Materials Literature
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Four dyad systems composed of a central truxene and either one or three β-substituted zinc(II) porphyrins (ZnP: TruZnP (7) and TruTriZnP (9)) or free-bases (H 2 P: TruP (6) and TruTriP (8)) have been prepared. The presence of β-methyl groups minimizes π-conjugation through the quasi right angle made by the porphyrin a…
Low-layered, transparent graphene is accessible by a chemical vapor deposition (CVD) technique on a Ni-catalyst layer, which is deposited on a <100> silicon substrate. The number of graphene layers on the substrate is controlled by the grain boundaries in the Ni-catalyst layer and can be studied by micro Raman analysi…
The self-assembly of two enantiomerically pure hexa(oligo(p-phenylene vinylene))-substituted benzenes having 24 stereocenters was studied in pure methylcyclohexane (MCH) and in a mixture of MCH/toluene (4:1). Irrespective of the solvent a cooperative supramolecular polymerization mechanism was determined for these sta…
Abstract The unique mixed conduction aspect has much to be explored for ceramic fuel/steam electrodes suggested for higher chemical stability than cermets in SOFC/SOEC applications. Typical symmetric cell configuration of the thin ceramic electrodes on the electrolytes was shown to be a versatile configuration of the…
<div class="section abstract"><div class="htmlview paragraph">It is discussed the use of ADI (Austempered Ductile Iron) for gears. The gears were produced from continuous cast iron bars, heat treated for grade 3 of ASTM ADI Standard A897M-06 (UTS ≻1200 MPa), and compared to carburized steel AISI 8620 and t…
Using global-minima search methods based on the density functional theory calculations of (AlH(3))(n) (n = 1-8) clusters, we show that the growth pattern of alanes for n ≥ 4 is dominated by structures containing hexa-coordinated Al atoms. This is in contrast to the earlier studies where either linear or ring structure…
Using the microwaves energy new organic polymers were synthesized by radicalic polymerization. These new organic compounds have anti-corrosive and anti-scale properties and for this reason, were used for cooling water systems protection. We presume that, these new organic polymers inhibit corrosion of carbon steel by…
With ionic conductivities superior to conventional doped zirconia and ceria at intermediate temperatures (IT, 700–800 °C), bismuth oxide (BiO 1.5 ) materials based on the defect fluorite structure are promising electrolyte candidates for solid oxide fuel cells (SOFCs) operating at reduced temperatures. In order to inv…
Abstract To improve the electrochemical performance of Pd‐based catalysts for formic acid oxidation, a carbon supported nanoporous PdNi catalyst is prepared by dealloying high‐Ni‐content PdNi alloy nanoparticles in acid solution. The structure of nanoporous PdNi/C catalyst is characterized by X‐ray diffraction, transm…
We have monitored the phase transformation from a Sandia octahedral molecular sieve Na 2 Nb 2 O 6 –H 2 O to a piezoelectric NaNbO 3 nanowire through in situ X-ray diffraction (XRD) and transmission electron microscopy (TEM) measurements at high temperatures. After dehydration at 288 °C, the Na 2 Nb 2 O 6 –H 2 O become…
Abstract Sol–gel films of tetraethoxysilane (TEOS), phenyltriethoxysilane (PTES) and phenyltrimethoxysilane (PTMS) were prepared on aluminium and aluminium alloy AA7075 and characterised. The corrosion inhibition properties of uncoated and coated specimens were evaluated with potentiodynamic polarisation scan, linear…
In this study, an operating strategy which uses focused beam reflectance measurement (FBRM) to achieve consistent product quality in a combined antisolvent-cooling crystallization process is developed. The proposed operating strategy involves rapid generation of seed crystals by antisolvent addition, which is followed…
Thermoplastic polyurethane (TPU)/single-walled carbon nanotube (SWCNT) nanocomposite films were prepared using 1,6-hexane diisocyanate and hydroxyl-terminated polybutadiene (HTPB) in tetrahydrofuran with various concentrations of SWCNTs. The interaction between polyurethane (PU) and SWCNTs in nanocomposite was studied…
High density three-dimensional AZO/Al2O3/AZO nanocapacitor arrays have been fabricated for energy storage applications. Using atomic layer deposition technique, the stack of AZO/Al2O3/AZO has been grown in the porous anodic alumina template which is directly formed on the Si substrate. The fabricated capacitor shows a…
Abstract The synthesis and the structural and magnetic characterization of two new cobalt(II) compounds [Co 4 (TTA) 4 (OMe) 4 (EtOH) 4 ] ( 1 ) and [Co 4 (TTA) 4 (OMe) 4 (MeOH) 4 ] ( 2 ) (TTA = 4,4,4‐trifluoro‐1‐thienoyl‐2,4‐butanedione) are reported. The structures consist of a tetranuclear Co 4 O 4 core in a cubane f…
Abstract The aim of this study is to investigate the corrosion behaviour of three ZrTi alloys (denoted with Zr5Ti, Zr25Ti, and Zr45Ti) in 0.9% NaCl solution. For comparison, cp‐Ti was also investigated. In order to study the localized corrosion resistance and corrosion behavior at open circuit potential versus time, t…
Recent developments in nanotechnology have provided new tools for both cancer imaging and treatment. The functionalization of the nanocarrier based drugs using biological ligands allows increasing specificity of drug targeting enhancing efficacy and reducing side effects. In this paper some current nanocarrier based d…
Abstract Pitting corrosion is one of the most common mechanisms of surface damage on stainless steels. Electrochemical methods have been preferentially applied for the evaluation of the pitting corrosion resistance of stainless steels in the laboratory. Nevertheless, some of them are not reliable enough and in general…
We successfully controlled the crystallographic surface of ZnSn(OH)(6) crystals and systematically obtained ZnSn(OH)(6) crystals in different shapes including cubes, truncated cubes, cuboctahedrons, truncated octahedrons, and octahedrons using a simple solvothermal method in a methylcellulose (MC) ethanol/water soluti…
The facile axial ligand exchange properties of gallium(III) protoporphyrin IX in methanol solution were utilized to explore self-association interactions by NMR techniques. Structural changes were observed, as well as competitive behavior with the ligands acetate and fluoride, which differed from that seen with the sy…