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Kinetic modeling of the alkaline decomposition of potassium arsenojarosite

Mizraím U. Flores、Francisco Patiño、Iván A. Reyes 等 6 位作者2012-06-01Journal of the Brazilian Chemical Society

A sample of potassium arsenojarosite was synthesized and thoroughly characterized. The obtained sample is a solid solution of potassium arsenojarosite, whose approximate formula is [K0.75(H3O)0.25 ]Fe1.84[(SO4)1.82(AsO 4)0.18][(OH)2.34(H 2O)3.66]. The decomposition process in alkaline medium was studied in the inducti…

Metal Extraction and BioleachingMinerals Flotation and Separation TechniquesThermal and Kinetic Analysis

In-situ Observation of Surface Graphitization of Gallium Droplet and Concentration of Carbon in Liquid Gallium

Ryuichi Ueki、Takuya Nishijima、Takeshi Hikata 等 7 位作者2012-06-01Japanese Journal of Applied Physics

Although carbon has been recognized to be insoluble in gallium, we found that the outermost surface of gallium has unexpectedly high carbon solubility, particularly the limited region of about a few nanometers in depth. Our in-situ transmission electron microscope observations revealed that a graphene layer was precip…

Carbon Nanotubes in CompositesGraphene research and applicationsnanoparticles nucleation surface interactions

Quantitative anomalous small-angle X-ray scattering — The determination of chemical concentrations in nano-scaled phases

G. Goerigk、Klaus Huber、N. Mattern 等 4 位作者2012-06-01The European Physical Journal Special Topics

In the last years Anomalous Small-Angle X-ray Scattering became a precise quantitative method resolving scattering contributions two or three orders of magnitude smaller compared to the overall small-angle scattering, which are related to the so-called pure-resonant scattering contribution. Additionally to the structu…

X-ray Spectroscopy and Fluorescence AnalysisIron oxide chemistry and applicationsX-ray Diffraction in Crystallography

High Density Biocomposite from Natural Fibers and Tannin Resin

A. Nicollin、Raphaël Kueny、L. Toniazzo 等 4 位作者2012-06-01Journal of Adhesion Science and Technology

Successful experiments on high, medium and low density natural fiber reinforced composites made from tannin/hexamine resin and flax–hemp fibers have recently been carried out. This study focused on the high density composites. In this work composite panels have been made of three different tannin extracts: mimosa, sul…

Natural Fiber Reinforced Composites

Application of Modified Calcium Sulfate Whisker in Methyl Vinyl Silicone Rubber Composites

Jincheng Wang、Tang Lijuan、Wu Ding 等 5 位作者2012-06-01Polymers and Polymer Composites

Novel methyl vinyl silicone rubber (MVQ)/calcium sulfate whisker (CSW) composites had been prepared. Two types of modification agents, hydrogen silicone oil and silane coupling agent, were used in the preparation of modified calcium sulfate whiskers (MCSW). The morphology and properties of MCSW were analyzed by Fourie…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Isothermal Crystallization Behavior of Biodegradable P(BS-b-PEGS) Multiblock Copolymers

Xirui Lu、Jian‐Bing Zeng、Cai-Li Huang 等 4 位作者2012-06-01Industrial & Engineering Chemistry Research

Biodegradable multiblock copolymers poly(butylene succinate-b-poly(ethylene glycol) succinate) (P(BS-b-PEGS)) were prepared by direct polycondensation. The thermal and crystallization behavior of P(BS-b-PEGS) with weight fraction of PEGS component from 6 to 26 wt % were comparatively investigated with those of neat po…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Novel Biodegradable Functional Amino Acid-Based Poly(ester Amide) Biomaterials: Design, Synthesis, Property and Biomedical Applications

C. C. Chu2012-06-01Journal of Fiber Bioengineering and Informatics

A new family of biodegradable and functional amino acid-based poly(ester amide)s (AA-PEAs) have been designed and synthesized as a new generation of biodegradable biomaterials for biomedical applications. This paper provides an overview of this new generation of biodegradable biomaterials, their design strategy, synth…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesBiopolymer Synthesis and Applications

Preparation of Alumina and Alumina-Ceria Microspheres using an Internal Gelation Process and their Characterization

B. V. Gangar、K. Nagarajan、R. Venkata Krishnan 等 4 位作者2012-06-01Transactions of the Indian Ceramic Society

Preparation of alumina and aluminium-cerium oxide microspheres was carried out by internal gelation process. The gelation behaviour of an acid deficient aluminium nitrate solution (NO3 −/AI3+ = 2.5) with hexamethylenetetramine and urea was investigated to develop a gelation field diagram. However, cerous nitrate solut…

Advanced ceramic materials synthesisCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

Study on Cell Adhesion Detection onto Biodegradable Electrospun PCL Scaffolds

Budimir Mijović、Mirna Tominac Trcin、Ante Agic 等 7 位作者2012-06-01Journal of Fiber Bioengineering and Informatics

The polycaprolactone (PCL) known for its slow biodegradability shows potential applications in the fleld of skin scafiold production. In the current study PCL mats with micro scaled structure were produced via electrospinning and treated with NaOH solution for enhanced cell adhesion. The scafiolds were evaluated as an…

Electrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic PollutionSilk-based biomaterials and applications

A reinvestigation of mayenite from the type locality, the Ettringer Bellerberg volcano near Mayen, Eifel district, Germany

Evgeny V. Galuskin、Joachim Kusz、Thomas Armbruster 等 7 位作者2012-06-01Mineralogical Magazine

Abstract New electron-microprobe analyses of mayenite from the Ettringer Bellerberg volcano near Mayen in the Eifel district, Germany have high Cl contents and Raman spectroscopy indicates the presence of OH groups. Neither of these components is included in the generally accepted chemical formula, Ca 12 Al 14 O 33 .…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationInorganic Chemistry and Materials

Absolute x-ray energy calibration over a wide energy range using a diffraction-based iterative method

Xinguo Hong、Zhiqiang Chen、T. S. Duffy2012-06-01Review of Scientific Instruments

In this paper, we report a method of precise and fast absolute x-ray energy calibration over a wide energy range using an iterative x-ray diffraction based method. Although accurate x-ray energy calibration is indispensable for x-ray energy-sensitive scattering and diffraction experiments, there is still a lack of eff…

High-pressure geophysics and materialsNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Manganese borides synthesized at high pressure and high temperature

Xiangxu Meng、Kuo Bao、Pinwen Zhu 等 8 位作者2012-06-01Journal of Applied Physics

We synthesized various kinds of manganese borides by liquid-solid reaction from manganese and amorphous boron powders at high pressure and high temperature. The mixed powders with various atomic ratio of boron to manganese, B/Mn = 0.6, 1.2, 2, 3, 4, 8, were treated at temperature 1100–1350 °C and pressure 4.8-5.5 GPa,…

Boron and Carbon Nanomaterials ResearchMXene and MAX Phase MaterialsAdvanced materials and composites

Accelerated hydrothermal aging of epoxy resin based syntactic foams with polymeric microspheres

Christoph Roggendorf、Armin Schnettler2012-06-01IEEE Transactions on Dielectrics and Electrical Insulation

Insulation systems have to interact with their environment. In outdoor applications they have to withstand atmospheric stress such as temperature and humidity. This leads to aging processes inside the insulation material and results in a change of material properties and consequently can lead to a failure of the high…

Polymer Nanocomposites and PropertiesHigh voltage insulation and dielectric phenomenaEpoxy Resin Curing Processes

Size effects on the impact response of copper nanobeams

Zhen Chen、Shan Jiang、Yong Gan 等 6 位作者2012-06-01Journal of Applied Physics

Molecular dynamics simulations are performed to study size effects on the impact response of copper nanobeam targets subjected to impacts by copper nanobeam flyers with different impact velocities. It is found that the Hugoniot response is size-dependent, while the aspect ratio – that is, the ratio of flyer and target…

Microstructure and mechanical propertiesHigh-Velocity Impact and Material BehaviorIon-surface interactions and analysis

Emission and propagation mechanisms of PD pulses for UHF and traditional electrical measurements

Stefan Hoek、Maik Koch、A. Kraetge 等 5 位作者2012-06-01OpenAlex

Partial Discharge (PD) measurements are considered as a very powerful technique for testing and monitoring the condition of high-voltage (HV) insulations. PD activity is generally accepted as an early breakdown indicator, which is also reflected in numerous standards. In the present contribution, the authors describe…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Phase equilibria and interfacial properties of two-dimensional Yukawa fluids

Gloria Arlette Méndez-Maldonado、Minerva González-Melchor、Alejandre2012-06-01Condensed Matter Physics

Molecular dynamics simulations of two-dimensional soft Yukawa fluids are performed to analyze the effect that the range of interaction has on coexisting densities and line tension. The attractive one-component fluid and equimolar mixtures containing positive and negative particles are studied at different temperatures…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Kazanskyite, Ba & TiNbNa3Ti(Si2O7)2O2(OH)2(H2O)4, a Group-III Ti-disilicate mineral from the Khibiny alkaline massif, Kola Peninsula, Russia: description and crystal structure

Fernando Cámara、Elena Sokolova、F. C. Hawthorne2012-06-01Mineralogical Magazine

Abstract Kazanskyite, Ba & TiNbNa 3 Ti(Si 2 O 7 )2O 2 (OH) 2 (H 2 O) 4 , is a Group-III TS-block mineral from the Kirovskii mine, Mount Kukisvumchorr, Khibiny alkaline massif, Kola Peninsula, Russia. The mineral occurs as flexible and commonly bent flakes 2–15 μm thick and up to 330 μm across. It is colourless to…

Crystal Structures and PropertiesRadioactive element chemistry and processingChemical Synthesis and Characterization

Electric field effect on superconductivity in La2−xSrxCuO4

Guy Dubuis、A. T. Bollinger、Davor Pavuna 等 4 位作者2012-06-01Journal of Applied Physics

We demonstrate a method to tune the carrier concentration of a high temperature superconductor over a wide range, using an applied electric field. Thin film devices were made in an electrical double layer transistor configuration utilizing an ionic liquid. In this way, the surface carrier density in La2−xSrxCuO4 films…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Extraction of dielectric and magnetic properties of carbonyl iron powder composites at high frequencies

Irena Zivkovic、Axel Murk2012-06-01Journal of Applied Physics

In this paper, we examine carbonyl iron composites in silicone rubber and epoxy matrices. Transmission measurements were performed at W (70 to 110 GHz) and Ka (26 to 40 GHz) bands and effective permittivity and permeability of composites with 10% volume fraction of carbonyl iron powder (CIP) were extracted at these fr…

Railway Engineering and DynamicsElectromagnetic wave absorption materials

Metamaterial analog of quantum interference: From electromagnetically induced transparency to absorption

Yong Sun、Wei Tan、Lanju Liang 等 7 位作者2012-06-01Europhysics Letters (EPL)

With a metamaterial structure, the phenomenology observed in quantum electromagnetically induced transparency is reproduced. Through the parametric comparison between quantum and classical systems, the physical mechanism of this novel phenomenon has been explained directly in our analysis. In addition, we use another…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchQuantum optics and atomic interactions