Materials Literature
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Pipe-dream realized: The as-made nanocomposite derived from a block-copolymer-directed sol–gel synthesis consists of silica networks embedded in an organic matrix. Calcination of the structure at high temperatures gives a final skeletal silica network consistent with the morphology called plumber's nightmare (point gr…
Abstract Summary: A series of polyimide/ZnO nanohybrid films with different ZnO content were prepared from a rigid pyromellitic dianhydride‐4,4′‐diaminodiphenyl ether (PMDA‐ODA) polyimide (PI) and a flexible 3,3′,4,4′‐benzophenonetetracarboxylic acid dianhydride‐4,4′‐diaminodiphenyl ether (BTDA‐ODA) PI with ZnO nanopa…
Abstract Summary: Poly(ethylene terephthalate) (PET) track‐etched membranes with a pore diameter of ca. 700 nm, optionally surface‐functionalized to create a “carboxyl” or “amino” surface, were used for heterogeneous graft copolymerizations. Grafted poly(acrylic acid) acted as a pH responsive, “smart” polymer. To eval…
Exact exchange (EXX) Kohn-Sham calculations within an all-electron full-potential method are performed on a range of semiconductors and insulators (Ge, GaAs, CdS, Si, ZnS, C, BN, Ne, Ar, Kr and Xe). We find that the band-gaps are not as close to experiment as those obtained from previous pseudopotential EXX calculatio…
We have investigated the electronic structure of nano-sized iron oxide by scanning tunnelling microscopy (STM) and spectroscopy (STS) as well as by photoelectron spectroscopy. Nano particles were produced by thermal treatment of Ferritin molecules containing a self-assembled core of iron oxide. Depending on the therma…
Abstract Carbon nanotubes (CNT) belong to the most promising new materials which can in the near future revolutionize the conventional electronics. When sandwiched between ferromagnetic electrodes, the CNT behaves like a spacer in conventional spin‐valves, leading quite often to a considerable giant magneto‐resistance…
We present a procedure for determining independently the lattice structure and the vibrational properties of the same individual nano-object. For the example of an individual single-walled carbon nanotube we demonstrate the determination of the structural indices (n,m) of the nanotube by electron diffraction and of th…
In great shape: Star-shaped telechelic oligomers can be coupled with a junction unit to yield amorphous copolyester-urethane networks, which are not only biodegradable but can also be fixed in a new, temporary shape after they have been processed into a permanent shape. The permanent shape can be recovered by heating…
Void coalescence and interaction in dynamic fracture of ductile metals have been investigated using three-dimensional strain-controlled multi-million atom molecular dynamics simulations of copper. The correlated growth of two voids during the coalescence process leading to fracture is investigated, both in terms of it…
China pays great attentions to the development of titanium alloys and their basic theory because of their excellent properties. New titanium alloys and their new basic theories developed in China in recent five years were reviewed, for example, high temperature Ti alloys, burn resistant titanium alloys, high strength…
Interfaces between Mo substrate and free-standing diamond films prepared by DC arc plasma jet operated at gas recycling mode were investigated, including for the first time used and multi-time used substrate. The morphology, phase composition and bonding state of elements in the interface between substrates and diamon…
Phthalocyanine polymers substituted with polyethylene glycol (PEG), PPEGPc, were synthesized and characterized by photo electrochemistry. To examine the effects of the ethyleneoxy group on the photoconductivity of phthalocyanine polymers, different PEGs of Mw 164 ~ 750 were introduced by the esterification of the phth…
In general, thermal treatment at 500oC ~ 900oC ranges depending upon alloy composition of stainless steels can sensitize the steels and promote the intergranular cracking, and their intergranular corrosion resistance is decreased. These behaviors seem to be related to the change of microstructures. So, heat treatment…
Superplastic forming provides a good way for Ti alloys which are usually difficult to be deformed. Ti75 alloy with a nominal composition of Ti-3Al-2Mo-2Zr is a newly developed corrosion resistant alloy, with a middle strength and high toughness. In the present paper, superplastic behavior of the alloy was investigated…
We investigate the growth of highly luminescent silicon nanocrystals by rapid thermal chemical vapor deposition (RTCVD), employing SiH4 and N2O as source gases. For [N2O]/[SiH4] = 7 ∼ 8 and a growth temperature of 650°C, we obtain the optimized deposition condition for silicon rich oxide (SRO) layer having highly lumi…
The thermal annealing effect on the compressive residual stress has been presented in thin diamond-like carbon (DLC) film on Si substrate. Annealing experiments were carried out with Rapid Thermal Procedure system at from 200 to 600 °C, and the variation of residual stress with annealing temperature was investigated b…
Al-Cu-Fe-Cr quasicrystalline coating was deposited on a substrate of stainless steel by low-pressure plasma spraying (LPPS) method. The corrosion behavior of such coating was studied by polarization in 1mol/l H2SO4 and 0.1mol/l NaOH solutions at room temperature. The polarization curve shows that LPPS Al-Cu-Fe-Cr quas…
The anodic degradation of aqueous phenol and 2-chlorophenol, which are model organic pollutants, has been studied using a flow-through electrochemical cell (FTEC) with carbon fibers as an anode material. For a controlled current electrolysis of an aqueous solution of 2-chlorophenol and phenol, experimental variables,…
A ternary alloying element Niobium addition to the Ni-Ti shape memory alloy could optimize transformation temperatures, mechanical properties. In this paper, with the help of ambient tensile test and scan electron microscope observation, the influences of Nb-content on the mechanical properties of (Ni47Ti44)100-xNbx a…
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