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第 196511 / 199632 页 · 当前展示 3,930,201–3,930,220 / 3,992,636 条匹配结果 · 摘要仅作预览

Stable polyradicals with high-spin ground states. 1. Synthesis, separation, and magnetic characterization of the stereoisomers of 2,4,5,6-tetrachloro-.alpha.,.alpha.,.alpha.',.alpha.'-tetrakis(pentachlorophenyl)-m-xylylene biradical

Jaume Veciana、Concepció Rovira、M. Crespo 等 6 位作者1991-03-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStable polyradicals with high-spin ground states. 1. Synthesis, separation, and magnetic characterization of the stereoisomers of 2,4,5,6-tetrachloro-.alpha.,.alpha.,.alpha.',.alpha.'-tetrakis(pentachlorophenyl)-m-xylylene biradicalJaume Veciana, Concepcio Rovira, Maria I. C…

Magnetism in coordination complexesSynthesis and Properties of Aromatic CompoundsAdvanced NMR Techniques and Applications

Host-guest complexation. 55. Guest capture during shell closure

Judi Bryant、Michael T. Blanda、Marco Vincenti 等 4 位作者1991-03-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHost-guest complexation. 55. Guest capture during shell closureJudi A. Bryant, Michael T. Blanda, Marco Vincenti, and Donald J. CramCite this: J. Am. Chem. Soc. 1991, 113, 6, 2167–2172Publication Date (Print):March 1, 1991Publication History Published online1 May 2002Publish…

Radioactive element chemistry and processingCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies

FTIRS in water demonstrates that collagen monomers undergo a conformational transition prior to thermal self-assembly in vitro

Anne George、Arthur Veis1991-03-01Biochemistry

The assembly of type I collagen molecules into native fibrils can be accomplished in vitro in solutions at physiological ionic strength and pH by raising the temperature above 30 degrees C. The thermal self-assembly reaction exhibits a distinct lag phase. This lag phase has been proposed to be evidence for a conformat…

Meat and Animal Product QualityMarine Biology and Environmental ChemistryCollagen: Extraction and Characterization

Effects of pairwise versus many-body forces on high-stress plastic deformation

Brad Lee Holian、Arthur F. Voter、Norman J. Wagner 等 9 位作者1991-03-01Physical Review A

We propose a model embedded-atom (many-body) potential and test it against an effective, density-independent, pairwise-additive potential in a variety of nonequilibrium molecular-dynamics simulations of plastic deformation under high stress. Even though both kinds of interactions have nearly the same equilibrium equat…

Microstructure and mechanical propertiesHigh-pressure geophysics and materialsIon-surface interactions and analysis

The influence of organic matter in organogenic dolomitization

M. Slaughter、R. J. Hill1991-03-01Journal of Sedimentary Research

Abstract We hypothesize that the decomposition of organic debris derived from plants, planktonic animals, and algae by sulfate-reducing bacteria, and specifically by the enzymatic degradation of protein, is vital to organogenic dolomitization. The role of this degradation is to increase both alkalinity and pH of the p…

Paleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation Techniques

Penetration of Strain-Hardening Targets With Rigid Spherical-Nose Rods

M. J. Forrestal、N. S. Brar、V.K. Luk1991-03-01Journal of Applied Mechanics

We developed engineering models that predict forces and penetration depth for long, rigid rods with spherical noses and rate-independent, strain-hardening targets. The spherical cavity expansion approximation simplified the target analysis, so we obtained closed-form penetration equations that showed the geometric and…

High-pressure geophysics and materialsEnergetic Materials and CombustionHigh-Velocity Impact and Material Behavior

Anion‐exchange membrane, water, and sodium bicarbonate extractions as soil tests for phosphorus

J.J. Schoenau、W.Z. Huang1991-03-01Communications in Soil Science and Plant Analysis

Three techniques were evaluated as soil P tests for western Canadian soils: anion‐exchange membrane (AEM), water, and bicarbonate extraction. The AEM, water, and bicarbonate‐extractable total P represented novel approaches to compare to the widely used bicarbonate‐extractable inorganic P (traditional Olsen) soil test.…

Soil Carbon and Nitrogen DynamicsSoil and Water Nutrient DynamicsClay minerals and soil interactions

Nematic-isotropic phase transition in a liquid-crystal droplet

Samo Kralj、S. Žumer、D. W. Allender1991-03-01Physical Review A

Possible phases in a nematic liquid crystal confined to a spherical submicrometer droplet embedded in a solid polymer are analyzed in terms of a Landau--de Gennes theory. For a droplet with a radial structure we show that the strength of the nematic-polymer interfacial interaction affects the nematic-paranematic (part…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Synthesis of nonionic gadolinium chelates useful as contrast agents for magnetic resonance imaging: 1,4,7-tris(carboxymethyl)-10-substituted-1,4,7,10-tetraazacyclododecanes and their corresponding gadolinium chelates

Douglas D. Dischino、Edward J. Delaney、John Emswiler 等 7 位作者1991-03-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of nonionic gadolinium chelates useful as contrast agents for magnetic resonance imaging: 1,4,7-tris(carboxymethyl)-10-substituted-1,4,7,10-tetraazacyclododecanes and their corresponding gadolinium chelatesD. D. Dischino, E. J. Delaney, J. E. Emswiler, G. T. Gaugha…

Medical Imaging Techniques and ApplicationsLanthanide and Transition Metal ComplexesRadiopharmaceutical Chemistry and Applications

Nuclear magnetic resonance studies on electrochemically prepared poly(3-dodecylthiophene)

Masa‐aki Sato、Hisayuki Morii1991-03-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNuclear magnetic resonance studies on electrochemically prepared poly(3-dodecylthiophene)Masaaki Sato and Hisayuki MoriiCite this: Macromolecules 1991, 24, 5, 1196–1200Publication Date (Print):March 1, 1991Publication History Published online1 May 2002Published inissue 1 Mar…

Conducting polymers and applicationsForce Microscopy Techniques and ApplicationsElectrochemical Analysis and Applications

Effect of soft segment chemistry on the biostability of segmented polyurethanes. I. In vitro oxidation

Atsushi Takahara、Arthur J. Coury、Robert W. Hergenrother 等 4 位作者1991-03-01Journal of Biomedical Materials Research

A series of segmented polyurethanes (SPUs) containing various polyol soft segments was prepared and their resistance to oxidative degradation was investigated after aging in AgNO3 solution. The SPU with the polyether soft segment showed a large reduction in mechanical strength after exposure to the oxidative environme…

biodegradable polymer synthesis and propertiesPolymer composites and self-healingMarine Biology and Environmental Chemistry

N-body interatomic potentials for hexagonal close-packed metals

M. Igarashi、M. Khantha、V. Vítek1991-03-01Philosophical Magazine B

Finnis-Sinclair (F-S) type many-body potentials have been constructed for eight hexagonal metals: Co, Zr, Ti, Ru, Hf, Zn, Mg and Be. The potentials are parameterized using cubic splines and fitted to the cohesive energy, unrelaxed vacancy formation energy, five independent second-order elastic constants and two eauili…

High-pressure geophysics and materialsRare-earth and actinide compoundsBoron and Carbon Nanomaterials Research

Screening in sedimenting suspensions

Donald L. Koch、Eric S. G. Shaqfeh1991-03-01Journal of Fluid Mechanics

Caflisch & Luke (1985) showed that, owing to the long range of the hydrodynamie interactions, the variance of the sedimentation velocity in a random suspension with uniform probability for the positions of the particles is divergent in the sense that it grows without bound as the macroscopic linear dimension of th…

Material Dynamics and PropertiesHeat and Mass Transfer in Porous MediaElectrostatics and Colloid Interactions

Anisotropic gels and plasticized networks formed by liquid crystal molecules

R. A. M. Hikmet1991-03-01Liquid Crystals

Two component mixtures containing liquid crystalline diacrylates and liquid crystal molecules with no reactive groups have been made. Upon photopolymeriz-ation of the mixtures anisotropic networks containing liquid crystal molecules which were not chemically attached to the networks were created. In these systems the…

Liquid Crystal Research AdvancementsAdvanced Polymer Synthesis and CharacterizationPhotopolymerization techniques and applications

Mutually interpenetrating inorganic-organic networks. New routes into nonshrinking sol-gel composite materials

Mark W. Ellsworth、Bruce M. Novak1991-03-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMutually interpenetrating inorganic-organic networks. New routes into nonshrinking sol-gel composite materialsMark W. Ellsworth and Bruce M. NovakCite this: J. Am. Chem. Soc. 1991, 113, 7, 2756–2758Publication Date (Print):March 1, 1991Publication History Published online1 M…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Direct In Situ Evidence for Proton/Anion Exchange in Polyaniline Films by Means of Probe Beam Deflection

César A. Barbero、M.C. Miras、Otto Haas 等 4 位作者1991-03-01Journal of The Electrochemical Society

Probe beam deflection (PBD) was used to monitor the ion exchange between polymer film and bulk electrolyte during the redox reaction in polyaniline in aqueous electrolyte ( , , ). The PBD results clearly show that protons as well as anions are exchanged during the first oxidation process. Protons are exchanged at pote…

Fuel Cells and Related MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Comb-burst dendrimer topology: new macromolecular architecture derived from dendritic grafting

Donald A. Tomalia、David M. Hedstrand、Michael S. Ferritto1991-03-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTComb-burst dendrimer topology: new macromolecular architecture derived from dendritic graftingDonald A. Tomalia, David M. Hedstrand, and Michael S. FerrittoCite this: Macromolecules 1991, 24, 6, 1435–1438Publication Date (Print):March 1, 1991Publication History Published onl…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesDendrimers and Hyperbranched Polymers

Physiology and molecular genetics of poly(β‐hydroxyalkanoic acid) synthesis in Alcaligenes eutrophus

Alexander Steinbüchel、H. G. Schlegel1991-03-01Molecular Microbiology

The Alcaligenes eutrophus genes for beta-ketothiolase, NADPH-dependent acetoacetyl-CoA reductase and poly(beta-hydroxybutyric acid) synthase (PHB synthase) which comprise the three-step PHB-biosynthetic pathway, were cloned. Molecular studies revealed that these genes are organized in a single operon. The A. eutrophus…

biodegradable polymer synthesis and propertiesMicrobial Metabolic Engineering and BioproductionEnzyme Production and Characterization

Interface Microstructures in Concrete

Francisca Puertas、Ángel Palomo、M.ª Teresa Blanco1991-03-01Materiales de Construccion

This paper constitutes a compilation as well as an interpretation of the present state of knowledge about the different microstructures developed in the interface areas of concrete, that is, the cement paste-aggregates, the cement paste-reinforcement, the cement paste-fiber, etc. The Chemical reactions taking place in…