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Catalytic Acyl Transfer by a Cyclic Porphyrin Trimer: Efficient Turnover without Product Inhibition

Lindsey G. Mackay、R. Stephen Wylie、Jeremy K. M. Sanders1994-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCatalytic Acyl Transfer by a Cyclic Porphyrin Trimer: Efficient Turnover without Product InhibitionLindsey G. Mackay, R. Stephen Wylie, and Jeremy K. M. SandersCite this: J. Am. Chem. Soc. 1994, 116, 7, 3141–3142Publication Date (Print):April 1, 1994Publication History Publi…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistrySurface Chemistry and Catalysis

On the Anelastic Flow with Damage

Khémaïs Saanouni、Ch. Förster、Fafa Ben Hatira1994-04-01International Journal of Damage Mechanics

Within the thermodynamics of irreversible processes and the concept of in ternal state variables, a general phenomenological theory of coupled damage-elasto- (visco)plasticity at small strains is given. The state variables (external and internal) are considered to evolve phenomenologically according to competing proce…

Metal Forming Simulation TechniquesHigh-Velocity Impact and Material BehaviorElasticity and Material Modeling

An introduction to biomimetics: A structural viewpoint

Mehmet Sarıkaya1994-04-01Microscopy Research and Technique

Biomimetics is a newly emerging interdisciplinary field in materials science and engineering and biology in which lessons learned from biology form the basis for novel technological materials. It involves investigation of both structures and physical functions of biological composites of engineering interest with the…

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionDiatoms and Algae Research

Adenosylmethionine-dependent synthesis of the glycyl radical in pyruvate formate-lyase by abstraction of the glycine C-2 pro-S hydrogen atom. Studies of [2H]glycine-substituted enzyme and peptides homologous to the glycine 734 site.

Markus Frey、M. Rothe、Arne Wagner 等 4 位作者1994-04-01Journal of Biological Chemistry

The active form of pyruvate formate-lyase (PFL) from Escherichia coli contains a glycyl radical in position 734 of the polypeptide chain which is produced post-translationally by pyruvate formate-lyase-activating enzyme (PFL activase) using S-adenosylmethionine (AdoMet) and dihydroflavodoxin as co-substrates (Wagner,…

Enzyme Structure and FunctionBiotin and Related StudiesAmino Acid Enzymes and Metabolism

Phase Behavior and Association Properties of Poly(oxypropylene)-Poly(oxyethylene)-Poly(oxypropylene) Triblock Copolymer in Aqueous Solution

Zukang Zhou、Benjamin Chu1994-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhase Behavior and Association Properties of Poly(oxypropylene)-Poly(oxyethylene)-Poly(oxypropylene) Triblock Copolymer in Aqueous SolutionZukang Zhou and Benjamin ChuCite this: Macromolecules 1994, 27, 8, 2025–2033Publication Date (Print):April 1, 1994Publication History Pu…

Advanced Polymer Synthesis and CharacterizationConducting polymers and applicationsPolymer crystallization and properties

Pressure and temperature dependent viscosity of two glass forming liquids: Glycerol and dibutyl phthalate

Richard L. Cook、H. E. King、Chris A. Herbst 等 4 位作者1994-04-01The Journal of Chemical Physics

The pressure and temperature dependent viscosities of two glass forming liquids, glycerol and dibutyl phthalate (DBP), have been studied in the range P=0–3 GPa, T=0–125 °C, and η=101–1010 cP. These studies were made using a combination of a rolling-ball and a centrifugal-force diamond anvil cell viscometer. The majori…

Material Dynamics and PropertiesLiquid Crystal Research AdvancementsRheology and Fluid Dynamics Studies

Algorithm for the rigorous coupled-wave analysis of grating diffraction

Nicolas Château、Jean‐Paul Hugonin1994-04-01Journal of the Optical Society of America A

Diffraction of light by periodic gratings is analyzed with a characteristic-matrix formalism based on a rigorous coupled-wave approach. This formalism is particularly convenient for modeling the diffraction by nonuniform periodic structures. In order to overcome numerical difficulties that are due to inhomogeneous eig…

Photonic Crystals and ApplicationsOptical Coatings and GratingsPhotonic and Optical Devices

Surface energy and microstructure in coherent phase transitions

Robert V. Kohn、Stefan Müller1994-04-01Communications on Pure and Applied Mathematics

Abstract We study a variational problem involving a nonconvex function of Δ u , regularized by a higher order term. The motivation comes from the theory of martensitic phase transformation—specifically, a model for the fine scale structure of twinning near an austenite‐twinned‐martensite interface. It is widely believ…

Adhesion, Friction, and Surface InteractionsShape Memory Alloy TransformationsContact Mechanics and Variational Inequalities

Resonance light-scattering studies of porphyrin diacid aggregates

Robert F. Pasternack、Kurt F. Schaefer、Peter Hambright1994-04-01Inorganic Chemistry

Resonance light-scattering measurements have been employed to investigate the solute species present in acidic aqueous media for some 14 sulfonated porphyrins. The results confirm that the anomalous absorption band in the Soret region reported for several of these porphyrins arises from the formation of extended aggre…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPhotochemistry and Electron Transfer Studies

Thin film microcalorimeter for heat capacity measurements from 1.5 to 800 K

D. W. Denlinger、E.N. Abarra、K. M. Allen 等 7 位作者1994-04-01Review of Scientific Instruments

A new microcalorimeter for measuring heat capacity of thin films in the range 1.5–800 K is described. Semiconductor processing techniques are used to create a device with an amorphous silicon nitride membrane as the sample substrate, a Pt thin film resistor for temperatures greater than 40 K, and either a thin film am…

Thermal properties of materialsAdvanced Thermoelectric Materials and Devicesthermodynamics and calorimetric analyses

Molecular interpretation of the absorption-induced optical reorientation of nematic liquid crystals

I. Jánossy1994-04-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

A molecular mechanism is proposed to explain the anomalous optical reorientation observed in nematic guest-host systems. According to the model, light-induced reorientation in these systems is due to the interaction between the excited dye molecules and the nematic host. The model justifies a phenomenological descript…

Nonlinear Optical Materials StudiesMolecular spectroscopy and chiralityLiquid Crystal Research Advancements

Analysis of the induction of general stress proteins of Bacillus subtilis

Uwe Völker、Susanne Engelmann、Björn Maul 等 8 位作者1994-04-01Microbiology

In Bacillus subtilis stress proteins are induced in response to different environmental conditions such as heat shock, salt stress, glucose and oxygen limitation or oxidative stress. These stress proteins have been previously grouped into general stress proteins (Gsps) and heat-specific stress proteins (Hsps). In this…

Heat shock proteins researchEnzyme Structure and FunctionProtein Structure and Dynamics