Materials Literature
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A [3Fe-3(μ-S)](3+) cluster is reported in which each ferric center has a distorted trigonal pyramidal geometry, with an S = 1/2 ground state for the cluster and unusually anisotropic hyperfine coupling constants as determined by variable temperature magnetometry and Mössbauer spectroscopy.
over the linear range (0.12 mM to 12.93 mM) of cholesterol. This coating method offers easy and inexpensive processing with a flexible and robust supporting structure for biosensing applications.
A new three-dimensional coordination polymer, {[Co(μ2-H2O)(bdc)(H2O)(dmf)]·0.5H2O}n (1), was obtained as a by-product in the synthesis of the laminar solid {[Co2(μ2-H2O)(bdc)2(S-nia)2(H2O)(dmf)]·(dmf)2·H2O}n (2) (where H2bdc = 1,4-benzenedicarboxylic acid, S-nia = thionicotinamide, dmf = N,N′-dimethylformamide). The t…
Chemical energy storage by water splitting is a promising solution for the utilization of renewable energy in numerous currently impracticable needs, such as transportation and high temperature processing. Here, the synthesis of efficient ultra-fine Mn3O4 water oxidation catalysts with tunable specific surface area is…
Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation Arash Momeni, Mark Joseph Filiaggi; Rheology of polyphosphate coacervates. J. Rheol. 1 January 20…
A new collective motion of non-bubble-propelled spherical Janus catalytic micromotors has been observed. When the local concentration of micromotors is high, bubbles start to form between the motors. As the bubble grows, micromotors move collectively toward the center of the bubble regardless of the orientations of th…
Through implementation of the 3-D tri-gate topology, GaN-based high-electron mobility transistors (HEMTs) have been fabricated and high-frequency performances as well as the short-channel effects are investigated. The designed tri-gate transistors are highly-scaled having 100 nm of gate length, which introduces the co…
Natural products or products from the plant source show pivotal role in the diseases prevention and treatment since ancient. Numerous plants and their ingredients such as Nigella sativa, curcumin , olive and dates fruits have proven health promoting effects. In this vista, Papaya ( C. Papaya family Caricaceae) is a me…
The objective of this study was to evaluate the effects of toxic levels of aluminum (Al) on the growth and external morphology of root tips in two maize genotypes with differential Al tolerance. The maize genotypes UFVM-100 (Al-sensitive) and UFVM-200 (Al-tolerant) were treated with 0 and 50 mM Al in a 0.5 mM CaCl2 so…
During X-ray data collection from a multicopper oxidase (MCO) crystal, electrons and protons are mainly released into the system by the radiolysis of water molecules, leading to the X-ray-induced reduction of O2 to 2H2O at the trinuclear copper cluster (TNC) of the enzyme. In this work, 12 crystallographic structures…
GaAs photocathodes are intrinsically stabilized by surface As during hydrogen evolution at −15 mA cm −2 in acid; etching at <0.5 nm h −1 while maintaining performance.
In this paper, we report on the engineering and the realization of optically transparent graphene-based microwave devices using Chemical Vapour Deposition (CVD) graphene whose sheet resistance may be tailored down to values below 30 Ω/sq. In particular, we show that the process was successfully used to realize and cha…
A new approach to largely enhancing light harvesting of solar cells by employing bifunctional polymer nanocomposites as hole-transport layers (HTLs) is proposed. To illustrate our working principle, CH3NH3PbI3-xClx perovskite solar cells are used as examples. Gold nanoparticles (Au-NPs) are added into a conjugated pol…
Er3+ doped tellurite fibers have been fabricated using a convenient suction technique. Different scanning calorimetry (DSC), Electro-probe micro-analyzer (EPMA), Raman, steady and dynamic luminescence spectra were performed to investigate their thermal, structure, and luminescent properties. Broadband 2.7 μm amplified…
Bulk heterojunctions continue to be the dominant architecture for solution processed organic solar cells. In general, photoactive films on the order of 100 nm thickness have delivered the highest power conversion efficiencies. However, it is becoming increasingly apparent that thicker junctions are needed for high yie…
The gas-phase enthalpies of formation (Δ f H 298 ° ) of 101 aromatic nitro compounds were calculated using the Gaussian-4 (G4) theory applied to the atomization and isodesmic reaction energies. The Δ f H 298 ° (g) values calculated from the atomization reactions were underestimated by an average of 13 kJ·mol –1 and th…
Graphene oxide catalyzes oxidation by NaClO of primary benzyl and aliphatic amines to a product distribution comprising nitriles and imines. Nitriles are the sole product for long chain aliphatic amines. Spectroscopic characterization suggests that percarboxylic and perlactone groups could be the active sites of the p…
A dual-selective sensor platform for detection of iron in ferrous (Fe 2+ ) and ferric (Fe 3+ ) oxidation states was developed. Upon dispersing reduced graphene oxide (rGO) sheets into poly(3,4-ethylenedioxythiophene) polystyrenesulfonate (PEDOT:PSS) polymer, we deposited a hybrid film of rGO-PEDOT:PSS onto a glassy ca…
The phenomenon of half-spectral unidirectional invisibility is introduced for one-dimensional periodic optical structures with tailored real and imaginary refractive index distributions in a non PT-symmetric configuration. The effect refers to the property in which the optical medium appears to be invisible, both in r…
Conventional chemotherapeutic drugs such as doxorubicin (DOX) are associated with severe adverse effects such as cardiac, hepatic, and gastrointestinal (GI) toxicities. Excessive production of reactive oxygen species (ROS) was reported to be one of the main mechanisms underlying these severe adverse effects. Recently,…