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NAC-Capped Quantum Dot as Nuclear Staining Agent for Living Cells via an In Vivo Steering Strategy

Dan Zhao、Zhike He、Pui Shan Chan 等 7 位作者2010-03-19The Journal of Physical Chemistry C

We describe a new nuclear staining strategy by in vivo anchoring Hoechst 33342, a commonly used nuclear staining organic dye, onto water-soluble N -acetylcysteine (NAC)-capped CdTe quantum dots (QDs). The strong H-bonding and electrostatic interaction between the organic dye and the QDs entice the positively charged n…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Effects of organophilic‐modified attapulgite nanorods on thermal and mechanical behavior of segmented polyurethane elastomers

Chia‐Hao Wang、Yeong‐Tarng Shieh、Gangjian Guo 等 4 位作者2010-03-19Polymer Composites

Abstract The effects of different grafting content of 4,4′‐methlenebis(phenyl isocyanate)‐modified attapulgite (ATT‐MDI) on thermal and mechanical properties of segmented polyurethane (PU) elastomers were investigated. The ATT‐MDI nanorods with different grafting content were prepared by treating ATT with heat and aci…

Structural Behavior of Reinforced ConcretePolymer Nanocomposites and PropertiesPolymer composites and self-healing

Intercalation of Ethylene Glycol into Yttrium Hydroxide Layered Materials

Yuanzhou Xi、Robert J. Davis2010-03-19Inorganic Chemistry

Intercalation of ethylene glycol into layered yttrium hydroxide containing nitrate counterions was accomplished by heating the reagents in a methanol solution of sodium methoxide under autogenous pressure at 413 K for 20 h. The resulting crystalline material had an expanded interlayer distance of 10.96 A, confirming t…

Supercapacitor Materials and FabricationMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Sub-band-gap photoconductivity inCo2+-doped ZnO

Claire A. Johnson、Tiffany C. Kaspar、Scott A. Chambers 等 5 位作者2010-03-19Physical Review B

Variable-temperature and polarized scanning photoconductivity measurements on ${\text{Zn}}_{1\ensuremath{-}x}{\text{Co}}_{x}\text{O}$ epitaxial films allow description of sub-band-gap ${\text{Co}}^{2+}$-derived photoionization excited states in this archetypal diluted magnetic oxide. Low-temperature (27 K) measurement…

ZnO doping and propertiesGa2O3 and related materialsElectronic and Structural Properties of Oxides

Development and Interfacial Characterization of Co/Mg Periodic Multilayers for the EUV Range

Karine Le Guen、Min Hu、Jean‐Marc André 等 9 位作者2010-03-19The Journal of Physical Chemistry C

We propose a new system, namely the periodic Co/Mg multilayer system, for optics applications in the EUV range. Close to the Mg L edge, i.e., around a wavelength of 25 nm or a photon energy of 50 eV, a reflectivity of about 43% is measured at 45° for s-polarized radiation. Moreover, it appears that this system is stab…

Magnetic properties of thin filmsElectron and X-Ray Spectroscopy Techniquesnanoparticles nucleation surface interactions

Synthesis and Properties of Turbostratically Disordered, Ultrathin WSe2 Films

Ngoc T. Nguyen、Polly A. Berseth、Qiyin Lin 等 11 位作者2010-03-19Chemistry of Materials

Turbostratically disordered tungsten diselenide (WSe 2 ) thin films with as few as two c -axis-oriented (basal plane) structural units were synthesized from modulated elemental reactants. By varying the number of elemental W−Se bilayers deposited, the thickness could be controllably varied from two to eighty such stru…

2D Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films

One-Step Dry Method for the Synthesis of Supported Single-Crystalline Organic Nanowires Formed by π-Conjugated Molecules

Ana Borrás、Oliver Gröning、Myriam H. Aguirre 等 5 位作者2010-03-19Langmuir

We present for the first time a general vacuum process for the growth of supported organic nanowires formed by pi-conjugated molecules, including metalloporphyrins, metallophthalocyanines, and perylenes. This methodology consists on a one-step physical vapor deposition of the pi-conjugated molecules. The synthesis is…

Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistryMolecular Junctions and Nanostructures

Fluorescent Silicate Materials for the Detection of Paraoxon

Brandy J. Johnson、Brian J. Melde、Cassandra Thomas 等 8 位作者2010-03-19Sensors

Porphyrins are a family of highly conjugated molecules that strongly absorb visible light and fluoresce intensely. These molecules are sensitive to changes in their immediate environment and have been widely described for optical detection applications. Surfactant-templated organosilicate materials have been described…

Mesoporous Materials and CatalysisPorphyrin and Phthalocyanine ChemistryAnalytical Chemistry and Sensors

Scattering matrix approach to multichannel transport in many lead graphene nanoribbons

Davide Mencarelli、T. Rozzi、Luca Pierantoni2010-03-19Nanotechnology

Multichannel analysis of graphene nanoribbons (GNR), often required for describing applications to practical devices, constitutes a heavy computational task, even in a simplified framework like that provided by discrete or nearest neighbour models. Scattering (S) matrix techniques, widely used for quantum transport in…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

Magnetic excitations of Fe1 +ySexTe1 −xin magnetic and superconductive phases

P. Babkevich、M. Bendele、A. T. Boothroyd 等 8 位作者2010-03-19Journal of Physics Condensed Matter

We have used inelastic neutron scattering and muon-spin rotation to compare the low energy magnetic excitations in single crystals of superconducting Fe(1.01)Se(0.50)Te(0.50) and non-superconducting Fe(1.10)Se(0.25)Te(0.75). We confirm the existence of a spin resonance in the superconducting phase of Fe(1.01)Se(0.50)T…

Rare-earth and actinide compoundsIron-based superconductors researchInorganic Chemistry and Materials

Domain walls at the spin-density-wave endpoint of the organic superconductor(TMTSF)2PF6under pressure

Namhyun Kang、B. Salameh、Pascale Auban‐Senzier 等 6 位作者2010-03-19Physical Review B

We report a comprehensive investigation of the organic superconductor ${(\text{TMTSF})}_{2}{\text{PF}}_{6}$ in the vicinity of the endpoint of the spin-density-wave metal phase transition where phase coexistence occurs. At low temperature, the transition of metallic domains toward superconductivity is used to reveal t…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research

Properties of broadband depth-graded multilayer mirrors for EUV optical systems

Andrey Yakshin、I. V. Kozhevnikov、E. Zoethout 等 5 位作者2010-03-19Optics Express

The optical properties of a-periodic, depth-graded multilayer mirrors operating at 13.5 nm wavelength are investigated using different compositions and designs to provide a constant reflectivity over an essentially wider angular range than periodic multilayers. A reflectivity of up to about 60% is achieved in these ca…

Advanced Surface Polishing TechniquesOptical Coatings and GratingsSurface Roughness and Optical Measurements

Biological monitoring of lotic ecosystems: the role of diatoms

Taurai Bere、JG. Tundisi2010-03-19Brazilian Journal of Biology

Increasing anthropogenic influence on lotic environments as a result of civilisation has captured public interest because of the consequent problems associated with deterioration of water quality. Various biological monitoring methods that provide a direct measure of ecological integrity by using the response of biota…

Aquatic Ecosystems and Phytoplankton DynamicsEnvironmental Toxicology and EcotoxicologyDiatoms and Algae Research

Thermal and Optical Properties of CdS Nanoparticles in Thermotropic Liquid Crystal Monomers

Hooi Ling Lee、Issam Ahmed Mohammed、M. Belmahi 等 6 位作者2010-03-19Materials

Two new mesogenic monomers, namely 3,3’-dimethoxy-4,4’-di(hydroxyhexoxy)-N-benzylidene-o-Tolidine (Ia) and 4,4’-di(6-hydroxyhexoxy)-N-benzylidene-o-Tolidine (IIa), were reacted with cadmium sulfide (CdS) via an in situ chemical precipitation method in ethanol to produce CdS nanocomposites. A series of different mass c…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPhotochemistry and Electron Transfer Studies

Electronic structure, localization, and spin-state transition in Cu-substitutedFeSe:Fe1−xCuxSe

Stanislav Chadov、Daniel Schärf、Gerhard H. Fecher 等 6 位作者2010-03-19Physical Review B

We report density-functional studies of the ${\text{Fe}}_{1\ensuremath{-}x}{\text{Cu}}_{x}\text{Se}$ alloy done using supercell and coherent-potential approximation methods. Magnetic behavior was investigated using the disordered local moment approach. We find that Cu occurs in a nominal ${d}^{10}$ configuration and i…

Magnetic properties of thin filmsRare-earth and actinide compoundsIron-based superconductors research

Two cases of nephrogenic systemic fibrosis after exposure to the macrocyclic compound gadobutrol

Tina Rask Elmholdt、Bettina Jørgensen、Mette Ramsing 等 5 位作者2010-03-19Clinical Kidney Journal

Nephrogenic systemic fibrosis (NSF) is a disease with progressive fibrosis. We describe two cases of NSF after exposure to a macrocyclic gadolinium-based contrast agent (GBCA) gadobutrol, which has been considered as a low-risk agent compared to linear GBCAs. The first case had chronic kidney disease (CKD) Stage 3 and…

Luminescence Properties of Advanced MaterialsAdvanced MRI Techniques and ApplicationsLanthanide and Transition Metal Complexes

Optical spectra of ZnO in the far ultraviolet: First-principles calculations and ellipsometric measurements

Paola Gori、M. Rakel、Christoph Cobet 等 9 位作者2010-03-19Physical Review B

We present ellipsometry data of the dielectric function of wurtzite ZnO in a wide energy range (2.5-32 eV). The ordinary and extraordinary components show a strong anisotropy above 10 eV, a feature for which ZnO deviates from the other II-VI wurtzite compounds. With the aid of ab initio calculations, performed within…

ZnO doping and propertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Poly(isoglycerol methacrylate)-b-poly(d or l-lactide) Copolymers: A Novel Hydrophilic Methacrylate as Building Block for Supramolecular Aggregates

Florian Wolf、Anna Maria Hofmann、Holger Frey2010-03-19Macromolecules

On the basis of a new acetal-protected glycerol monomethacrylate monomer ( cis -1,3-benzylidene glycerol methacrylate/BGMA) a series of potentially biocompatible and partially biodegradable homo- and block copolymers were synthesized. ATRP polymerization of BGMA yielded well-defined polyacrylates with pendant benzylid…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesSynthetic Organic Chemistry Methods

Controlled Storage of Ferrocene Derivatives as Redox-Active Molecules in Dendrimers

Yousuke Ochi、Mana Suzuki、Takane Imaoka 等 7 位作者2010-03-19Journal of the American Chemical Society

Dendritic polyphenylazomethines (DPA) could encapsulate ferroceniums by complexation of the electron-donating skeleton of the DPA imines. Upon addition of ferroceniums to a series of dendritic polyphenylazomethines (DPAGX, where X is the generation number, X = 1-4), the UV-vis spectra showed changes in a manner simila…

Molecular Junctions and NanostructuresDendrimers and Hyperbranched PolymersFerrocene Chemistry and Applications

Influence of various retting methods on properties of kenaf fiber

Hongqin Yu、Chongwen Yu2010-03-19Journal of the Textile Institute

Gum, as the important noncellulosic tissue present in kenaf fiber, has a close relation with downstream processing and product properties, so the predominant task in pretreatment of kenaf fiber for textile application, retting, is to remove gum including pectin, hemicellulose, lignin, and other impurities without dama…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesTextile materials and evaluations