Materials Literature
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Micellar ordering in semidilute solutions of polystyrene−polyisoprene diblock and triblock copolymers in the slightly selective solvent di- n -butyl phthalate has been studied using rheology and small-angle X-ray scattering (SAXS). Ordering as a function of temperature has been investigated for a range of polymer conc…
Three-dimensional cyanide-bridged bimetallic assemblies [Ni(L) 2 ] 3 [Fe II (CN) 6 ]X 2 ((L, X) = (ethylenediamine (en), PF 6 - ) ( 1 ), (trimethylenediamine (tn), PF 6 - ) ( 2 ), (tn, ClO 4 - ) ( 3 )) were synthesized and structurally characterized. Compounds 1 − 3 crystallize in the trigonal system of the space grou…
Poly(ether ketone ketone)s were prepared and used to improve the brittleness of the bismaleimide resin. The bismaleimide resin was composed of 4,4′-bismaleimidediphenyl methane (BMI) and o,o′-diallyl bisphenol A (DBA). Poly(ether ketone ketone)s include poly(phthaloyl diphenyl ether) (PPDE), poly(phthaloyl diphenyl et…
Dielectric spectroscopy of polarization phenomena and electromigration kinetics is fraught with discrepancies. The removal of these discrepancies and the generalization of the available data using the theoretical models introduced here allow the basic features of proton relaxation to be revealed. The features of proto…
Data on hydrogenation of mechanical alloys and intermetallic compounds formed in the course of mechanical alloying and mechanical milling are generalised. It is shown that mechanochemical methods make it possible to solve a number of problems arising in the hydrogenation of metals and alloys and to synthesise novel hy…
A new model is presented for the numerical calculation of pressure fields in liquids with an inhomogeneous distribution of cavitation bubbles. To calculate the pressure field in a homogeneous single-phase fluid, the Helmholtz integral and the Kirchhoff integral are solved numerically. The Helmholtz integral equation a…
The influence of the terminal segment of hydrophobically modified ethoxylated urethane (HEUR) on the linear mechanical behavior is examined through the synthesis of perfluoroalkyl telechelic HEUR (defined as F-HEUR). A series of perfluoroalkyl-modified poly(oxyethylene) (POE) of molecular weight M n = 6000, 10 000, an…
We present the results of some film simulations of polyethylene (PE) on a coarse-grained lattice, which is termed as the second nearest neighbor diamond (2nnd) lattice. Monte Carlo simulations of PE melts have been performed on the 2nnd lattice by including short- and long-range interactions. Films can be obtained fro…
Three compounds of general formula (NBu 4 )[M II Ru III (ox) 3 ] have been synthesized; NBu 4 + stands for tetra- n -butylammonium, M for Mn, Fe, and Cu, and ox 2 - for the oxalate dianion. The X-ray powder patterns for the three derivatives have revealed that these compounds are isostructural with (NBu 4 )[Mn II Cr I…
The intramolecular cyclization of α-carboxyl, ω-amino heterodifunctional polystyrene was carried out to obtain cyclic polystyrene having an amide moiety in the main chain. The amide moiety was reduced with lithium aluminum hydride to give macrocyclic amine. The reactions of the macrocyclic amine with carboxylic-termin…
Two dicarboxylic acids were prepared by alkylation of 4-hydroxycinammic acid with 1,6-dibromohexane or 1,12-dibromododecane. The dichlorides of these dicarboxylic acids were polycondensed with mixtures of isosorbide and methylhydroquinone. All copolyesters then obtained showed nematic schlieren textures. Furthermore,…
Recent results on the effect of the nanocrystalline state on the mechanical, thermal, and magnetic properties and microscopic structure of metals and solid-phase compounds are reviewed. Basic methods for preparing compact nanocrystalline materials are briefly discussed. Size effects in such materials are discussed in…
The first high-temperature endotherm ( T 1 ) of polyurethane hard segment based on 4,4‘-diphenylmethane diisocyanate (MDI) and 1,4-butanediol (BD) was studied by differential scanning calorimetry (DSC). The materials contain 69% (w/w) of MDI and BD as the hard segment and hydroxyl-terminated cis -polybutadiene with nu…
Nonisothermal melt crystallization kinetics of PEDEKmK linked by meta-phenyl and biphenyl was investigated by differential scanning calorimetry (DSC). A convenient and reasonable kinetic approach was used to describe the nonisothermal melt crystallization behavior, and its applicability was verified when the modified…
The position operator (defined within Schroedinger representation as usual) becomes meaningless when the usual Born-von Karman periodic boundary conditions are adopted: this fact is at the root of the polarization problem. I show how to define the position expectation value by means of rather peculiar many-body (multi…
A nonlinear kinetic exclusion model is used to study osmosis and pressure driven flows through nearly single file pores such as antibiotic channels, aquaporins, zeolites and nanotubules. Two possible maxima in the steady state flux as a function of pore-solvent affinity are found. For small driving forces, the linear…
Carbon nanotubes can be functionalized by oxidation of HNO 3 or H 2 SO 4 −HNO 3 . The latter shows a higher capability in producing a high density of surface functional groups. These groups can act as specific nucleation sites for a well-dispersed deposition of Pt clusters on the surface of carbon nanotubes. These mod…
We have synthesized two classes of polyureas with mono- and bisazoaromatic groups in their main chains via reactions between isophorone diisocyanate and the corresponding diamines. Holographic gratings were fabricated on azoaromatic polyurea films prepared by spin-coating from solutions. The effect of high glass trans…
Polysulfonates with reactive pendant chloromethyl groups were synthesized by polyadditions of bisepoxides with disulfonyl chlorides. The polyaddition of bisphenol A diglycidyl ether (BPGE) with m-benzene disulfonyl chloride (m-BDSC) occurred in anisole without any catalyst at 130°C for 24 h. However, polymer with high…
Diacetylene-containing polyimides have been prepared by the oxidative coupling of new diethynyl diimide monomers. Condensation of various ethynyl-terminated amines with either 4,4‘-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) or pyromellitic dianhydride (PMDA) provided the monomers. Processability was enhance…