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Highly Efficient and Stable Solar Cells Based on Thiazolothiazole and Naphthobisthiadiazole Copolymers

Masahiko Saito、Itaru Osaka、Yasuhito Suzuki 等 7 位作者2015-09-23Scientific Reports

A critical issue in polymer-based solar cells (PSCs) is to improve the power conversion efficiency (PCE) as well as the stability. Here, we describe the development of new semiconducting polymers consisting of thiophene, thiazolothiazole and naphthobisthiadiazole in the polymer backbone. The polymers had good solubili…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Interplay of Molecular Orientation, Film Formation, and Optoelectronic Properties on Isoindigo- and Thienoisoindigo-Based Copolymers for Organic Field Effect Transistor and Organic Photovoltaic Applications

Chien Lu、Hsieh‐Chih Chen、Wei‐Ti Chuang 等 6 位作者2015-09-23Chemistry of Materials

A systematic study on the effects of heteroarenes on the solid state structure and optoelectronic properties of isoindigo analogues, namely, PBDT-IIG and PBDT-TIIG, used in solution-processed organic field effect transistors (OFETs) and organic photovoltaics (OPVs) is reported. We discover that the optical absorption,…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Self‐Recovering Triboelectric Nanogenerator as Active Multifunctional Sensors

Mingyuan Ma、Qingliang Liao、Guangjie Zhang 等 6 位作者2015-09-23Advanced Functional Materials

A novel self‐recovering triboelectric nanogenerator (STENG) driven by airflow is designed as active multifunctional sensors. A spring is assembled into the STENG and enables the nanogenerator to have self‐recovering characteristic. The maximum output voltage and current of the STENG is about 251 V and 56 μA, respectiv…

Advanced Sensor and Energy Harvesting MaterialsGas Sensing Nanomaterials and SensorsConducting polymers and applications

Host–Guest Interaction-Based Self-Engineering of Nano-Sized Vesicles for Co-Delivery of Genes and Anticancer Drugs

Bin Yang、Dong Xing、Qi Lei 等 6 位作者2015-09-23ACS Applied Materials & Interfaces

On the basis of host-guest interactions, this study reported a kind of linear-hyperbranched supramolecular amphiphile and its assembled vesicles for the combined achievement of drug encapsulation and DNA delivery. Amine-attached β-cyclodextrin-centered hyperbranched polyglycerol and linear adamantane-terminated octade…

Advanced biosensing and bioanalysis techniquesRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Hierarchical SnO2/Carbon Nanofibrous Composite Derived from Cellulose Substance as Anode Material for Lithium‐Ion Batteries

Mengya Wang、Shun Li、Yiming Zhang 等 4 位作者2015-09-23Chemistry - A European Journal

A hierarchical fibrous SnO2 /carbon nanocomposite composed of fine SnO2 nanocrystallites immobilized as a thin layer on a carbon nanofiber surface was synthesized employing natural cellulose substance as both scaffold and carbon source. It was achieved by calcination/carbonization of the as-deposited SnO2 -gel/cellulo…

Advancements in Battery MaterialsSupercapacitor Materials and Fabrication

2D-Conjugated Benzodithiophene-Based Polymer Acceptor: Design, Synthesis, Nanomorphology, and Photovoltaic Performance

Long Ye、Xuechen Jiao、Hao Zhang 等 7 位作者2015-09-23Macromolecules

All polymer photovoltaic cells offer unique potentials owing to the chemical and electronic tunability of both polymer donors and polymer acceptors. Compared with the numerous π-conjugated polymer donors, choices of π-conjugated polymer acceptors are limited for photovoltaic applications. Although 2D-conjugated benzo[…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Effective Two-Photon Excited Photodynamic Therapy of Xenograft Tumors Sensitized by Water-Soluble Bis(arylidene)cycloalkanone Photosensitizers

Qianli Zou、Hongyou Zhao、Yuxia Zhao 等 10 位作者2015-09-23Journal of Medicinal Chemistry

A series of bis(arylidene)cycloalkanone photosensitizers modified by polyethylene glycol (PEG) have been studied for two-photon excited photodynamic therapy (2PE-PDT). As compared with their prototype compounds, these PEGylated photosensitizers show enhanced water solubilities while their photophysical and photochemic…

Nanoplatforms for cancer theranosticsPhotodynamic Therapy Research StudiesPhotochromic and Fluorescence Chemistry

Highly Dispersed SiO x /Al 2 O 3 Catalysts Illuminate the Reactivity of Isolated Silanol Sites

Aidan R. Mouat、Cassandra George、Takeshi Kobayashi 等 7 位作者2015-09-23Angewandte Chemie International Edition

The reaction of γ-alumina with tetraethylorthosilicate (TEOS) vapor at low temperatures selectively yields monomeric SiO(x) species on the alumina surface. These isolated (-AlO)3Si(OH) sites are characterized by PXRD, XPS, DRIFTS of adsorbed NH3, CO, and pyridine, and (29)Si and (27)Al DNP-enhanced solid-state NMR spe…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisAdvanced NMR Techniques and Applications

Coupling Protein Side-Chain and Backbone Flexibility Improves the Re-design of Protein-Ligand Specificity

Noah Ollikainen、René M. de Jong、Tanja Kortemme2015-09-23PLoS Computational Biology

Interactions between small molecules and proteins play critical roles in regulating and facilitating diverse biological functions, yet our ability to accurately re-engineer the specificity of these interactions using computational approaches has been limited. One main difficulty, in addition to inaccuracies in energy…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

Pressure—A Gateway to Fundamental Insights into Protein Solvation, Dynamics, and Function

Trung Quan Luong、Shobhna Kapoor、Roland Winter2015-09-23ChemPhysChem

Now that the centennial anniversary of the first report on pressure denaturation of proteins by Nobel Laureate P. W. Bridgman can be celebrated, this Review on the application of high pressure as a key variable for studying the energetics and interactions of proteins appears. We demonstrate that combined temperature-p…

Protein Structure and DynamicsEnzyme Structure and FunctionHemoglobin structure and function

Highly Selective and Sensitive Voltammetric Sensor Based on Ruthenium Nanoparticle Anchored Calix[4]amidocrown‐5 Functionalized Reduced Graphene Oxide: Simultaneous Determination of Quercetin, Morin and Rutin in Grape Wine

Serkan Elçin、Mehmet Lütfi Yola、Tanju Eren 等 5 位作者2015-09-23Electroanalysis

Abstract In this report, ruthenium nanoparticles (RuNPs) and calix[4]amidocrown‐5 (C4A5) were synthesized and grafted onto the surface of reduced graphene oxide (RGO) nanocomposite (RuNPs/C4A5/RGO). The morphologies of the nanocomposites were characterized by transmission electron microscope, scanning electron microsc…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Tolerance of Flexible MOFs toward Repeated Adsorption Stress

Volodymyr Bon、Negar Kavoosi、Irena Senkovska 等 4 位作者2015-09-23ACS Applied Materials & Interfaces

The adsorption/desorption cyclability of four flexible MOFs, namely, MIL-53(Al), ELM-11, DUT-8(Ni), and SNU-9, was studied at 298 K using n-butane as adsorptive. The detailed analysis of thermal response curves, physisorption isotherm data, powder X-ray diffraction patterns, as well as SEM images revealed the highly s…

Metal-Organic Frameworks: Synthesis and ApplicationsGas Sensing Nanomaterials and SensorsAdvanced Nanomaterials in Catalysis

Polypept(o)ides: Hybrid Systems Based on Polypeptides and Polypeptoids

Kristina Klinker、Matthias Barz2015-09-23Macromolecular Rapid Communications

Polypept(o)ides combine the multifunctionality and intrinsic stimuli-responsiveness of synthetic polypeptides with the "stealth"-like properties of the polypeptoid polysarcosine (poly(N-methyl glycine)). This class of block copolymers can be synthesized by sequential ring opening polymerization of α-amino acid N-carbo…

Advanced biosensing and bioanalysis techniquesPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Fluidic origami with embedded pressure dependent multi-stability: a plant inspired innovation

Suyi Li、K. W. Wang2015-09-23Journal of The Royal Society Interface

Inspired by the impulsive movements in plants, this research investigates the physics of a novel fluidic origami concept for its pressure-dependent multi-stability. In this innovation, fluid-filled tubular cells are synthesized by integrating different Miura-Ori sheets into a three-dimensional topological system, wher…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsPlant and Biological Electrophysiology Studies

Magnetic Saturation in Semi-Analytical Harmonic Modeling for Electric Machine Analysis

R. L. J. Sprangers、Johannes Paulides、B. L. J. Gysen 等 4 位作者2015-09-23IEEE Transactions on Magnetics

A semi-analytical method based on the harmonic modeling (HM) technique is presented for the analysis of the magneto-static field distribution in the slotted structure of rotating electric machines. In contrast to the existing literature, the proposed model does not require the assumption of infinite tooth permeability…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsElectromagnetic Simulation and Numerical Methods

Demagnetization Fault Indexes in Permanent Magnet Synchronous Motors—An Overview

Jawad Faiz、H. Nejadi-Koti2015-09-23IEEE Transactions on Magnetics

Demagnetization fault is the most widespread fault in permanent magnet synchronous motors (PMSMs). Diagnosing this fault and extracting appropriate indexes for the PMSM are proposed and discussed in this paper. The index-extracting techniques and their advantages, disadvantages, and significant ambiguities are propose…

Machine Fault Diagnosis TechniquesElectric Motor Design and AnalysisMagnetic Properties and Applications

Broadband Black Phosphorus Optical Modulator in the Spectral Range from Visible to Mid‐Infrared

Rui Zhang、Yuxia Zhang、Haohai Yu 等 8 位作者2015-09-23Advanced Optical Materials

Black phosphorus (BP), a two‐dimensional (2D) material, has a direct bandgap that can be tuned by changing the layers and applied strain, which fills the lacuna left by graphene topological insulators and transition‐metal dichalcogenides. Theoretically, the direct and tunable bandgap should enable broadband applicatio…

2D Materials and ApplicationsPhotonic and Optical DevicesAdvanced Fiber Laser Technologies

Seed-mediated growth of MOF-encapsulated Pd@Ag core–shell nanoparticles: toward advanced room temperature nanocatalysts

Liyu Chen、Binbin Huang、Xuan Qiu 等 6 位作者2015-09-23Chemical Science

a seed mediated growth strategy is reported and attributed to the presence of activated physisorbed hydrogen atoms on embedded Pd NPs as reducing agents to selectively direct the deposition of Ag onto Pd while minimizing the Ag self-nucleation. The obtained Pd@Ag core-shell NPs exhibited a significant increase in sele…

Metal-Organic Frameworks: Synthesis and ApplicationsDendrimers and Hyperbranched PolymersNanocluster Synthesis and Applications

Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)Ni II Complexes

Sherzod T. Madrahimov、James R. Gallagher、Guanghui Zhang 等 10 位作者2015-09-23ACS Catalysis

NU-1000-(bpy)Ni II, a highly porous MOF material possessing well-defined (bpy)Ni II moieties, was prepared through solvent-assisted ligand incorporation (SALI). Treatment with Et 2 AlCl affords a single-site catalyst with excellent catalytic activity for ethylene dimerization (intrinsic activity for butenes that is up…

Organometallic Complex Synthesis and CatalysisMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexes

High‐Throughput Continuous Flow Production of Nanoscale Liposomes by Microfluidic Vertical Flow Focusing

Renee R. Hood、Don L. DeVoe2015-09-23Small

Liposomes represent a leading class of nanoparticles for drug delivery. While a variety of techniques for liposome synthesis have been reported that take advantage of microfluidic flow elements to achieve precise control over the size and polydispersity of nanoscale liposomes, with important implications for nanomedic…

Nanoparticle-Based Drug DeliveryMicrofluidic and Bio-sensing TechnologiesInnovative Microfluidic and Catalytic Techniques Innovation