Materials Literature
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Fully characterized organic nanoparticles ( R1 ) decorated on the surface of ZnO ( N1 ), used for selective nanomolar determination of mercury ions.
The B12F12(-) radical anion was generated by oxidation of [CoCp2(+)]2B12F12(2-) with AsF5 in SO2. In the crystal structure of [CoCp2(+)]B12F12(-), the anion displays a lowered symmetry (D2h) instead of an Ih-symmetric dianion as a result of Jahn-Teller distortion. Moreover, shortening of the B-F bonds and subtle chang…
The modulation of quasi-one-dimensional plasmonic nanorods via the utilization of localized surface plasmon resonance is critical for achieving local dynamic tuning on the nanoscale as well as for fundamental studies. In particular, a magnetic field has been used as an effective external stimulus that can be activated…
In the last decade, many nanomachines with controlled molecular motions have been studied, mainly on metallic surfaces, which are easy to obtain very clean, and are stable over months. However, the studies of mechanical properties of nanomachines are mainly performed at very low temperatures, usually between 5 and 80…
Although many studies have been conducted on the wood property and chemical changes caused by thermal modification, little has been reported on the microstructural and topochemical changes occurring in the cell wall during heat treatment. In this study, poplar (Populus cathayaha) was treated within a temperature range…
An indanedione–coumarin conjugate behaves as an off–on type fluorescent receptor for rapid, selective, and sensitive detection of cyanide anions in an aqueous mixture via a nucleophilic interaction with the electrophilic β-carbon of the receptor.
Multidrug resistance (MDR) induced by chemotherapy in breast cancer frequently leads to tumor invasion, metastasis and poor clinical outcome. We preliminarily found that the epidermal growth factor receptor (EGFR) is involved in enhancing the malignant potential of MDR breast cancer cells, but the mechanism remains un…
High-temperature coatings for superalloys can be divided into three categories: Two of them, diffusion and overlay coatings, are both used to protect a system from oxidation and corrosion. The third type, thermal barrier coatings, protects the substrate from thermal degradation.
Two 11-ring-fused quinacridone derivatives, TTQA and DCNTTQA, have been synthesized by ferric chloride mediated cyclization and Knoevenagel reaction. Replacement of the carbonyl groups (in TTQA) with dicyanoethylene groups (in DCNTTQA) not only red-shifted the emission to the near-infrared region but also led to a non…
The prevalence of engineered metallic nanoparticles within electronic products has evoked a need to assess their occurrence and fate within environmental systems upon potential release of these nanoparticles. Quantum dots (QDs) are mixed-metal nanocrystals with the smallest of particle sizes (2–10 nm) that readily lea…
We propose a model that explains the phenomenon of polytypism in metal particle-seeded III–V semiconductor nanowires. The model is based on classical nucleation theory, utilizing the axial next-nearest-neighbor Ising (ANNNI) model to account for interlayer interaction up to the third nearest-neighboring layer. We inve…
Hispolon has been shown to have anticancer effects on various tumors. However, whether hispolon exerts anti-migration activity in breast cancer cells and the underlying mechanisms, have not been elucidated yet. In the present study, our data demonstrated that hispolon inhibited TPA-induced breast cancer MCF-7 cell mig…
Abstract This work presents a detailed characterisation of the MAST Scrape Off Layer in L-mode. Scans in line averaged density, plasma current and toroidal magnetic field were performed. A comprehensive and integrated study of the SOL was allowed by the use of a wide range of diagnostics. In agreement with previous re…
The energy from biomass can be utilized through the thermochemical conversion processes of pyrolysis and gasification. The Aspen Plus simulation tool is applicable for simulation of the gasification processes.
Conjugated semiconducting polymers, such as poly(3-hexylthiophene) (P3HT), are poised to play an integral role in the development of organic electronic devices; however, their performance is governed by factors that are intrinsically coupled: dopant concentration, carrier mobility, crystal structure, and mesoscale mor…
The response function of graphene is calculated in the presence of a constant current across the sample. For small drift velocities and finite chemical potential, analytic expressions are obtained and consequences on the plasmonic excitations are discussed. For general drift velocities and zero chemical potential, num…
The amphiphilic star-like copolymer polyethylenimine-block-poly(ε-caprolactone) (PEI-b-PCL) was utilized to transfer the pre-synthesized citrate-capped noble metal nanoparticles (NMNPs) from an aqueous layer to an organic layer without any additional reagents. Dynamic light scattering (DLS) and transmission electron m…
of PS (polystyrene), P2VP (poly(2-vinylpyridine)), and PEO (poly(ethylene oxide)), never reported before, were synthesized by combining atom transfer radical and anionic polymerizations. The synthesis involves the transformation of the -Br groups of the previously reported Br-terminated 3-arm star diblock copolymers t…
Recent developments in shape-controlled synthesis of metallic nano-particles present a promising path for precisely tuning chemical activity, selectivity, and stability of nano-materials. While previous studies have highlighted the macroscopic description of synthesis processes, there is less understanding as to wheth…
The interplay of interactions and disorder is studied using the Anderson-Hubbard model within the typical medium dynamical cluster approximation. Treating the interacting, nonlocal cluster self-energy $[{\mathrm{\ensuremath{\Sigma}}}_{c}[\stackrel{\ifmmode \tilde{}\else \~{}\fi{}}{\mathcal{G}}](i,j\ensuremath{\ne}i)]$…