Materials Literature
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Abstract Thermoreversible reaction of Diels‐Alder polymer composed of difurufuryladipate with bismaleimidodiphenylmethane was studied in dimethylformamide solution. The retro‐Diels‐Alder degradation occurred gradually at 90°C and Diels–Alder polymerization proceeded quickly at 60°C. © 1994 John Wiley & Sons, Inc.
Li 4 siO 4 , M r =119.84, λ(Mo Kα)=0.71073 A 150 K, monoclinic, P2 1 /m, a=11.532 (1), b=6.075 (1), c=16.678 (1) A, β=99.04 (4) o , V=1153.9 (2) A 3 , μ(Mo Kα)=5.3 cm -1 , Z=14, F(000)=812, D x =2.414 Mg m -3 , R=0.028, wR=0.025 for 2255 observed reflections with I>2.5σ(I). The crystal structure of lithium nesosilicat…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTQuasi-two-dimensional metallic character of Sm2Te5 and SmTe3E. DiMasi, B. Foran, M. C. Aronson, and S. LeeCite this: Chem. Mater. 1994, 6, 10, 1867–1874Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Published inissue 1 October 1994https…
Fabric hand evaluation, previously applied to men's suiting, is used here to assess the touch or feel of nonwoven fabrics. In this method, fabric mechanical property parameters are converted by a first conversion equation (equation type I ) to numbers (the hand value or Hv) that express three primary hand values (the…
Dense SiC‐whisker‐reinforced mullite composites with up to 50 vol% whiskers can be obtained by tape casting and hot pressing. The tape casting process results in high degrees of SiC whisker orientation as determined visually and by X‐ray diffraction. The ability to achieve dense composites with as much as 50 vol % whi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTUnusually Strong Adsorption of Highly Charged Heteropolytungstate Anions on Mercury Electrode SurfacesChaoying. Rong and Fred C. AnsonCite this: Anal. Chem. 1994, 66, 19, 3124–3130Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Published…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDetermination of the Critical Micelle Concentration of Block Copolymer Micelles by Static Light ScatteringKarine Khougaz, Zhisheng Gao, and Adi EisenbergCite this: Macromolecules 1994, 27, 22, 6341–6346Publication Date (Print):October 1, 1994Publication History Published onl…
The identification of a myriad of small peptide and carbohydrate ligands recognized by cell surface receptors has generated enthusiasm for the use of these ligands of components of biomaterials for controlling cellular interactions. Achieving control of cell interactions via ligand modification of materials also requi…
In the course of studies on anaerobic citrate metabolism in Klebsiella pneumoniae, the DNA region upstream of the gene for the sodium-dependent citrate carrier (citS) was investigated. Nucleotide sequence analysis revealed a cluster of five new genes that were oriented inversely to citS and probably form an operon. Th…
Book Review| Online October 01 1994 Burn Care and Rehabilitation: Principles and Practice Burn Care and Rehabilitation: Principles and Practice. Reginald L. Richard, MS, PT, & Marlys J. Staley, MS, PT, (Eds.) ( 1994) F. A. Davis, 1915 Ark Street, Philadelphia, PA 19103 711 pages, $90.00. Cynthia D. Alexander, MS, OTR,…
In summary, the compounds reported here demonstrate that it is possible to design chromophores that simultaneously exhibit large nonlinearity and good thermal stability. Furthermore, with the synthesis of bis(4-hydroxyphenyl)thiobarbituric acid, we believe that it should be possible to covalently incorporate these and…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and Electrochemistry of Iron(III) Corroles Containing a Nitrosyl Axial Ligand. Spectral Characterization of [(OEC)FeIII(NO)]n where n = 0, 1, 2, or -1 and OEC is the Trianion of 2,3,7,8,12,13,17,18-OctaethylcorroleMarie Autret, Stefan Will, E. V. Caemelbecke, Johan…
The isolation and characterization is described of four novel cyclic polyethers, bistramides B [2], C [3], D [4], and K [5], which are closely related to the previously reported bistramide A [1] from the New Caledonian urochordata Lissoclinum bistratum. The structures of these metabolites were defined by spectroscopic…
With the aid of a double-tilt holder, a simple method for determining orientation and misorientation of a cubic crystal specimen in a transmission electron microscope is developed. To use this method, a recognizable zone axis from one grain needs to be aligned along the beam direction, the corresponding tilt positions…
Examination of the electrochemical behavior of Ti‐15 V‐3 Cr‐3 Al‐3 Sn (Ti‐15‐3) alloy was performed as an initial step in understanding mechanisms for environmentally assisted cracking of β‐titanium alloys in room temperature aqueous chloride solutions. Both solution heat‐treated (SHT) and peak‐aged (PA) Ti‐15‐3 were…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of model super H-shaped block copolymersHermis Iatrou, Apostolos Avgeropoulos, and Nikos HadjichristidisCite this: Macromolecules 1994, 27, 21, 6232–6233Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Published inissue 1 Octobe…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMixed, Neutral-Charged, Platinum-Platinum and Platinum-Palladium Macrocyclic Tetranuclear ComplexesPeter J. Stang and Jeffery A. WhitefordCite this: Organometallics 1994, 13, 10, 3776–3777Publication Date (Print):October 1, 1994Publication History Published online1 May 2002P…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIntercalation in Novel Organogels with a "Stacked" Phenol MicrostructureMurthy Tata, Vijay T. John, Yan Y. Waguespack, and Gary L. McPhersonCite this: J. Am. Chem. Soc. 1994, 116, 21, 9464–9470Publication Date (Print):October 1, 1994Publication History Published online1 May…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInvestigations of Zeolites by Photoelectron and Ion Scattering Spectroscopy. 2. A New Interpretation of XPS Binding Energy Shifts in ZeolitesWolfgang Gruenert, Martin Muhler, Klaus-Peter Schroeder, Joachim Sauer, and Robert SchloeglCite this: J. Phys. Chem. 1994, 98, 42, 109…
Abstract Molecular orientation imparted during film fabrication is known to have a major effect on mechanical and thermal properties of both glassy and semicrystalline polymers. A three‐variable Box‐Behnken designed experiment was used to study the effects of die gap, die land length, and blowup ratio (BUR) on key lin…