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Magnetic property enhancement of melt-spun Pr2Fe23B3 ribbons with dilute Ti substitution

H. W. Chang、Chiung‐Hui Chiu、W.C. Chang2003-06-19Applied Physics Letters

The phase evolution and magnetic properties of Pr2Fe23B3 and Pr2(Fe0.975Ti0.025)23B3 melt-spun ribbons have been investigated. For Pr2Fe23B3 spun at 25 m/s, the magnetically hard Pr2Fe14B phase coexists with α-Fe, Pr2Fe23B3, and Fe3B when annealed at temperatures above 700 °C, while merely two phases, namely, Pr2Fe14B…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

Effects of uniaxial stress on dielectric properties lead magnesium niobate–lead zirconate titanate ceramics

Rattikorn Yimnirun、Supon Ananta、Ekarat Meechoowas 等 4 位作者2003-06-19Journal of Physics D Applied Physics

Effects of uniaxial stress on the dielectric properties of ceramics in lead magnesium niobate–lead zirconate titanate (PMN–PZT) system are investigated. The ceramics with a formula ( x )Pb(Mg 1/3 Nb 2/3 )O 3 –(1− x )Pb(Zr 0.52 Ti 0.48 )O 3 or ( x )PMN–(1 − x )PZT when x = 0.0, 0.1, 0.3, 0.5, 0.7, 0.9, and 1.0 are prep…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Residual stress analysis in ferroelectric Pb(Zr0.52Ti0.48)O3 thin films fabricated by a sol-gel process

Kui Yao、Shuhui Yu、Francis Eng-Hock Tay2003-06-19Applied Physics Letters

Ferroelectric Pb(Zr0.52Ti0.48)O3 (PZT) films were prepared by a modified sol-gel process, in which polyethylene glycol (PEG) was added to the precursor solutions. An x-ray diffraction (XRD) method that detected the d(123) variation associated with the change in the incline angle ψ of the plane (123) was developed to q…

Ferroelectric and Piezoelectric MaterialsMetal and Thin Film MechanicsAcoustic Wave Resonator Technologies

Phase diagram and influence of defects in the double perovskites

José L. Alonso、L. A. Fernández、F. Guinea 等 5 位作者2003-06-19Physical review. B, Condensed matter

The phase diagram of the double perovskites of the type ${\mathrm{Sr}}_{2\ensuremath{-}x}{\mathrm{La}}_{x}{\mathrm{FeMoO}}_{6}$ is analyzed, with and without disorder due to antisites. In addition to an homogeneous half metallic ferrimagnetic phase in the absence of doping and disorder, we find antiferromagnetic phase…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Flexible low-voltage electro-optic polymer modulators

Hyun-Chae Song、Min‐Cheol Oh、Seh‐Won Ahn 等 6 位作者2003-06-19Applied Physics Letters

A high-performance electro-optic (EO) polymer modulator on a flexible substrate was fabricated using a polymer substrate layer lift-off method. The SU-8 polymer has widely different adhesion properties on Si and gold substrates that makes selective lift-off possible. The flexible EO polymer modulators on a 100-μm poly…

Photonic and Optical DevicesNonlinear Optical Materials ResearchSemiconductor Lasers and Optical Devices

Synthesis of Coinage-Metal Nanoparticles from Mesityl Precursors

S.D. Bunge、Timothy J. Boyle、T.J. Headley2003-06-19Nano Letters

An anhydrous route for the synthesis of amine-capped coinage-metal nanoparticles (NP) has been developed using coinage-metal mesityl (mesityl = 2,4,6-Me 3 C 6 H 2 ) derivatives. Under an argon atmosphere, crystalline [Cu(μ-mesityl)] 5, [Ag(μ-mesityl)] 4, and [Au(μ-mesityl)] 5 were readily dissolved in octylamine (0.3…

Molecular Junctions and NanostructuresNanocluster Synthesis and ApplicationsNanomaterials for catalytic reactions

Intrinsic viscosity dependence on polymer molecular weight and fluid temperature

Todd S. Rushing、Roger D. Hester2003-06-19Journal of Applied Polymer Science

Abstract Experimental solution intrinsic viscosity responses to temperature and polymer molecular weight variations were used to test the modeling capability of a simplified intrinsic viscosity equation. The multiple linear equation contains three parameters that are related to the thermodynamic properties of a polyme…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Factors influencing the small‐scale melt spinning of poly(ε‐caprolactone) monofilament fibres

Anodar Charuchinda、Robert Molloy、Jintana Siripitayananon 等 5 位作者2003-06-19Polymer International

Abstract Some of the main factors affecting the small‐scale melt spinning of poly(ε‐caprolactone), PCL, monofilament fibres have been studied. These factors included spinning temperature, extrusion rate, take‐up rate and draw ratio. The underlying influence of the polymer's own characteristic properties, in particular…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Morphology and rheological properties of nanocomposites based on nitrile rubber and organophilic layered silicates

Jin‐Tae Kim、Taeg‐su Oh、Dong‐ho Lee2003-06-19Polymer International

Abstract Organo‐montmorillonite/nitrile rubber (NBR) nanocomposites were prepared by a melt intercalation process. The characteristics of NBR nanocomposites were determined by an oscillating disk rheometer and transmission electron microscopy. The cure characteristics were investigated according to the change in clay…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Synthesis and characterisation of branched and partially crosslinked poly(ethylene terephthalate)

Dimitrios Ν. Bikiaris、GP Karayannidis2003-06-19Polymer International

Abstract In the present study, a series of branched and partially crosslinked poly(ethylene terephthalate) (PET) samples were prepared by the two‐stage melt polycondensation method, using different amounts of trimethyl trimellitate (TMT) as polyfunctional monomer. The samples were characterised with respect to intrins…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Fabrication and properties of poly(propylene carbonate)/calcium carbonate composites

Xiaodong Li、S. C. Tjong、Yuezhong Meng 等 4 位作者2003-06-19Journal of Polymer Science Part B Polymer Physics

Abstract Composites of poly(propylene carbonate) (PPC) reinforced with micrometric and nanometric calcium carbonate particles were prepared via melt mixing followed by compression molding. The morphology and mechanical and thermal behaviors of the composites were investigated. Static tensile tests showed that the tens…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesPolymer composites and self-healing

Structure and electronic properties of a nongraphitic disordered carbon system and its heat-treatment effects

Kazuyuki Takai、Meigo Oga、Hirohiko Sato 等 8 位作者2003-06-19Physical review. B, Condensed matter

The heat-treatment effect on electronic properties is investigated in relation to structural change for pulsed-laser-deposited amorphous carbon thin films having ${\mathrm{sp}}^{2}{/sp}^{3}$ ratio $\ensuremath{\approx}9.$ The heat treatment at temperatures 200--400 $\ifmmode^\circ\else\textdegree\fi{}\mathrm{C}$ incre…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Theoretical study of the ambient-pressure dependence of sonochemical reactions

Kyuichi Yasui、Toru Tuziuti、Yasuo Iida 等 4 位作者2003-06-19The Journal of Chemical Physics

Computer simulations of bubble oscillations are performed for various ambient pressures in order to study the mechanism of the ambient-pressure dependence of sonochemical reactions: sonochemiluminescence of aqueous luminol solutions [T. Tuziuti et al., J. Chem. Phys. 116, 6221 (2002)] and the oxidation of iodide [A. H…

Ultrasound and Hyperthermia ApplicationsUltrasound and Cavitation PhenomenaPhotoacoustic and Ultrasonic Imaging

Magnetic and conducting Fe3O4–polypyrrole nanoparticles with core‐shell structure

Jianguo Deng、Yuxing Peng、Chuanlan He 等 6 位作者2003-06-19Polymer International

Abstract Magnetic and conducting Fe 3 O 4 –polypyrrole nanoparticles with core‐shell structure were prepared in the presence of Fe 3 O 4 magnetic fluid in aqueous solution containing sodium dodecylbenzenesulfonate (NaDS) as a surfactant and dopant. Both the conductivity and magnetization of the composites depend stron…

Electrochemical sensors and biosensorsConducting polymers and applicationsPorphyrin and Phthalocyanine Chemistry

Ultrasonic synthesis and optical properties of Au/Pd bimetallic nanoparticles in ethylene glycol

Canxia Kan、Weiping Cai、Cuncheng Li 等 5 位作者2003-06-19Journal of Physics D Applied Physics

Au/Pd bimetallic nanoparticles, even with core–shell structure, were synthesized by successive and simultaneous sonochemical irradiation of their metal precursors in ethylene glycol, respectively. In the successive method, Pd clusters or nanoparticles are first obtained by reduction of Pd(NO 3 ) 2 , followed by adding…

Gold and Silver Nanoparticles Synthesis and Applicationsnanoparticles nucleation surface interactionsLaser-Ablation Synthesis of Nanoparticles

Spatial anisotropy of the exciton level in CaF$_2$ at 11.1 eV and its relation to the weak optical anisotropy at 157 nm

M. Letz、L. Parthier、A. Gottwald 等 4 位作者2003-06-19arXiv

The energy level of the exciton around the $Γ$ point in CaF$_2$ at about 11.1 eV was investigated by reflection measurements on oriented surfaces using dispersed synchrotron radiation. A small but clear energy shift of the exciton resonance structure was observed which depends on the crystal orientation with respect t…

Materials ScienceStrongly Correlated Electrons

Electronic excitations and the tunneling spectra of metallic nanograins

Gustavo A. Narvaez、George Kirczenow2003-06-19arXiv

Tunneling-induced electronic excitations in a metallic nanograin are classified in terms of {\em generations}: subspaces of excitations containing a specific number of electron-hole pairs. This yields a hierarchy of populated excited states of the nanograin that strongly depends on (a) the available electronic energy…

Materials Science

Quantum model of phonon transport and heat conductivity in carbon nanoclusters and nanotubes

E. Ya. Glushko、V. N. Evteev、M. V. Moiseenko 等 5 位作者2003-06-19arXiv

A complex approach phonon quantum discrete model (PQDM) was developed to describe dynamics, kinetics and statistics of phonons in carbon nanostructures with zero-chirality of both zig-zag and armchair geometry. The model allows include into the pure phonon problem existing interaction with others subsystems: electrons…

Mesoscale and Nanoscale PhysicsMaterials Science

X-Ray Studies of the Structure and Electronic Behavior of Alkanethiolate-Capped Gold Nanoparticles: The Interplay of Size and Surface Effects

Peng Zhang、Tsun‐Kong Sham2003-06-19OpenAlex

We report a study of the structure and electronic properties of a series of thiol-capped Au nanoparticles (NP) of nominal sizes of 1.6, 2.4, and 4.0 nm. Transmission electron microscopy, x-ray powder diffraction, x-ray absorption fine structure, and x-ray photoemission spectroscopy have been used to investigate the si…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesMolecular Junctions and Nanostructures

Carbon dissolution and diffusion in ferrite and austenite from first principles

De‐en Jiang、Emily A. Carter2003-06-19OpenAlex

We perform density-functional theory (DFT) calculations of carbon dissolution and diffusion in iron, the latter being a typical example of interstitial diffusion. The Kohn-Sham equations are solved with periodic boundary conditions and within the projector-augmented-wave formalism, using the generalized gradient appro…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsFusion materials and technologies