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The Stability of Fe-Mg Chlorites in Hydrothermal Solutions: Ii. Thermodynamic Properties

Stephen U. Aja2002-10-01Clays and Clay Minerals

Abstract The hydrothermal stabilities of a low-Fe clinochlore and a high-Mg chamosite, in the presence of kaolinite, were investigated recently at T ⩽ 200°C and <mml:math xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mnf="http://cambridge.org/core/manifest" xmlns:cup="http://contentservices.cambridge.org" xmlns:mml…

Clay minerals and soil interactionsMine drainage and remediation techniquesChemical and Physical Properties in Aqueous Solutions

Small-angle x-ray scattering in a carbon-sulfur nanocomposite produced from bulk nanoporous carbon

É. A. Smorgonskaya、R. N. Kyutt、V. B. Shuman 等 6 位作者2002-10-01Physics of the Solid State

A new nanocomposite material containing approximately 50 vol % S is prepared by filling pores of bulk nanoporous carbon samples with sulfur. The initial nanoporous carbon samples are synthesized from polycrystalline α-SiC through the chemical reaction. A comparative investigation of small-angle x-ray scattering (SAXS)…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchX-ray Diffraction in Crystallography

ESR and Photo-ESR Study of Defects in CVD Diamond

Konstantin Iakoubovskii、A. Stesmans、Miloš Nesládek 等 4 位作者2002-10-01physica status solidi (a)

Two hydrogen and two Si-related defect centers were detected and characterized by electron spin resonance (ESR) in diamond films grown by chemical vapor deposition. Observation of hyperfine structure, combined with illumination and polishing treatments, suggests that the KUL2 and KUL9 ESR centers originate from two ch…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Photochromic characteristics of monodisperse microcapsules containing azobenzene derivative-doped nematic liquid crystals

No-Hyung Park、Sung-Ll Park、Kyung‐Do Suh2002-10-01Liquid Crystals

Highly mono-sized dye-doped liquid crystal (LC) microcapsules were prepared by the solute codiffusion method for application in photoswitchable devices. Azobenzene derivatives, which can be photoisomerized by irradiation with UV (366 nm) and visible (433 nm) light, were used as a photoresponsive dichroic dye. The micr…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Titanium dioxide photocatalysed oxidation of plasticisers in thin poly(vinyl chloride) films

Justin Searle、David Worsley2002-10-01Plastics Rubber and Composites Macromolecular Engineering

A closed system incorporating FTIR continuous monitoring and GC-MS sampling has been developed to study the generation under UVA illumination of volatile photodegradation products from model plasticised and TiO2 pigmented films. The presence of the plasticiser dibutyl adipate (DBA), at levels of 0-88 phr, has been sho…

Advanced Polymer Synthesis and CharacterizationMicroplastics and Plastic PollutionPolymer Science and PVC

Synthesis of nanosize PZT powders by pulsed wire discharge

Yoshiaki Kinemuchi、Tadashi Ikeuchi、Takahiro Suzuki 等 6 位作者2002-10-01IEEE Transactions on Plasma Science

Nanosize ferroelectric powders of Pb(Zr,Ti)O/sub 3/ (PZT) have been successfully synthesized by pulsed wire discharge. This has been achieved by the evaporation of Pb, Zr, and Ti wires simultaneously. Since these metals have considerable difference at the boiling point, instant heating by using pulsed-power technology…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesElectrical and Thermal Properties of Materials

Geneses of Cobaltic Oxide

Jin‐Fa Huang、Aina Hung、Chen‐Bin Wang 等 4 位作者2002-10-01Journal of the Chinese Chemical Society

Abstract A sample of cobalt oxide with cobalt ions in a highly oxidative state, p‐Co 2 O 3 , was prepared from Co(NO 3 ) 2 (aq) through a precipitation by NaOH and an oxidation by H 2 O 2 . The prepared p‐Co 2 O 3 was characterized as a nonstoichiometric sample with a chemical formula of Co 3+ 0.96 Co 4+ 0.04 O 2− 1.5…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsCopper-based nanomaterials and applications

Phase diagrams and physical properties of binary ferroelectric mixtures based on a series of chiral α-cyanocinnamate derivatives

Á. Vajda、Miroslav Kašpar、Věra Hamplová 等 6 位作者2002-10-01Liquid Crystals

We report a detailed investigation of binary mixtures composed of members of the homologous series of (S)-4′-(2-n-alkoxypropanoyloxy)biphenyl-4-yl 4-n-alkoxy- f-cyanocinnamates. The phase transition curves for these mixtures have no minima. On the contrary, eutectic behaviour was obtained if the members of this homolo…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Oligophenylazomethines: synthesis, structure, electrochemical property and photocyclization

Masayoshi Higuchi、Kimihisa Yamamoto2002-10-01Polymers for Advanced Technologies

Abstract Oligophenylazomethines (OPAs) and the aniline‐capped OPAs (OPA's) as soluble model compounds of polyphenylazomethine (PPA) were synthesized via dehydration of 4‐aminobenzophenone in the presence of TiCl 4 or PTS as a Lewis acid. The 1 H‐NMR spectra of OPAs revealed that OPAs have some isomers, which are based…

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

GEOMETRIC DIRECT MINIMIZATION OF HARTREE–FOCK CALCULATIONS INVOLVING OPEN SHELL WAVEFUNCTIONS WITH SPIN RESTRICTED ORBITALS

Barry D. Dunietz、Troy Van Voorhis、Martin Head‐Gordon2002-10-01Journal of Theoretical and Computational Chemistry

Recently, we have introduced a method based on geometric considerations, termed geometric direct minimization (GDM), to achieve robust convergence of self consistent field calculations. GDM was limited to calculations involving either spin-unrestricted orbitals or closed shell systems. We report the extension of the G…

Magnetism in coordination complexesMatrix Theory and AlgorithmsAdvanced NMR Techniques and Applications

On the role played by bending vibrations in heat transfer in layered crystals

Н. А. Абдуллаев、Р А Сулейманов、M. A. Aldzhanov 等 4 位作者2002-10-01Physics of the Solid State

The temperature dependences of the thermal conductivity of layered crystals (LCs) of graphite, boron nitride, gallium sulfide, etc., are analyzed. It is shown that the bending branch of vibrations typical of LCs determines the behavior of the thermal conductivity only in the region of its increase. The decrease in the…

Thermal properties of materialsThermography and Photoacoustic TechniquesThermal Radiation and Cooling Technologies

Local Piezoelectric Response in Bismuth-Based Ferroelectric Thin Films Investigated by Scanning Force Microscopy

Desheng Fu、Kazuyuki Suzuki、Kazumi Kato2002-10-01Japanese Journal of Applied Physics

Scanning force microscopy (SFM) has been used to probe the local polarization state and piezoelectric properties of ferroelectric films. The conductive SFM tip was employed as a movable top electrode to detect the piezoresponse in the film induced by an ac voltage. Our measurements reveal a spatial dependence of the p…

Ferroelectric and Piezoelectric MaterialsForce Microscopy Techniques and ApplicationsAcoustic Wave Resonator Technologies

The role of niobium as microalloying element in electrical sheet

Klaus Hulka、Constantin M. Vlad、Ana Doniga2002-10-01Steel Research

The processing route of grain oriented electrical sheet was simulated by laboratory trials. Besides MnS, the effect of AIN and NbC as an inhibitor phase in 3 % silicon steel was also investigated. In the hot strip material the niobium microalloyed steel showed the highest volume fraction of the {110}&lt;001&gt; Goss t…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMagnetic Properties and Applications

Influence of Interaction between Neighboring Oxygen Ions on Phase Stability in Cubic Zirconia

Akihide Kuwabara、Junji Katamura、Yuichi Ikuhara 等 4 位作者2002-10-01Journal of the American Ceramic Society

The electronic structures of undoped c ‐ and t ‐ZrO 2 were calculated by a first‐principles molecular orbital method. A preliminary analysis revealed that experimental energy‐loss near‐edge structure profiles obtained in ZrO 2 –8 mol% Y 2 O 3 could be satisfactorily explained from the present theoretical calculation.…

Advancements in Solid Oxide Fuel CellsNuclear materials and radiation effectsElectronic and Structural Properties of Oxides

Anticoagulant Activity of Immobilized Heparin on the Polypropylene Nonwoven Fabric Surface Depending upon the pH of Processing Environment

Yu‐Chang Tyan、Jiunn‐Der Liao、Yi-Te Wu 等 4 位作者2002-10-01Journal of Biomaterials Applications

Antenna coupling microwave plasma enables a highly oxidative treatment of the outmost surface of polypropylene (PP) nonwoven fabric within a short time period. Subsequently, grafting copolymerization with acrylic acid (AAc) makes the plasma-treated fabric durably hydrophilic and excellent in water absorbency. With hig…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsBlood properties and coagulation

A Study of the Thermoluminescent Properties of CVD Diamond Detectors

B. Marczewska、P. Bilski、Miloš Nesládek 等 6 位作者2002-10-01physica status solidi (a)

A batch of 20 diamond detectors obtained by the chemical vapour deposition (CVD) method at the Institute for Materials Research at the Limburg University, Belgium, was investigated with respect to their thermoluminescent (TL) properties. The investigated detectors demonstrate TL sensitivity similar to that of the stan…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchAdvanced X-ray and CT Imaging

Hydrothermal Synthesis of InP Semiconductor Nanocrystals

Shuo Wei、Jun Lu、Liling Zeng 等 5 位作者2002-10-01Chemistry Letters

Abstract Pure InP nanocrystals were synthesized in aqueous ammonia (potassium stearate, 0.01 mol·L−1) at 170 °C for 12 h. The X-ray diffraction pattern was of the cubic phase with lattice constant a=5.8523±5×10−4 Å. The secondary particles with 180 nm consisting of fine InP NCs with 15 nm in size were found from the t…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

Determination of full set material constants of piezoceramics from phase velocities

Haifeng Wang、Wenwu Cao2002-10-01Journal of Applied Physics

The determination of elastic and piezoelectric constants by means of the resonance method is described in detail in the Institute of Electrical and Electronics Engineers Standards. However, in practice, it is not easy to obtain a self-consistent complete set of elastic and piezoelectric coefficients using the resonanc…

Ferroelectric and Piezoelectric MaterialsUltrasonics and Acoustic Wave PropagationAcoustic Wave Resonator Technologies

Atomic-scale observations of franckeite surface morphology

René B. Henriksen、Emil Makovicky、S. L. S. Stipp 等 5 位作者2002-10-01American Mineralogist

Franckeite, approximately Pb 4.6 Ag 0.2 Sn 2.5 Fe 0.8 Sb 2 S 12.6 , consists of alternating pseudohexagonal (H) and pseudotetragonal (Q) layers. Scanning tunneling microscopy (STM) and atomic force microscopy (AFM) of freshly cleaved franckeite, from San José, Bolivia, revealed the atomic structure of the pseudohexago…

High-pressure geophysics and materialsChalcogenide Semiconductor Thin FilmsCrystal Structures and Properties

Prepregs — raw material for high-performance composites

George Marsh2002-10-01Reinforced Plastics

Prepregs have become accepted where performance, material qualification and product consistency are paramount requirements, as in aerospace, defence, marine, offshore, mass transit and renewable energy sectors. George Marsh reviews prepreg materials and manufacture.

Material Properties and Applications