Materials Literature
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A detailed parametric study quantifying the effect of various operating parameters on the reduction of nitric oxide (NO) in the presence of oxygen by inexpensive carbons was carried out. The selectivity of the carbon−NO reaction over the parasitic carbon−oxygen reaction was measured by a global selectivity parameter,…
The effects of oxygen on the photochemical properties of ruthenium(II) complexes in solution and in polymers are reported. In solution, the complex is actually protected from decomposition by the presence of oxygen as a result of deactivation of the complex by oxygen quenching before it can undergo ligand loss by mono…
Dimeric azobenzene-appended cholesterol organogel 1 was synthesized and its gelation ability was evaluated in organic solvents. It can gelate 1-hexanol, 1-octanol, toluene, m -xylene, and p -xylene, under 5.0 wt %, indicating that 1 acts as a versatile gelator of various organic solvents. To obtain visual insights int…
Azobenzenophanes, in which two (2), three (3), and four (4) azobenzene units are connected cyclically by methylene linkers at the meta positions, were synthesized. The effect of ring strain on the structure and the photochemical and the thermal isomerization of azobenzene were investigated. Complex formation with gues…
We report the multistep electrolytic process for the synthesis of high Tc single phase HgBa2Ca2Cu3O8+ (Hg-1223) superconducting films. The process includes : i) deposition of BaCaCu precursor alloy, ii) oxidation of BaCaCu films, iii) electrolytic intercalation of Hg in precursor BaCaCuO films and iv) electrochemical…
By using the projection operator technique it is observed that the strong Hund's rule coupling and s-d interaction in transition metal elements may lead to an effective coupling between the spin current and spin spirality. As a result, the spin spirality can be regarded as a driving force to produce a spin current. Th…
The phase-field method is reviewed from the general perspective of converting a free boundary problem into a set of coupled partial differential equations. Its main advantage is that it avoids front tracking by using phase fields to locate the fronts. These fields interpolate between different constant values in each…
Abstract The effects of boiling water on the mechanical and thermal properties and morphologies of polycarbonate (PC), PC/acrylonitrile–butadiene–styrene resin (PC/ABS), and PC/low‐density polyester (PC/LDPE) blends (compositions of PC/ABS and PC/LDPE blends were 80/20) were studied. PC and the PC/ABS blend had a tran…
Abstract The hot stretching of thick, extruded sheets at high temperatures is a very important process in the production of finished biaxially oriented polypropylene (BOPP) films with special inner structures. Through a simulation of hot stretching in the machine direction (MD) of the processing of BOPP films, it was…
Abstract Grafting of itaconic acid (IA) onto low‐density polyethylene (LDPE) was performed by reactive extrusion where the initiator was dicumyl peroxide, and the neutralizing agents (NAs) were zinc oxides and hydroxides as well as magnesium oxides and hydroxides. The carboxyl groups were neutralized in molten LDPE di…
Abstract Ethylene–propylene–diene terpolymer (EPDM) was modified by bromination reaction. Blending the resulting brominated EPDM with natural rubber (STR5L) and blending the unmodified EPDM with STR5L at various compositions were carried out. The rheological properties of the blends were investigated using a capillary…
Abstract A copolymer (4‐HAOF) prepared by condensation of 4‐hydroxyacetophenone and oxamide with formaldehyde in the presence of an acid catalyst proved to be a selective chelating ion‐exchange copolymer for certain metals. Chelating ion‐exchange properties of this copolymer were studied for Fe 3+ , Cu 2+ , Ni 2+ , Co…
Abstract Polyamide‐6 (PA6)/polybutadiene (PB) block copolymers were synthesized with macroactivators (MAs) based on hydroxyl‐terminated polybutadiene functionalized with diisocyanates and having three N ‐acyllactam chain‐growing centers per molecule. Two different diisocyanates, hexamethylene diisocyanate and isophoro…
Abstract Fine particles of barium ferrite (BaFe 12 O 19 ) were synthesized by the conventional ceramic technique. These materials were then characterized by the X‐ray diffraction method and incorporated in the natural rubber matrix according to a specific receipe for various loadings of ferrite. The rubber ferrite com…
Abstract An amphiphilic graft copolymer, hydroxypropylcellulose‐graft‐poly(ε‐caprolactone) (HPC‐ g ‐PCL), was synthesized by bulk polymerization without a catalyst and characterized with one‐dimensional and two‐dimensional NMR spectroscopy. Molar substitution of ε‐caprolactone on HPC (MS CL ) was estimated by both gra…
Abstract A series of polyamides were synthesized by the direct polycondensation of 2,2‐bis[4‐(4‐amino‐2‐fluorophenoxy)phenyl]hexafluoropropane with various commercially available dicarboxylic acids such as terephthalic acid, isophthalic acid, 5‐ t ‐butyl isophthalic acid, and 2,6‐naphthalene dicarboxylic acid. The syn…
Abstract The conductance behavior of copolymers of aniline and thiophene with varying concentration ratios were studied in acetonitrile/tetrabutylammonium tetrafluoroborate using cyclic voltammetry and in situ conductance measurements. These studies revealed that compared with homopolymers, the copolymers have extende…
Abstract The application of rubber seed oil (RSO) and epoxidized RSO (ERSO) as a plasticizer in acrylonitrile butadiene rubber (NBR) was studied using RSO and ERSO with different levels of epoxidation. The results indicated that ERSO could be used as a less leachable and low volatility plasticizer for NBR. The use of…
Broadband dielectric measurements were carried out on di-n-butyl phthalate (DBP) under isothermal conditions at hydrostatic pressures up to 1.6 GPa. A comparison of the dielectric relaxation times with the viscosity revealed that no breakdown of the Einstein-Debye relation is induced by high compression. This absence…
Abstract In this study, the effect of the high‐energy mechanical milling of a mixture of poly(vinyl chloride) (PVC) with zinc borate (ZB) or ZB–aluminum trihydrate (ATH), a mixture of ZB and ATH, on the flame‐retardant and mechanical properties of ZB and ZB–ATH filled PVC was examined. The high‐energy mechanical milli…