Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
OBJECTIVES: PEGylated liposomes could evade recognition by the reticulo-endothelial system and prolong the circulation time of vesicles, resulting in enhanced targeting efficiency and antitumour effect. Typically, vesicles are modified with distearoylphosphatidylethanolamine (DSPE)-polyethylene glycol (PEG) at a high…
A systematic approach for increasing the accuracy of the reference interaction site model (RISM) theory is introduced that uses input from simulation results to produce very accurate site-site pair correlation functions for single component molecular liquids. The methodology allows the computation of the "RISM bridge…
In situ cation exchange between alkali ions in ternary alkali lanthanide (Ln3+) fluoride on the nanoscale is reported. Experimental results reveal that the differences in the solubility constants and thermodynamic stability of the reactants and products affect the irreversible cation exchange between potassium and sod…
Abstract Different laser dyes (with special interest in boron dipyrromethene) are incorporated as guests into the channels of zeolite L. The resulting doped material is fully characterized by steady‐state and time‐resolved photophysical techniques. The pores of zeolite L are filled with high amounts of dyes, which are…
The compound Ba(8)Hg(3)U(3)S(18) was obtained from the solid-state reaction at 1123 K of U, HgS, BaS, and S, with BaBr(2)/KBr or BaCl(2) as a flux. This material crystallizes in a new structure type in space group P6 of the hexagonal system with three formula units in a cell of dimensions a = 27.08(1) Å, c = 4.208(2)…
Two series of o-diamidobenzenes, bearing long-chain alkyl substituted gallic ester groups, have been synthesised. The 3,4,5,6-unsubstituted amides 7 with a minimum chain length of C9 exhibited columnar rectangular mesophases of p2mm symmetry with Z = 2. The liquid crystalline phases spread over phase width of extremel…
We have studied the mechanism of the water–gas shift reaction (WGS, CO + H 2 O → CO 2 + H 2 ) catalyzed by nanosized gold particles by using density functional theory calculations. The molecular structures and adsorbate/substrate interaction energies of H 2 O/Au 38, CO/Au 38, HO/Au 38, and H/Au 38 configurations were…
New inorganic hybrid nanoparticles integrating different materials in a core/shell structure of iron and bismuth oxides have been synthesized by a simple aqueous route. The method is based on the precipitation of an Fe(II) salt in the presence of bismuth(III) cations in a mild oxidant and leads to highly uniform and c…
Nano and micro imaging were used to evaluate effects of pretreatment solution on gelatin. Four types of pretreatment solution were used during fish gelatin extraction in this study. They are acetic acid (A), acetic acid-NaCl (SA), acetic acid-NaOH (BA) and acetic acid-NaOH-NaCl (SBA). Different patterns were observed…
A detailed analysis of the selected DFT functionals for the calculations of interaction-induced dipole moment, polarizability and first-order hyperpolarizability has been carried out. The hydrogen-bonded model chains consisting of HF, H(2)CO and H(3)N molecules have been chosen as a case study. The calculations of the…
The structural and electronic properties of N-doped zigzag graphene ribbons with various ratios of dihydrogenated to monohydrogenated edge carbons are investigated within the density functional theory framework. We find that the stability of graphitic N next to the edge, which is claimed to play important roles in the…
We demonstrate structural and room temperature magnetic properties of Fe doped ZnO nanofibers (NFs) obtained by electrospinning followed by calcination. The observed NFs, formed from crystalographically oriented, approximately 4.5 nm particles conglomerates, were approximately 200 nm in diameter. The reported synthesi…
In Nature, chromophoric groups play various roles, such as oxygen carriers, electron donors, light sensitizers, which are achieved in many cases by control of their aggregation modes in proteins. Host-guest chemistry between cyclodextrins and porphyrins has attracted great interest from supramolecular chemists because…
Hypercholesterolemia increases the incidence of atherosclerosis and its pathologic complications. This study was performed to test the effect of an ethanol extract of Cynanchum wilfordii (ECW) on vascular dysfunction in rats fed with high fat/cholesterol diets (HFCD). Male rats were fed a HFCD consisting of 7.5% cocoa…
Hydroxyls are omnipresent on oxide surfaces under ambient conditions. While they unambiguously play an important role in many catalytic processes, it is not well-understood how these species influence surface chemistry at atomic scale. We investigated the adsorption of nitric oxide (NO) on a hydroxylated rutile TiO 2…
We present evidence for the generation of free carriers in aggregated single-wall carbon nanotubes by photoexcitation in the energetic range of the π→π(*) transition associated with the M saddle point of the graphene lattice. The underlying broad absorption culminating at 4.3 eV can be fit well with a Fano line shape…
The diffusion of lanthanum and manganese cations in Ba0.5Sr0.5Co0.8Fe0.2O3−δ polycrystalline ceramics was measured in the temperature range 1123 ≤ T/K ≤ 1283 at the pO2 of 0.21 bar, and at 1173 K over the range of pO2 10−5 ≤ pO2/bar ≤ 1. The diffusion coefficients of La and Mn were similar at all temperatures investig…
Abstract Bistable electrical conductivity switching behavior and write‐once, read‐many‐times (WORM) memory effects have been demonstrated in Al/polymer/ITO sandwich devices. These devices were constructed from two poly( N ‐vinylcarbazole) derivatives with pendant donor–trap–acceptor (D‐T‐A) structures. The observed el…
Methylcellulose (MC)-based films were prepared by solution casting from its 1% aqueous suspension containing 0.25% glycerol. Trimethylolpropane trimethacrylate (TMPTMA) monomer (0.1-2% by wt) along with the glycerol was added to the MC suspension. The films were cast and irradiated from a radiation dose varied from 0.…
A three-dimensional surface enhanced Raman scattering (SERS)/plasmonic sensing platform based on plasma-enabled, catalyst-free, few-layer vertical graphenes decorated with self-organized Au nanoparticle arrays is demonstrated. This platform is viable for multiple species detection and overcomes several limitations of…