Materials Literature
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The new perovskite cuprate material ${\mathrm{Sr}}_{8}{\mathrm{CaRe}}_{3}{\mathrm{Cu}}_{4}{\mathrm{O}}_{24}$, which behaves ferrimagnetically and shows an unusually high Curie temperature (${T}_{\mathrm{C}}\ensuremath{\sim}440\text{ }\text{ }\mathrm{K}$), is found from density-functional theory calculation to display…
Self-assembled zinc oxide (ZnO) and indium-doping zinc oxide (ZnO:In) nanorod thin films were synthesized on quartz substrates without catalyst in aqueous solution by sol-gel method. The samples were characterized by x-ray diffraction (XRD), scanning electron microscope (SEM), Raman-scattering spectroscopy, room-tempe…
Abstract Molecular oxygen plays an important role in many of the chemical reactions involved in the synthesis of biological life. In this review, we explore the interaction between O 2 and silicon nanocrystals, which can be employed in the photosynthesis of singlet oxygen. We demonstrate that nanoscale Si has entirely…
A first order transition from a paramagnetic-austenite phase to a ferromagnetic-martensite phase occurring in off-stoichiometry single crystals of ${\mathrm{Ni}}_{2}\mathrm{Mn}\mathrm{Ga}$ at 313 K presents unique features due to the multifunctional character of the magnetic shape memory alloy. A remarkable magnetocal…
The properties of ZnO films grown by molecular-beam epitaxy are reported. The primary focus was on understanding the origin of deep-level luminescence. A shift in deep-level emission from green to yellow is observed with reduced Zn pressure during the growth. Photoluminescence and Hall measurements were employed to st…
We present the concept of ferroelectric tunnel junctions (FTJs). These junctions consist of two metal electrodes separated by a nanometer-thick ferroelectric barrier. The current-voltage characteristics of FTJs are analyzed under the assumption that the direct electron tunneling represents the dominant conduction mech…
Colloidal particles or nanoparticles, with equal affinity for two fluids, are known to adsorb irreversibly to the fluid-fluid interface. We present large-scale computer simulations of the demixing of a binary solvent containing such particles. The newly formed interface sequesters the colloidal particles; as the inter…
Pairs of noble metal nanoparticles can be used to measure distances via the distance dependence of their plasmon coupling. These "plasmon rulers" offer exceptional photostability and brightness; however, the advantages and limitations of this approach remain to be explored. Here we report detailed plasmon peak versus…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCurved Pi-Conjugation, Aromaticity, and the Related Chemistry of Small Fullerenes (<C60) and Single-Walled Carbon NanotubesXin Lu and Zhongfang ChenView Author Information State Key Laboratory of Physical Chemistry of Solid Surfaces & Center for Theoretical Chemistry, Depart…
A methodology is described to systematically derive coarse-grained (CG) force fields for molecular liquids from the underlying atomistic-scale forces. The coarse graining of an interparticle force field is accomplished by the application of a force-matching method to the trajectories and forces obtained from the atomi…
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[reaction: see text] A pair of chiral, branched monomer building blocks, consisting of a solvatochromic probe and a spectroscopically inactive volume dummy, has been developed. The probe can selectively be excited, and its fluorescence characteristics provide information about local polarity. Incorporation of these mo…
Highly textured Bi 3 NbTiO 9 ceramics are fabricated by normal sintering from molten salt‐synthesized plate‐like crystallites. Fine Bi 3 NbTiO 9 plate‐like crystallites (∼1 μm) not only facilitate the densification, but also enhance texture in Bi 3 NbTiO 9 ceramics. Weak‐agglomerated platelets exhibit higher sinterabi…
Automatic fitting methods that build molecules into electron-density maps usually fail below 3.5 A resolution. As a first step towards addressing this problem, an algorithm has been developed using an approximation of the medial axis to simplify an electron-density isosurface. This approximation captures the central a…
Abstract Summary: Polyurethane/silica hybrid coatings were prepared via in situ (IS) or blending (BL) method using different acidic silica sols. The effects of preparation methods, silica types, and content on the structure and mechanical properties of the hybrid coatings were investigated. It was found that there exi…
Abstract The crystal structures of solvent-free lithium, sodium, rubidium, and cesium squarates have been determined from high resolution synchrotron and X-ray laboratory powder patterns. Crystallographic data at room temperature of Li 2 C 4 O 4 : a = 7.1073(3) Å, b = 9.5627(4) Å, c = 3.2973(1) Å, β = 101.11(1)°, V =…
The coherent spin dynamics of holes in Mg-doped ($p$-type) wurtzite GaN is studied by time-resolved Kerr rotation technique. We observe the spin precession of holes with the spin coherence time of $120\phantom{\rule{0.3em}{0ex}}\mathrm{ps}$, which is distinguished from that of electrons by comparison with the results…
Indirect high resolution electron microscopy using one of several possible data-set geometries offers advantages over conventional high-resolution imaging in enabling the recovery of the complex wavefunction at the specimen exit plane and simultaneously eliminating the aberrations present in the objective lens. This a…
Abstract For three icosahedral alloys in the Mg—Zn- RE ( RE = Ho, Y) systems, the atomic pair distribution functions (PDFs) have been obtained from sealed X-ray tube (in-house) and synchrotron (ESRF and APS) powder diffraction experiments. The PDFs are at least qualitatively comparable and are suitable for least squar…
We prepared a novel composite consisting of a side chain liquid crystalline polysiloxane matrix and gold nanoparticles. We showed that the size and morphology of the nanoparticles were strongly linked to the macroscopic organization of the mesophase during reduction of gold ions