Materials Literature
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We report on the linear and nonlinear-optical properties of 4-dimethylamino-4′-nitrostilbene (DANS), 4-diethylamino-1-nitrobenzyl (DANB), and 4-[N-ethyl-N-(2-hydroxyethyl)]amino-4′-nitroazobenzene) (Disperse Red 1;DR1) side chain polymers whose second-harmonic generation at the telecommunication wavelength of 1.55 μm…
High-field antiferromagnetic-resonance (AFMR) spectra were obtained in the frequency range $40 \mathrm{GHz}<\ensuremath{\nu}<700 \mathrm{GHz}$ and for magnetic fields up to 8 T in twin-free single crystals of ${\mathrm{La}}_{0.95}{\mathrm{Sr}}_{0.05}{\mathrm{MnO}}_{3}.$ At low temperatures two antiferromagnetic…
Cs3Sb7 und Cs4Sb2 wurden aus den Elementen dargestellt und ihre Kristallstrukturen auf der Basis von Röntgeneinkristalldaten ermittelt. Cs3Sb7 kristallisiert monoklin in der Raumgruppe P21/c (a = 1605.7(1) pm, b = 1571.1(1) pm, c = 2793.9(2) pm, β = 96.300(2)°, Z = 16) und enthält Anionen Sb73–. In der Kristallstruktu…
We have studied the ground-state properties of Ge-related paramagnetic defect centers in Ge-doped silica. Hartree-Fock and density functional theory calculations have been performed to determine the structure, charge, and spin distribution of paramagnetic defects in Ge-doped silica, in particular a trapped electron at…
In this study, the effect of bismuth content on phase-transition behavior, ferroelectric property, and crystal structure of strontium–bismuth–tantalate (SBT) ceramics was explored with the aid of εr(T), ferroelectric hysteresis loop, x-ray diffraction (XRD), and Raman spectroscopy. Both the phase-transition behavior a…
A number of woven fabrics are selected and their rustling sounds recorded. The spectra forms of these recorded sounds are then obtained by FFT. The level pressure of total sound (LPT) is calculated to evaluate sound loudness of specimens. Level range (Δ L) and frequency differences (Δ f) are used to quantify sound spe…
A gold contact with polypyrrole (PPy) doped with the copper phthalocyanine toluenesulfonate (CuPcTS) anion (Au/PPy-CuPcTS) was studied using complex impedance spectroscopy, current density voltage ( J - V ) and capacitance voltage ( C - V ) measurements. The J - V characteristics of these junctions are asymmetrical an…
A well characterized homogeneous ceramic sample of ${\mathrm{La}}_{0.7}{\mathrm{Ca}}_{0.3}{\mathrm{M}\mathrm{n}(}^{57}{\mathrm{C}\mathrm{o})\mathrm{O}}_{3}$ shows two ferromagnetic phases below ${T}_{c}$ in contrast to the 20% Ca compound where only one is observed. One of the phases exhibits stronger exchange interac…
Using Monte Carlo simulations we study the dynamics of three-dimensional Ising models with nearest-, next-nearest-, and four-spin (plaquette) interactions. During coarsening, such models develop growing energy barriers, which leads to very slow dynamics at low temperature. As already reported, the model with only the…
Abstract Analytical electron microscopy of representative smectites from soils and sediments revealed that K was present in significant proportions. It was the major interlayer cation in soils from pelitic rocks, continental and marine sediments, independent of their diagenetic grade. Sodium was predominant only in so…
The effect of Cu substitution for Mn in layered manganese oxides ${\mathrm{La}}_{1.4}{\mathrm{Sr}}_{1.6}{\mathrm{Mn}}_{2\ensuremath{-}x}{\mathrm{Cu}}_{x}{\mathrm{O}}_{7}$ on magnetic and transport properties has been investigated. It is interesting that the undoped samples undergo complex transitions with lowing tempe…
After a few hundred years in a geologic repository, α-emissions will dominate the radiation field in and around spent nuclear fuel. In the event of a failure of the spent fuel container, the dissolution of the uranium dioxide matrix in contact with groundwater could be enhanced by α-radiolysis, which could create oxid…
We report on the growth of 99,9 % enriched 28Si, dislocation free monocrystals (111- and 100-orientated) with nearly 10 g weight and less than 1015 foreign atoms/cm3.
A redox-active alternating π-conjugated copolymer of ferrocene with dithiafulvene was synthesized by cycloaddition polymerization of aldothioketene derived from 1,1‘-bis(trimethylsilylethynyl)ferrocene ( 1 ). The obtained polymer ( 2 ) was soluble in common organic solvents such as THF, CH 2 Cl 2, CHCl 3, DMF, and DMS…
Silicon (Si)-doped diamond-like carbon (DLC) was prepared on Si(100) and polymethyl metha_crylate (PMMA) substrates using a C2H2–SiH4–Ar plasma immersion ion processing (PIIP) method. The chemical composition of the films was varied by adjusting the reactive gas-flow ratio of SiH4 to C2H2 during PIIP depositions. The…
Abstract A new prominent gelator 1, Nε-lauroyl-Nα-stearylaminocarbonyl-l-lysine ethyl ester was effortlessly prepared by esterification of Nε-lauroyl-l-lysine and addition of n-octadecyl isocyanate in a total yield of 89%. Gelator 1 was capable of gelling up a wide variety of organic fluids. A comparison of the gelati…
Theoretical analysis and extensive numerical simulations are performed on the system of a spherical absorber illuminated by a pulsed laser. Both bubble formation and shock wave generation are investigated. We find that a strong shock front forms just outside the absorber and attenuates quickly into an acoustic wave as…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTPredictions and Assignments of NMR Spectra for Strongly Paramagnetic Supramolecular Lanthanide Complexes: The Effect of the "Gadolinium Break"Stéphane Rigault and Claude PiguetView Author Information Department of Inorganic, Analytical and Applied Chemistry University…
To obtain powder with a composition of 3 mol% Y 2 O 3 –97 mol% ZrO 2 , a process of Y‐Zr oxalate powder production has been optimized, to produce an oxalate with minimal particle size. The methodology of the nonisothermal decomposition of Y‐Zr oxalate has been explained. Characteristics of the nonisothermal decomposit…
Accurate quantitative X‐ray diffraction analysis of SiC‐based ceramics is difficult because of the significant overlap of the Bragg reflections from the different SiC polytypes. In this regard, the Rietveld method is a powerful tool for the accurate and precise analysis of the phase/polytype compositions in these mate…