Materials Literature
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We synthesized a new porous coordination polymer {La1.75(OH)1.25[Ru(dcbpy)3]· 16H2O} (La7-[4Ru]4; H2dcbpy = 4,4'-dicarboxy-2,2'-bipyridine) composed of a luminescent ruthenium(II) metalloligand [Ru(4,4'-dcbpy)3](4-) and La(3+) cations. X-ray analysis for La7-[4Ru]4 revealed that the La(3+) cations and [4Ru] metallolig…
Columns are essential load carrying structural components and may experience accidental loads such as terrorist bombing attacks during their service life. Damages to columns may trigger structural collapse and it is therefore very important to protect critical load-carrying columns. In recent studies, a novel ultra-hi…
Actual multiphase steels guarantee tensile strengths in different grades between 500 and 1000 MPa. Specifications and standards permit a wide field of chemical compositions. On one hand, carbon amounts higher than 0.12% are not seldom for grades exceeding 600 MPa tensile strength. However, frequently encountered diffi…
We report on solid-electrolyte-gated FETs with ferromagnetic contacts that result in a decrease in contact resistance and assess their potential for spintronics.
Abstract We have reported that the transistors having the c‐axis‐aligned crystalline (CAAC) In‐Ga‐Zn oxide (IGZO) show good performance. Recently, In‐Sn‐Zn Oxide (ITZO) has attracted much attention because of its high electron mobility, as well as IGZO. However, it has been reported that ITZO field effect transistors…
Non-destructive evaluation (NDE) techniques have been shown to be effective for evaluating mechanical properties of wood-based materials. In this study, transverse vibration of a beam under the two ends free boundary condition (FBV) was employed to measure the modulus of elasticity (MOE) in different strength directio…
Abstract We present an approach that makes use of DNA base pairing to produce hydrogen‐bonded macrocycles whose supramolecular structure can be transferred from solution to a solid substrate. A hierarchical assembly process ultimately leads to two‐dimensional nanostructured porous networks that are able to host size‐c…
The efficiency of organic photodetectors and optoelectronic devices is strongly limited by exciton diffusion, in particular for acceptor materials. Although mechanisms for exciton diffusion are well established, their correlation to molecular organization in real systems has received far less attention. In this report…
The synthesis of 5‐hydroxymethylfurfural (HMF) has been investigated from a number of carbohydrates (fructose, glucose, cellulose, and starch) and a natural biopolymer (lignocellulose) using an N,N‐dimethylacetamide‐LiCl solvent system. In each case, the dynamics of the desired product formation were evaluated and the…
The persistence of bacterial biofilms in chronic wounds delays wound healing. Although Ga(3+) can inhibit or kill biofilms, precipitation as Ga(OH)3 has prevented its use as a topical wound treatment. The design of a microfilm construct comprising a polyelectrolyte film that releases noncytotoxic concentrations of Ga(…
Recently, several groups have reported observations of collective modes of the charge order present in underdoped cuprates. Motivated by these experiments, we study theoretically the oscillations of the order parameters, both in the case of pure charge order and for charge order coexisting with superconductivity. Usin…
Refractive indices of [111] Gd3Ga5O12 single crystals under shock compression are investigated with planar impact and high-speed laser velocimetry, in the pressure range of 100–290 GPa. The refractive index, n, at 1550 nm is obtained as a function of shock pressure or density (ρ). n increases as pressure increases fro…
The determination of the power conversion efficiency of solar cells based on organo-metal-halides is subject to an ongoing debate. As solar cell devices may exhibit very slow transient response, current-voltage scans in different directions may not be congruent, which is an effect often referred to as hysteresis. We h…
We present a non-mechanical microiris based on two complementary electrochromic (EC) materials, namely viologens and phenozines, with an almost neutral spectral behavior. Measurements concerning the spectral light transmission, modulation transfer function, and response time validate that the optical performance of th…
Here we present the results of investigations aimed at the development and testing of robust, chemically inert single-crystal diamond probes for atomic force microscopy (AFM). The probes were prepared by assembling common silicon probes with micrometer-sized pyramid-shaped single-crystal diamonds (SCD). The SCD were o…
Dihydroxyacetone (DHA) kinase from Citrobacter freundii provides an easy entry for the preparation of DHA phosphate; a very important C3 building block in nature. To modify the phosphoryl donor specificity of this enzyme from ATP to inorganic polyphosphate (poly-P); a directed evolution program has been initiated. In…
The initial austenite grain size of boron microalloyed steel with three different amounts of boron (20, 40, and 60 ppm) was investigated under different heating temperatures (1150, 1100, and 1050 °C), and hot compression tests of samples in a wide range of temperature (900–1100 °C) and strain rate (0.1–10 s−1) were co…
Organic photovoltaic materials have recently seen intense interest from the research community. Improvements in device performance are occurring at an impressive rate; however, visualization of the active layer phase separation still remains a challenge. This paper outlines the application of two electron energy-loss…
Titanate nanotubes are promising materials for Li-ion battery anodes because of their special morphology and high specific surface areas. These titanates provide high rate capability and low volume expansion upon lithiation. More importantly, their tubular structure helps the transport of ions through the crystal. In…
We conducted a molecular dynamics simulation to investigate current inversions in a nanosized water pump based on a single-walled carbon nanotube powered by mechanical vibration. It was found that the water current depended sensitively on the frequency of mechanical vibration. Especially in the resonance region, the n…