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Photosynthesis of hydrogen and methane as key components for clean energy system

Seng Sing Tan et al2007-01-01Science and Technology of Advanced Materials

While researchers are trying to solve the world's energy woes, hydrogen is becoming the key component in sustainable energy systems. Hydrogen could be produced through photocatalytic water-splitting technology. It has also been found that hydrogen and methane could be produced through photocatalytic reduction of carbo…

Tip preparation for usage in an ultra-low temperature UHV scanning tunneling microscope

S. Ernst, S. Wirth, M. Rams, V. Dolocan and F. Steglich2007-01-01Science and Technology of Advanced Materials

This work deals with the preparation and characterization of tungsten tips for the use in UHV low-temperature scanning tunneling microscopy and spectroscopy (STM and STS, respectively). These specific environments require in situ facilities for tip conditioning, for further sharpening of the tips, as well as for relia…

Low-energy spin fluctuations in the non-Fermi-liquid compound YbRh2Si2

O. Stockert et al2007-01-01Science and Technology of Advanced Materials

We report on inelastic neutron scattering experiments on YbRh2Si2 powder to study the low-energy spin dynamics at temperatures between T=0.8 and 22 K. The low-energy magnetic response is quasielastic. However, it exhibits an unusual form not modelled by a simple relaxation rate yielding a Lorentzian lineshape, but can…

Microwave-assisted route for synthesis of nanosized metal oxides

Arunkumar Lagashetty et al2007-01-01Science and Technology of Advanced Materials

Microwave-assisted route for the synthesis of nanomaterials has gained importance in the field of synthetic technology because of its faster, cleaner and cost effectiveness than the other conventional and wet chemical methods for the preparation of metal oxide nanoparticles. In the present work, synthesis of metal oxi…

Nanoionics phenomenon in proton-conducting oxide: Effect of dispersion of nanosize platinum particles on electrical conduction properties

Hiroshige Matsumoto et al2007-01-01Science and Technology of Advanced Materials

High-temperature proton conductors are oxides in which low-valence cations are doped as electron acceptors; the incorporation of water molecules into the oxides results in the formation of protonic defects that act as charge carriers. Since the protons thus formed are in equilibrium with other electronic defects, elec…

Prediction of powder particle size during centrifugal atomisation using a rotating disk

Huiping Li and Xucheng Deng2007-01-01Science and Technology of Advanced Materials

The centrifugal atomisation of metallic melts using a rotating disk is an important process for powder production and spray deposition. The theoretical prediction of powder particle size is desirable for the design of atomisers. In this paper, wave theory was applied to analyse the disintegration of metallic melts in…

Crystal, electronic and luminescence properties of Eu2+-doped Sr2Al2−xSi1+xO7−xNx

Yuan Qiang Li, Naoto Hirosaki, Rong-Jun Xie and Mamoru Mitomo2007-01-01Science and Technology of Advanced Materials

The crystal and electronic structures, as well as the luminescence properties of Sr2Al2−xSi1+xO7−xNx:Eu2+ are reported. First-principles calculations energetically confirm that the Al and Si atoms are in partial ordering in the 2a and 4e sites in Sr2Al2SiO7. In addition, the band structure calculation shows that Sr2Al…

The effect of nanocrystalline magnetite size on arsenic removal

J.T. Mayo et al2007-01-01Science and Technology of Advanced Materials

Higher environmental standards have made the removal of arsenic from water an important problem for environmental engineering. Iron oxide is a particularly interesting sorbent to consider for this application. Its magnetic properties allow relatively routine dispersal and recovery of the adsorbent into and from ground…

Effect of aggregates on the magnetization property of ferrofluids: A model of gaslike compression

Jian Li, Yan Huang, Xiaodong Liu, Yueqing Lin, Lang Bai and Qiang Li2007-01-01Science and Technology of Advanced Materials

The effect of field-induced aggregation of particles on the magnetization property of ferrofluids is investigated. From the viewpoint of energy, magnetizability of ferrofluids is more complicated than predicted by Langevin theory because the aggregation, i.e., the transition of ferrofluid microstructure, would consume…

Preparations and photocatalytic degradation of methyl orange in water on magnetically separable Bi12TiO20 supported on nickel ferrite

Shihong Xu, Wenfeng Shangguan, Jian Yuan, Jianwei Shi and Mingxia Chen2007-01-01Science and Technology of Advanced Materials

A magnetically separable photocatalyst Bi12TiO20/SiO2/NiFe2O4 (BSN) with a typical ferromagnetic hysteresis was prepared by a simple process: the magnetic 200 wt% SiO2/NiFe2O4 (SN) dispersion prepared by a liquid catalytic phase transformation method and the visible-light-active photocatalyst Bi12TiO20 prepared by a s…

Precision grinding of microarray lens molding die with 4-axes controlled microwheel

Yuji Yamamoto, Hirofumi Suzuki, Takashi Onishi1, Tadashi Okino and Toshimichi Moriwaki2007-01-01Science and Technology of Advanced Materials

This paper deals with precision grinding of microarray lens (fly eye) molding die by using a resinoid bonded diamond wheel. An ultra-precision grinding system of microarray lens molding die and new truing method of resinoid bonded diamond wheel were developed. In this system, a grinding wheel was four-dimensionally co…

Nanostructures in environmental pollution detection, monitoring, and remediation

A. Vaseashta et al2007-01-01Science and Technology of Advanced Materials

We present preliminary results of our joint investigations to monitor and mitigate environmental pollution, a leading contributor to chronic and deadly health disorders and diseases affecting millions of people each year. Using nanotechnology-based gas sensors; pollution is monitored at several ground stations. The se…

Review: Silicon-based oxynitride and nitride phosphors for white LEDs

Rong-Jun Xie and Naoto Hirosaki2007-01-01Science and Technology of Advanced Materials

As a novel class of inorganic phosphors, oxynitride and nitride luminescent materials have received considerable attention because of their potential applications in solid-state lightings and displays. In this review we focus on recent developments in the preparation, crystal structure, luminescence and applications o…

Systematic study of the Grüneisen ratio near quantum critical points

R. Küchler, P. Gegenwart, C. Geibel and F. Steglich2007-01-01Science and Technology of Advanced Materials

At any pressure-sensitive quantum critical point (QCP), the volume thermal expansion coefficient is more singular than the specific heat. Consequently, the resulting critical Grüneisen ratio Γcr~βcr/Ccr, where βcr and Ccr denote the thermal expansion and specific heat after subtraction of non-critical background contr…

Theoretical investigation to thermal equilibrium concentration of point defect through first-principles calculation

Akihide Kuwabara2007-01-01Science and Technology of Advanced Materials

First-principles calculations based on density functional theory enable us to quantify the thermal equilibrium concentration of a point defect through calculating the formation energy of the defect. In order to know the formation energy, we need three parameters: the energy difference between defective and perfect sys…

(Sr6N)[CoN2][CN2]2: The first low-valency nitridometalate carbodiimide

Joanna Katarzyna Bendyna, Peter Höhn, Walter Schnelle and Rüdiger Kniep2007-01-01Science and Technology of Advanced Materials

The first nitridocobaltate carbodiimide (Sr6N)[CoN2][CN2]2 has been synthesized from the elements Sr, Co, and graphite powder and NaN3 (as a nitrogen source). The crystal structure was determined from X-ray single-crystal diffraction data as orthorhombic (space group P21212, No. 18, a=9.8807(6) Å, b=14.6474(9) Å, c=3.…

Degradation of magnetic tunnel junctions with thin AlOx barrier

Tadashi Mihara, Yoshinari Kamakura, Masato Morifuji and Kenji Taniguchi2007-01-01Science and Technology of Advanced Materials

The degradation of magnetic tunnel junctions (MTJs) with AlOx barrier was experimentally investigated. Constant voltage stress (CVS) measurement was carried out to monitor the time evolution of the conductance and tunneling magnetoresistance (TMR) of MTJs. The gradual increase of the stress-induced leakage current (SI…

Physical characteristics of nanoparticles emitted from incense smoke

Siao Wei See et al2007-01-01Science and Technology of Advanced Materials

Incense is habitually burned in various religious settings ranging from the Eastern temples to the Western churches and in residential homes of their devotees, representing one of the most significant sources of combustion-derived particulate matter in indoor air. Incense smoke has been known to be associated with adv…