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Solution Structure and Dynamics of Lanthanide Complexes of the Macrocyclic Polyamino Carboxylate DTPA-dien. NMR Study and Crystal Structures of the Lanthanum(III) and Europium(III) Complexes

Sonya J. Franklin、Kenneth N. Raymond1994-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolution Structure and Dynamics of Lanthanide Complexes of the Macrocyclic Polyamino Carboxylate DTPA-dien. NMR Study and Crystal Structures of the Lanthanum(III) and Europium(III) ComplexesSonya J. Franklin and Kenneth N. RaymondCite this: Inorg. Chem. 1994, 33, 25, 5794–58…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Nature and Stability of Radiation-Induced Defects in Natural Kaolinites: New Results and a Reappraisal of Published Works

Blandine Clozel、Thierry Allard、Jean-Pierre Muller1994-12-01Clays and Clay Minerals

Abstract A new appraisal of radiation-induced defects (RID) in natural kaolinite, i.e., positive trapped holes on oxygen atoms, has been undertaken using Q-band EPR spectra, recorded at 93 K, of irradiated annealed and oriented kaolinite samples originating from various environments. Three different centers were ident…

Glass properties and applicationsClay minerals and soil interactionsNuclear materials and radiation effects

Synthesis and Functionalization of Unsaturated Polyethylene: Poly(ethylene-co-1,4-hexadiene)

T. C. Chung、Hua Lu、C. L. Li1994-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and Functionalization of Unsaturated Polyethylene: Poly(ethylene-co-1,4-hexadiene)T. C. Chung, H. L. Lu, and C. L. LiCite this: Macromolecules 1994, 27, 26, 7533–7537Publication Date (Print):December 1, 1994Publication History Published online1 May 2002Published in…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and Properties

Effects of component addition protocol on the reactive compatibilization of HDPE/PET blends

S. S. Dagli、Kunal M. Kamdar1994-12-01Polymer Engineering and Science

Abstract Polyethylene terephtyalate (PET) and high‐density polyethylene (HDPE) constitute a major portion of the thermoplastic materials currently being used in the packaging industry. Blends of HDPE/PET can be compatibilized by utilizing ester groups or terminal carboxyl and hydroxyl groups present in PET. An ethylen…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesFiber-reinforced polymer composites

Polycarbonate/ABS blends: Processability, thermal properties, and mechanical and impact behavior

Roberto Greco、Maria Francesca Astarita、Lisong Dong 等 4 位作者1994-12-01Advances in Polymer Technology

Abstract PC/ABS blends, encompassing the whole composition range between PC and ABS, were prepared by a Brabender‐like apparatus and compression molded in sheets. The analysis of processability, confirming the improved PC processability by ABS additions, was accomplished by the same apparatus used for the blend prepar…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesRecycling and Waste Management Techniques

Mortality Through 1990 Among White Male Workers at the Los Alamos National Laboratory

Laurie D. Wiggs、Emily Johnson、Carol A. Cox-Devore 等 4 位作者1994-12-01Health Physics

A cohort mortality study was conducted of 15,727 white men employed by the Los Alamos National Laboratory, a nuclear research and development facility. Some of the workers at this facility have been exposed to various forms of ionizing radiation and other potentially hazardous materials. These analyses focused on whol…

Radiation Dose and ImagingRadiation Therapy and DosimetryGraphite, nuclear technology, radiation studies

Strong Mn-Mn distance dependence of the Mn interlayer coupling inSmMn2Ge2-related compounds and its role in magnetic phase transitions

J.H.V.J. Brabers、A. J. Nolten、F.E. Kayzel 等 6 位作者1994-12-01Physical review. B, Condensed matter

The interplay between the Mn interlayer coupling constant ${\mathit{n}}_{\mathrm{Mn}\mathrm{\ensuremath{-}}\mathrm{Mn}}$ and the thermal expansion has been investigated by means of thermal-expansion, specific-heat, and magnetization measurements. A linear relation between ${\mathit{n}}_{\mathrm{Mn}\mathrm{\ensuremath{…

Magnetic properties of thin filmsMagnetic and transport properties of perovskites and related materialsMagnetic Properties of Alloys

Porous silicon superlattices

Stephan Frohnhoff、M. Berger1994-12-01Advanced Materials

Porous silicon superlattices (PSSs) are a novel type of siliconbased heterostructures, in which the porosity varies periodically with depth. The two different types of PSSs and their techniques of formation are described, as are their optical properties and an example of an application: a Fabry‐Perot‐type interference…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

P-T Phase Diagram and Gold Valence State of the Perovskite-Type Mixed-Valence Compounds Cs2Au2X6 (X = Cl, Br, and I) under High Pressures

N. Kojima、Masashi Hasegawa、H. Kitagawa 等 5 位作者1994-12-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTP-T Phase Diagram and Gold Valence State of the Perovskite-Type Mixed-Valence Compounds Cs2Au2X6 (X = Cl, Br, and I) under High PressuresN. Kojima, M. Hasegawa, H. Kitagawa, T. Kikegawa, and O. ShimomuraCite this: J. Am. Chem. Soc. 1994, 116, 25, 11368–11374Publication Date…

Perovskite Materials and ApplicationsOrganic and Molecular Conductors ResearchThermal Expansion and Ionic Conductivity

Compositional Dependence of Absorption Spectra of Ti 3+ in Silicate, Borate, and Phosphate Glasses

Kenji Moringa、Hideki Yoshida、Hiromichi Takebe1994-12-01Journal of the American Ceramic Society

Absorption spectra of Ti 3+ were measured for silicate, borate, and phosphate glasses doped with 0.5 mol% Ti 2 O 3 .The absorption coefficient at the peak wavelength of the 2 T 2 → 2 E transition of Ti 3+ is used as a parameter showing the relative content of Ti 3+ ions in glass samples. The effect of glass compositio…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPigment Synthesis and Properties

Ab Initio Calculation of the Magnetic Exchange Coupling in Linear Oxo-Bridged Binuclear Complexes of Titanium(III), Vanadium(III), and Chromium(III)

Karin Fink、Reinhold F. Fink、Volker Staemmler1994-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAb Initio Calculation of the Magnetic Exchange Coupling in Linear Oxo-Bridged Binuclear Complexes of Titanium(III), Vanadium(III), and Chromium(III)K. Fink, R. Fink, and V. StaemmlerCite this: Inorg. Chem. 1994, 33, 26, 6219–6229Publication Date (Print):December 1, 1994Publi…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMolecular spectroscopy and chirality

Using a two-dimensional detector for X-ray powder diffractometry

S. N. Sulyanov、А. Н. Попов、D. M. Kheĭker1994-12-01Journal of Applied Crystallography

Special software has been developed to calculate the intensity–scattering-angle dependence. Powder diffraction patterns are obtained in a diffractometer with a two-dimensional area detector. The detector used is a planar proportional chamber with fast delay lines. The optimum sample geometry for both the transmission…

Liquid Crystal Research AdvancementsX-ray Diffraction in CrystallographyPolymer Synthesis and Characterization

Nonionic Superbase-Promoted Synthesis of Oxazoles and Pyrroles: Facile Synthesis of Porphyrins and .alpha.-C-Acyl Amino Acid Esters

Jiansheng Tang、John G. Verkade1994-12-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNonionic Superbase-Promoted Synthesis of Oxazoles and Pyrroles: Facile Synthesis of Porphyrins and .alpha.-C-Acyl Amino Acid EstersJiansheng Tang and John G. VerkadeCite this: J. Org. Chem. 1994, 59, 25, 7793–7802Publication Date (Print):December 1, 1994Publication History P…

Porphyrin and Phthalocyanine ChemistryFluorine in Organic ChemistrySynthesis and Characterization of Pyrroles

Polyoxometalate-Diphosphate Complexes. 2. Structure of 18-Molybdopyrophosphate, [(P2O7)Mo18O54]4-, Which Encloses a Linear, Eclipsed Conformation of the Pyrophosphate Anion, and Preliminary Characterization of its One- and Two-Electron Heteropoly Blues

U. Kortz、Michael T. Pope1994-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolyoxometalate-Diphosphate Complexes. 2. Structure of 18-Molybdopyrophosphate, [(P2O7)Mo18O54]4-, Which Encloses a Linear, Eclipsed Conformation of the Pyrophosphate Anion, and Preliminary Characterization of its One- and Two-Electron Heteropoly BluesUli Kortz and Michael T…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Novel Nanoscopic Architectures. Linear-Globular ABA Copolymers with Polyether Dendrimers as A Blocks and Polystyrene as B Block

Ivan Gitsov、Jean M. J. Fréchet1994-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNovel Nanoscopic Architectures. Linear-Globular ABA Copolymers with Polyether Dendrimers as A Blocks and Polystyrene as B BlockIvan Gitsov and Jean M. J. FrechetCite this: Macromolecules 1994, 27, 25, 7309–7315Publication Date (Print):December 1, 1994Publication History Publ…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresDendrimers and Hyperbranched Polymers

Syntheses, Crystal Structures, and Properties of New Layered Molybdenum(VI) Selenites: (NH4)2(MoO3)3SeO3 and Cs2(MoO3)3SeO3

William T. A. Harrison、Laurie L. Dussack、Allan J. Jacobson1994-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSyntheses, Crystal Structures, and Properties of New Layered Molybdenum(VI) Selenites: (NH4)2(MoO3)3SeO3 and Cs2(MoO3)3SeO3William T. A. Harrison, Laurie L. Dussack, and Allan J. JacobsonCite this: Inorg. Chem. 1994, 33, 26, 6043–6049Publication Date (Print):December 1, 1994…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyInorganic Chemistry and Materials

Acid Hydrolysis of Octahedral Mg 2+ Sites in 2:1 Layered Silicates: An Assessment of Edge Attack and Gallery Access Mechanisms

Hemamali Kaviratna、Thomas J. Pinnavaia1994-12-01Clays and Clay Minerals

Abstract The acid hydrolysis products of trioctahedral fluorohectorite and phlogopite have been investigated by XRD, MAS NMR spectroscopy and nitrogen BET surface area analysis in an effort to assess the relative importance of edge attack and gallery access mechanisms. A dramatic loss of X-ray crystallinity and the fo…

Clay minerals and soil interactionsLayered Double Hydroxides Synthesis and ApplicationsChemical Synthesis and Characterization

Substituierte N,N‐Chelat‐Liganden ‐ Anwendungen in der Molybdän‐katalysierten Olefin‐Epoxidation

Werner R. Thiel、Michaela Angstl、Thomas Priermeier1994-12-01Chemische Berichte

Abstract Substituted N,N‐Chelate Ligands ‐ Applications in Molybdenum‐Catalyzed Epoxidation of Olefins * Oxodiperoxomolybdenum complexes 4 of substituted 2‐[3(5)‐pyrazolyl]pyridines ( 2a‐g ) were synthesized in order to control the solubility of these complexes in organic solvents. Alkyl side chains (butyl, octyl, oct…

Organometallic Complex Synthesis and CatalysisPolyoxometalates: Synthesis and ApplicationsSynthetic Organic Chemistry Methods

Design of antireflection gratings with approximate and rigorous methods

Ralf Bräuer、Olof Bryngdahl1994-12-01Applied Optics

High-spatial-frequency gratings can be used as an alternative to thin-film antireflection coatings to reduce the reflectivity at the boundary between two different media. In the case of one-dimensional gratings, the conditions on the grating structure can be approximately determined by the effective medium theory (EMT…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings