Materials Literature
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Stoichiometric and amorphous thin layers of In2Te3 are obtained by vacuum thermal evaporation on glass substrates preheated at 300 °C. Annealing under nitrogen atmosphere modify the film structure. The best annealing conditions are determined to obtain polycrystalline films of In2Te3 with preferential orientation [111…
Electron diffraction and microscopy observations reveal that the sequence of the phase transformations of Cu2−xTe (x < 0.05) is a typical case of a normal-incommensurate–commensurate phase transition, with the incommensurate phase splitted into two phases; one of these, the γ-phase, is modulated by regularly spaced di…
Grain boundary precipitations of the B93 alloy (Al + 7% Zn + 1.9% Mg + 1% Cu + 0.3% Fe) are studied in the as-annealed state and after 2% pre-straining at room temperature, the alloy being characterized by equilibrium and non-equilibrium boundaries. A considerable enhancement of grain boundary precipitates associated…
A high-speed optically addressed spatial light modulator is described which uses the electroclinic effect in chiral smectic A liquid crystals with a p-i-n photodiode of hydrogenated amorphous silicon (a-Si:H). The near microsecond response time is a function of the liquid-crystal mixture and temperature. We present an…
The formation of a plastic zone, in the form of a linear array of inclined edge dislocations in front of a mode-I crack in plane strain, is studied. The direction of the force field on an edge dislocation due to the crack load allows for the determination of the plastic zone as a function of the inclination angle. The…
Silicon nitride films were synthesized in a Balzers BAP 800 coating plant by low voltage reactive ion plating. Transparent, stoichiometric films free of hydrogen, oxygen, argon, and heavy metals were obtained. The properties of the silicon nitride films were investigated in terms of optical constants, chemical composi…
We report the observation of electrically induced changes in transmissivity in Fabry-Perot devices consisting of spin-cast azo-dye/polymer films deposited between gold mirrors. In poled samples the observed modulation shows a linear dependence on the applied modulating voltage. The ratio of the transmissivity modulati…
The adsorption, thermoreactions, and photoreactions of NO coadsorbed with potassium on Si(111)7×7 at 90 K have been investigated using work-function measurements, high-resolution electron energy loss spectroscopy, and mass spectrometry. A minimum in the work function of Si(111)7×7 at 90 K vs the potassium exposure is…
Using the energy transfer parameters deduced from the study on nonexponential luminescence decay of the 4F3/2 level of Nd3+ in YAG at room temperature, it is shown that up to 1.5 at. % Nd, the relative quantum efficiency is reduced by an amount of 18.2C, C being the relative (to Y3+) Nd concentration. It is pointed ou…
Heat capacity measurements of four lanthanide sesquisulfides La2S3, Ce2S3, Nd2S3, and Gd2S3, prepared in the γ phase, have been obtained between 6 and 350 K by adiabatic calorimetry. The total heat capacity has been resolved into lattice, electronic, magnetic, and Schottky components. The Schottky contributions agree…
A new type of superlattice, a Fibonacci acoustic superlattice, is presented. Its ultrasonic spectrum, which is excited by the piezoelectric effect, has been studied theoretically and experimentally. The results are in good agreement with each other.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotoreduction fluorescence detection of quinones in high-performance liquid chromatographyJames R. Poulsen and John W. BirksCite this: Anal. Chem. 1989, 61, 20, 2267–2276Publication Date (Print):October 15, 1989Publication History Published online1 May 2002Published inissue…
We present an ab initio calculation of polarizability and second hyperpolarizability for the benzene molecule including electron–electron correlation. The finite field method is used. For each selected strength of the applied electric field the energy of the benzene molecule is calculated using the self-consistent fie…
The effect of hydrostatic pressure on the lowest direct gaps ${E}_{a}$ (${\ensuremath{\Gamma}}_{2}^{v}$\ensuremath{\rightarrow}${\ensuremath{\Gamma}}_{3}$,${2}^{\mathrm{c}}$) and ${E}_{b}$ (${\ensuremath{\Gamma}}_{2}^{v}$\ensuremath{\rightarrow}${\ensuremath{\Gamma}}_{3}$,${1}^{\mathrm{c}}$,${\ensuremath{\Gamma}}_{1}^…
Fourier transform infrared multiple specular reflectance (FTIR-MSR) spectroscopy has been applied to study the chemisorption of n-hexadecanoic or palmitic acid [CH3(CH2)14COOH] on aluminium as a function of surface coverage. The intensity of the symmetric carboxylate stretching vibration has been used to estimate the…
We present data on the electro-optics and the display performance of liquid-crystal devices based on the distorted helix ferroelectric (DHF) effect which demonstrate TV switching rates and low driving voltages. The DHF effect is based on S*c ferroelectric liquid crystals with very short pitch, which form in suitable c…
Results are presented on a Raman study of diamond films prepared by the filament-assisted chemical vapor deposition technique from a methane-hydrogen gas mixture. It is shown that Raman spectroscopy is a useful probe of both the phase of carbon present and of the quality of the diamond component in the films. The stud…
B2H4 has been produced by the reaction of F atoms with B2H6, in successive abstraction reactions. The B2H4 species was detected and analyzed by photoionization mass spectrometry. The adiabatic ionization potential of this species (9.70±0.02 eV) and the vertical value (∼10.4 eV) are obtained from the photoion yield cur…
The fracture process in ceramic materials upon impact loading is complex in nature. Most often, the brittle ceramic deforms inelastically due to microcracking under shock (compression) loading. At high-velocity impact, the shock generated microcracks rapidly open and extend under subsequent tension (due to the release…
We have demonstrated that single point diamond turning can be used to generate high optical quality finished surfaces on a new organic nonlinear crystal, L-arginine phosphate (LAP). The proper choice of cutting conditions can produce surfaces with <5-A rms local roughness. Local softening or melting near the cutting t…