Materials Literature
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A versatile and room temperature synthesis of thin films of polymer/graphene is reported. Drastically differing from other methods, not only the polymer but also the graphene are completely built from their simplest monomers (thiophene and benzene) in a one-pot polymerization reaction at a liquid-liquid interface. The…
Detailed kinetic studies on the hydrolysis of glycylglycine (Gly-Gly) in the presence of the dimeric tetrazirconium(IV)-substituted Wells-Dawson-type polyoxometalate Na14[Zr4(P2W16O59)2(μ3-O)2(OH)2(H2O)4] · 57H2O (1) were performed by a combination of (1)H, (13)C, and (31)P NMR spectroscopies. The catalyst was shown t…
Benzo[5]helicene-based conjugated polymers were synthesized and demonstrated as fluorescent chemosensors for the highly selective and sensitive detection of nitroaromatic explosives.
ABSTRACT The aim of this work is to use lignocellulosic wastes as low price additives in biodegradable polymers. The rice straw (RS) was treated by means of different methods, and then it was introduced to the poly(lactic acid)/starch composites. The effects of different treatments on RS properties were investigated u…
Diatoms are widespread unicellular photosynthetic algae that produce unique highly ordered siliceous cell wall, called frustule. Micro- to nanoporous structure with high surface area that can be easily modified, high mechanical resistance, unique optical features (light focusing and luminescence) and biocompatibility…
Many small-molecule anti-cancer drugs have short blood half-lives and toxicity issues due to non-specificity. Nanotechnology has shown great promise in addressing these issues. Here, we report the development of an anti-cancer drug gemcitabine-conjugated iron oxide nanoparticle for glioblastoma therapy. A glioblastoma…
Fracture mechanics experiments and occluded crack chemistry modeling validate the mechanism for intergranular stress corrosion cracking (IGSCC) of sensitized Al-Mg alloys: dissolution of discontinuous grain boundary β (Al3Mg2) precipitates activates Al-Mg (α) solid solution dissolution to acidify the crack solution fo…
We investigated the effect of oxygen content on the microstructural and magnetic properties of a DyH2 dip-coated Nd–Fe–B sintered magnet. When the magnet had a low oxygen content (1500 ppm), the volume and size of the rare-earth-rich oxide (Nd–Dy–O) phase was reduced, and a uniform and continuous thin Nd-rich grain bo…
Orderly molecular self‐assembly for tunable micro/nanostructures is an effective way to prepare novel functional materials with desired properties. Squarylium cyanine (SCy) dyes have received great attention in the fields of laser, imaging, and optoelectronic device. However, the detailed self‐assembly behavior of SCy…
With the rise in human population across the globe especially in developing countries, the incidence of microbial infections are increasing with greater pace. On the other hand, available medication and therapies are found to be insufficient for the complete cure of such microbial infections due to the development of…
A nitro group functionalized porous aromatic framework (NO 2 -PAF-1) was synthesized via a copper-mediated Ullmann reaction. Its CO 2 uptake was higher that of PAF-1 due to the strong interaction of the nitro group with CO 2 .
3-Dimensional (3D) composites based on a unique combination of MnO2-nanostructures, graphene oxide nanosheets and porous Diatomaceous Earth (DE) microparticles (GO-DE@MnO2) were synthesized and explored for application in high-performance supercapacitors. To explore the influence of the structural properties of MnO2 n…
We study a twisted Hubbard tube modeling the [CrAs]_{∞} structure of quasi-one-dimensional superconductors A_{2}Cr_{3}As_{3} (A=K, Rb, Cs). The molecular-orbital bands emerging from the quasi-degenerate atomic orbitals are exactly solved. An effective Hamiltonian is derived for a region where three partially filled ba…
Insulation performance of the dielectrics under extreme conditions always attracts widespread attention in electrical and electronic field. How to improve the high-temperature dielectric properties of insulation materials is one of the key issues in insulation system design of electrical devices. This paper studies th…
The defects on graphene make Au atoms active while being monodisperse and superior for ethylene epoxidation.
Elastic anomalies are signatures of phase transitions in condensed matters and have traditionally been studied using various techniques spanning from neutron scattering to static mechanical testing. Here, using band-excitation elastic/piezoresponse spectroscopy, we probed sub-MHz elastic dynamics of a tip bias-induced…
Three-component hybrid nanoparticle heterotrimers, which are important multifunctional constructs that underpin diverse applications, are commonly synthesized by growing a third domain off of a two-component heterodimer seed. However, because heterodimer seeds expose two distinct surfaces that often can both support n…
BACKGROUND: The limitation of current breast cancer treatments was elucidated by the presence of cancer stem cells (CSCs) that play essential role in cancer initiation, progression, resistance, recurrence and metastasis. Materials & methods: Biocompatible multimodality single-walled carbon nanotube (SWCNT) nanoprobes…
The glass transition of colloidal dispersions interacting with both a short-ranged attraction and long-ranged repulsion is studied using highly purified lysozyme solutions. Newtonian liquid behavior is observed at all conditions while measurements of the dynamics in the short-time limit show features typical of glassy…
Quantum dot (QD) nanocrystals dispersed in photoresist (PR) film was developed and applied to white organic light-emitting diode (OLED) to improve optical power of red color through down-converting of blue and green light. To integrate to white OLED display panel, the QD dispersed photoresist film was prepared in a th…