Frontiers

The second methylviologen (MV)-templated zeolite JU104 exhibits interesting photochromism and thermochromism with multi-colours, as well as fluorescent and photoelectric properties.

Advanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and Applications

Frequency and voltage dependent profile of dielectric properties, electric modulus and ac electrical conductivity in the PrBaCoO nanofiber capacitors

S. Demirezen、Ahmet Kaya、Seçkin Altındal Yerişkin 等 5 位作者2016-01-01Results in Physics

In this study, praseodymium barium cobalt oxide nanofiber interfacial layer was sandwiched between Au and n-Si. Frequency and voltage dependence of ε′, ε′, tanδ, electric modulus (M′ and M″) and σac of PrBaCoO nanofiber capacitor have been investigated by using impedance spectroscopy method. The obtained experimental…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationSemiconductor materials and interfaces

Plasmon-free SERS detection of environmental CO 2 on TiO 2 surfaces

Nicolò Bontempi、Luca Carletti、Costantino De Angelis 等 4 位作者2016-01-01Nanoscale

SiO2/TiO2 core/shell beads (T-rex) were designed, fabricated and tested for Raman detection of environmental CO2 under real-working conditions, as those encountered, for example, in solar-to-fuel conversion reactions. The exploitation of light trapping and morphology dependent resonances was crucial for extending the…

Advanced Photocatalysis TechniquesGold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And Properties

Predictive analytics for crystalline materials: bulk modulus

Al’ona Furmanchuk、Ankit Agrawal、Alok Choudhary2016-01-01RSC Advances

The machine learning-based generalized model developed for forecasting bulk moduli of various types of stoichiometric and non-stoichiometric crystalline materials. The web application (ThermoEl) deploying the developed predictive model is available for public use.

Machine Learning in Materials ScienceGeochemistry and Geologic MappingX-ray Diffraction in Crystallography