Materials Literature
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Synthesis of class II hybrid silica materials requires the formation of covalent linkage between organic moieties and inorganic frameworks. The requirement that organosilylating agents be present to provide the organic part limits the synthesis of functional inorganic oxides, however, due to the water sensitivity and…
A method for the comparison of kinetic parameters of reaction/process for thermogravimetric measurements at isothermal and dynamic conditions and processes on a larger scale were considered. It is based on the concept of finite time and corresponding total conversion of the solid phase. The method allows for the deter…
In the present study, biogenic silver nanoparticles rapidly synthesized using leaf extract of Rosa indicawichuriana hybrid Francois guillot were investigated for their potential use as a antibacterial and antifungal additive to commercially available dish wash and hand wash. UV-vis spectrophotometer, Powder X-ray diff…
Vanadium-based catalysts are used in many technological processes, among which the removal of nitrogen oxides (NOx) from waste gases is one of the most important. The chemical reaction responsible for this selective catalytic reaction (SCR) is based on the reduction of NOx molecules to N2, and a possible reductant in…
This article deals with the nonisothermal degradation kinetics of insulating and conducting epoxy/Zn composites. A comparison of thermal degradation data obtained from epoxy/Zn composites revealed that the addition of zinc content in epoxy significantly increases its degradation rate. However, the zinc content activat…
Upconversion luminescence nanoparticles (UCNPs) have shown promising applications in biomedical fields as luminescent probes because of their excellent advantages such as single excitation with multicolor emission, low autofluorescence, and deep penetration. But the biological applications of such nanomaterials are st…
This paper describes the activation of a biologically inert Co(III) Schiff base [Co(III)-SB] complex to its protein inhibitor form by photoinduced electron transfer (PET) from a colloidal PbS quantum dot (QD, radii of 1.5-1.7 nm) to the cobalt center, with a charge separation time constant of 125 ns. Reduction of the…
In this study, an antimicrobial film containing cinnamaldehyde was developed to pack bread and pastry made without preservatives. These products were wrapped with the antimicrobial films and packaged in low-density polyethylene bags. The antimicrobial activity of the films, the migration of the cinnamaldehyde in the f…
The focuses of this study were to investigate the effect of sodium montmorillonite clay (MMT-Na) content on the physical properties and extent of enzymatic hydrolysis Polyvinyl Alcohol (PVA): Starch (S): Carboxymethyl Cellulose (CMC) nanocomposites using enzyme <alpha>-amylase. The results of this work have revealed t…
Silver ions are widely used as antibacterial agents, but the basic molecular mechanism of this effect is still poorly understood. X-ray absorption near-edge structure (XANES) spectroscopy at the Ag LIII, S K, and P K edges reveals the chemical forms of silver in Staphylococcus aureus and Escherichia coli (Ag(+) treate…
This work examined the influence of different chemical blowing agents (CBA), one endothermic and one exothermic, at the same concentration (2% by mass), on poly(acid lactic), PLA foams. The CBA was incorporated into the PLA in a single-screw extruder, and the foams were expanded by heating in an electric oven under fr…
The recent rise of nanotechnology and nanomaterial research is marked by the huge amount of publications indexed in electronic databases, which can be evaluated using bibliometric indicators in order to help researchers find hidden trends, gain novel insights and support new scientific developments. Although in-depth…
Wood-based panels have been widely used around the world in various segments of timber industry. Thus, alternative raw-materials have been systematically researched in order to reduce of wood demand in particleboard production. The aim of this work was to produce and evaluate particleboards of Eucalyptus grandis and o…
Recently, two-dimensional nanostructures consisting of alternating graphene and boron nitride (BN) domains have been synthesized. These systems possess interesting electronic and mechanical properties, with potential applications in electronics and optical devices. Here, we perform a first-principles investigation of…
A continuum model for the dynamics of a single step with the strongly anisotropic line energy is formulated and analyzed. The step grows by attachment of adatoms from the lower terrace, onto which atoms adsorb from a vapor phase or from a molecular beam, and the desorption is non-negligible (the "one-sided" model). Vi…
Mixed-valent perovskite oxides based on BaBiO3 (BBO) are, like cuperates, well-known high-Tc superconductors. Recent ab inito calculations have assigned the high-Tc superconductivity to a correlation-enhanced electron--phonon coupling mechanism, stimulating the prediction and synthesis of new superconductor candidates…
We have studied the energetics, electronic structure, optical excitation, and electron relaxation of dinitromethane molecules (CH 2 N 2 O 4 ) adsorbed on semiconducting carbon nanotubes (CNTs) of chiral index ( n,0) ( n = 7, 10, 13, 16, 19). Using first-principles density functional theory (DFT) with generalized gradi…
We have applied dispersion corrected density functional theory to gauge the reactivity of the most common defects found in graphene. Specifically, we investigated single vacancies, 585 double vacancies, 555–777 reconstructed double vacancies, Stone–Wales defects, and hydrogenated zigzag and armchair edges. We found th…
ABSTRACT The discovery and development of high trans styrene–butadiene rubber (SBR) is presented. High trans SBR is prepared using a novel polymerization initiator of a specific combination of a barium salt and organometallic compound in a hydrocarbon solvent. The trans -1,4 content of the polybutadiene repeat units i…
To date, majority shape adaptations of shape memory polymer (SMP) are thermo responsive. A desire for isothermal, remotely controlled shape adaptations of SMP has motivated examinations of other stimulus. We successfully construct novel TiO<sub>2</sub>-polystyrene shape memory nanocomposites and investigate influence…