Materials Literature
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We report on the discovery of a lead-free morphotropic phase boundary (MPB) in Sm doped BiFeO3 with a simple perovskite structure using the combinatorial thin film strategy. The boundary is a rhombohedral to pseudo-orthorhombic structural transition which exhibits a ferroelectric to antiferroelectric transition at app…
There has been significant progress in the biological synthesis of nanomaterials. However, the molecular mechanism of synthesis of such bio-nanomaterials remains largely unknown. Here, we report the extracellular synthesis of crystalline silver nanoparticles (AgNPs) by using Morganella sp., and show molecular evidence…
We present Raman spectra of epitaxial graphene layers grown on 63×63 reconstructed silicon carbide surfaces during annealing at elevated temperature. In contrast to exfoliated graphene a significant phonon hardening is observed. We ascribe that phonon hardening to a minor part to the known electron transfer from the s…
Electrical conductivity of β-Ga2O3 has been attributed so far to an oxygen deficiency, the donors presumably being oxygen vacancies. This letter shows, however, that the conductivity can be intentionally controlled over three orders of magnitude by Si doping. The related free-carrier concentration, which varies betwee…
We address the electronic structure and magnetic properties of vacancies and voids both in graphene and graphene ribbons. By using a mean-field Hubbard model, we study the appearance of magnetic textures associated with removing a single atom (vacancy) and multiple adjacent atoms (voids) as well as the magnetic intera…
Here we report a new quaternary iron-arsenide superconductor Nd[O 1− x F x ]FeAs , with the onset resistivity transition at 51.9 K and Meissner transition at 51 K. This compound has the same crystal structure as LaOFeAs, and becomes the second superconductor after Pr[O 1− x F x ]FeAs that superconducts above 50 K.
We present systematic magnetoelectronic measurements of magnetic nanopillars with different structures of polarizing magnetic layers. The magnetic reversal at small magnetic field, the onset of magnetic dynamics at larger field, and the magnetoresistance exhibit a significant dependence on the type of the polarizing l…
If a stochastic system during some periods of its evolution can be divided into non-interacting parts, the kinetics of each part can be simulated independently. We show that this can be used in the development of efficient Monte Carlo algorithms. As an illustrative example the simulation of irreversible growth of exte…
A nanoscale sensor employing fluorescent resonance energy transfer interactions between fluorescent quantum dots (QDs) and organic quencher molecules can be used for the multiplexed detection of biological antigens in solution. Detection occurs when the antigens to be detected displace quencher-labelled inactivated (o…
γ-Fe 3 O 4 doped polyimide films with different weight percentages (1, 5, and 10 wt % of Fe 3 O 4 ) have been prepared and the effect of nonmagnetic γ-Fe 3 O 4 content on the structural and magnetic properties has been studied. X-ray diffraction (XRD) studies revealed that the nanopowders obtained are magnetite. The c…
Deprotonation reactions of cyclophosphazenes containing secondary amino groups in the side chain lead to a doubly bridged tricyclophosphazene structure or to a cyclophosphazene-cyclophosphazane-cyclophosphazene compound, which are very stable and could be used as building blocks for larger structures.
Abstract Solid-state luminescence quantum efficiency is modulated drastically by CH–O interaction and packing rigidity of secondary ammonium anthracene-2,6-disulfonate. Appropriate alkyl chains of amines gave small free space and long CH–O distance, resulting in strong luminescence due to suppression of nonradiative d…
We give an exact formula for the velocity profile of shear localisation in a 2D foam, represented by a continuum model that incorporates a Herschel–Bulkley constitutive relation and wall drag. A more approximate treatment provides a relation between the localisation length and the boundary velocity as a power law whos…
In neutral phosphate buffer solution of pH 7.0, the interaction between apoCopC and Vitamin B6 has been investigated in detail by means of fluorescence spectroscopy. According to the change of Vitamin B6 fluorescence spectra and fluorescence polarization, we can conclude that a novel supramolecular system is generated…
Thermoresponsive polymer layers offer the possibility of preparing smart surfaces with properties that are switchable through a phase transition, usually close to the lower critical solution temperature of the polymer. In particular, poly( N-isopropylacrylamide) (pNIPAM) has gained a great deal of attention because it…
The temperature-dependent self-assembly and the mixing behavior of symmetrical single-chain bolaamphiphiles with different polymethylene chain lengths and different headgroup structures were investigated in water by differential scanning calorimetry (DSC), cryo transmission electron microscopy (cryo-TEM), and small an…
The adsorption of three modified dextrins on the basal plane of talc has been studied using in situ tapping mode atomic force microscopy (TMAFM). The images have been used to determine the layer thickness and coverage of the adsorbed polymers. Adsorption isotherms of the polymers on talc particles were also determined…
Platinum (Pt) nanoparticles encapsulated in microporous carbon with a hollow structure (nPt@hC) were fabricated on the basis of a titanium(IV) oxide (TiO2) photocatalytic reaction. From the tomogram of a sample studied by using a transmission electron microscope (TEM), the Pt nanoparticles were found to be embedded in…
Scanning tunneling spectroscopy in the shell-filling regime was carried out at room temperature to investigate the size dependence of the band gap and single-electron charging energy of single Si quantum dots (QDs). The results are compared with model calculation. A 12-fold multiple staircase structure was observed fo…
A study is presented of the stabilization of gold and palladium nanoparticles (NPs) via a place-exchange reaction. Au and Pd NPs of approximately 3.5 nm were prepared by a conventional method using tetraoctylammonium bromide (TOAB) as the stabilizing agent. The resulting nanoparticles, referred to as Au-TOAB or Pd-TOA…