Materials Literature
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In order to clarify the tritium behavior in Pb–Li blanket system, the solubility of hydrogen isotopes in the Pb–Li eutectic alloy was experimentally investigated. The effects of (i) Li preferential evaporation from Pb–Li, (ii) thermal convection in a quartz-glass reaction tube and (iii) difference in crucible material…
Monetite is a phosphate mineral formed by the reaction of the chemicals in bat guano with calcite substrates and is commonly found in caves. The analog of the mineral monetite CaHPO4 has been synthesized and the Raman and infrared spectra of the natural monetite originating from the Murra-el-elevyn Cave, Eucla, Wester…
Abstract This study explored the combined influence of shear flow and nucleating agents on isotactic polypropylene (iPP) crystallisation. The study showed that oriented α‐iPP crystals were not necessary to form β‐iPP crystals, contrary to the accepted view that the surface of oriented α‐iPP crystals provides nucleatio…
A simple fluid, in a microscopic capillary capped at one end, is studied by means of fundamental measure density functional. The model represents a single, infinitely long nanogroove with long-range wall-fluid attractive (dispersion) forces. It is shown that the presence or absence of hysteresis in adsorption isotherm…
Four hundred tons of sulfamethazine are fed to livestock annually in North America to prevent disease and promote growth, but most of the drug is excreted unmetabolized into the environment. Because of slow degradation and high mobility, sulfamethazine contaminates groundwater supplies and causes aquatic ecosystem dam…
Abstract We report on the characterization of wide-band-gap heterojunction diodes based on the p-ZnO/n-GaN material system. The layer structure consists of 11 µ m GaN on sapphire substrates and As-doped ZnO film of thickness 0.4 µ m obtained by plasma-assisted molecular beam epitaxy (PA-MBE). The quality of the hetero…
Thermoreversible polyurethane networks were successfully prepared by Diels–Alder reaction using a highly maleimide-functionalized urethane prepolymer with an epoxy-based furan coupling agent or a furan-functionalized polyurethane. Highly functional maleimide prepolymers with various functionalities were synthesized by…
A facile method for synthesis of CdS nanoparticles has been described. Monodisperse face-centered cubic CdS NPs could be synthesized in switchable surfactant reverse micelles. The micelles could be broken easily and CdS NPs without a coating of surfactants could be obtained by bubbling N(2) at 65 °C.
A new inorganic-organic hybrid In(2)Se(3)(en) was synthesized as hollow nanospheres via a facile and controllable hydrothermal method in a system containing ethylenediamine (en) and hydrazine hydrate. These as-obtained hybrid hollow nanospheres with an average diameter of 200 nm were assembled by irregularly small-siz…
The antibiotic resistance developed among several pathogenic bacterial strains has spurred interest in understanding bacterial adhesion down to a molecular level. Consequently, analytical methods that rely on bioactive and multivalent sensor surfaces are sought to detect and suppress infections. To deliver functional…
Heterotetranuclear geometrical (Er 2 Yb 2 /Yb 2 Er 2 ) and configuational (EuTb 3 /Eu 3 Tb) isomeric lanthanide(III) complexes have been synthesized and characterized by spectroscopy as well as X-ray crystallography. The geometric Er 2 Yb 2 /Yb 2 Er 2 isomers exhibit dual emissions from both erbium(III) and ytterbium(…
Bombyx mori cypovirus is a major pathogen which causes significant losses in silkworm cocoon harvests because the virus particles are embedded in micrometer-sized protein crystals called polyhedra and can remain infectious in harsh environmental conditions for years. But the remarkable stability of polyhedra can be ap…
The importance of surfactant self-assemblies in foam stabilization is well-known. The aim of the current study was to investigate the self-assemblies of the nonionic surfactant polyglycerol ester (PGE) in bulk solutions, at the interface and within foams, using a combined approach of small-angle neutron scattering, ne…
Einzelmoleküle: Über die durch synthetisierte Goldnanostäbe bis zu 1100-fach verstärkte Fluoreszenz von Einzelmolekülen wird berichtet (siehe Bild). Die hohe Verstärkung wird durch die Auswahl des Farbstoffs erreicht, dessen Adsorption und Emission in der Nähe der Oberflächenplasmonenresonanzen der Goldnanostäbe liege…
Here, we report the preparation and characterization of hollow polymer microspheres based on the preprecipitation of porous calcium carbonate cores with an average size of 5 μm and their use for encapsulation of living microorganisms. The microspheres filled with individual living E. coli cells were prepared by layer-…
The relationship between the strain and defect structure in gadolinia-doped ceria has been studied with atomistic simulations. It was found that the next nearest neighbor type associations are preferred under zero or tensile applied strains, but the nearest neighbor type defect associations became favorable under comp…
Abstract Calix[4]phyrins are an important class of hybrid macrocyclic systems at the interface between porphyrins and calixpyrroles (porphyrinogens). A new stepwise synthesis of oxidation‐resistant meso ‐hydrogenated calix[4]phyrins is reported, which allows variable substitution in the residues of their sp 2 ‐ meso ‐…
Plasma aided materials conversion is the use of charged particles for producing new materials with unusual and superior properties or to convert unwanted materials such as waste into environmentally friendly products. The near LTE plasma (in atmospheric or reduced pressure) is a nice tool for engineering of materials…
The solubility of l -lactide in pure ethanol, ethyl acetate, acetone, isopropanol, methanol, and methylbenzene from (278.15 to 338.15) K was determined by dynamic method with a laser monitoring technique. It was found that l -lactide is sparingly soluble in ethanol, isopropanol, methanol, and methylbenzene while it ha…
Enhanced luminescence in rare‐earth‐doped chalcogenide glass–ceramics is of great interest for the potential integrated optoelectronic devices. However, fundamental mechanism on the enhancement of luminescence upon crystallization remains largely unknown. We report the fabrication and characterization of wide transmis…