Materials Literature
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We report on the growth of epitaxial bilayers of the La2∕3Sr1∕3MnO3 (LSMO) half-metallic ferromagnet and the BiFeO3 (BFO) multiferroic, on SrTiO3(001) by pulsed laser deposition. The growth mode of both layers is two dimensional, which results in unit-cell smooth surfaces. We show that both materials keep their proper…
Here we make use of the Hellmann-Feynman theorem, with the aim to calculate macroscopic quantum velocities instead of forces, and we show how it is possible to derive the expression of the work per unit time, per unit volume (power density) done by a static external uniform electromagnetic field interacting with a qua…
In light of the recent work by Sahni et al., Harbola, and Gaudoin and Burke, the question of mapping from an excited-state density of a many-electron interacting system to the potential of the related non-interacting system is analyzed. To do so, we investigate the Levy-Nagy criterion quantitatively for several excite…
In this paper we make use of the concept of conserved geometric phase and of group velocity,in conjunction with the representation theory\cite{Dirac,Dirac-letture}, in order to derive some relevant physical quantities for the description of the dielectric and magnetic response of crystalline materials. As an applicati…
We report spectral features of far infrared electromagnetic radiation absorption in anatase TiO2 nanopowders which we attribute to absorption by acoustic phonon modes of nanoparticles. The frequency of peak excess absorption above the background level corresponds to the predicted frequency of the dipolar acoustic phon…
We show that sputtered, pure epitaxial iron films can have high-frequency loss as low as, or lower than, any known metallic ferromagnetic heterostructure. Minimum 34 Ghz ferromagnetic resonance (FMR) linewidths of 41 Oe are demonstrated, some ~ 5-10 % lower than the previous minimum reported for molecular beam epitaxi…
An exchange energy functional is proposed and tested for obtaining a class of excited-state energies using density functional formalism. The functional is the excited-state counterpart of the local-density approximation functional for the ground state. It takes care of the state dependence of the energy functional and…
This paper deals with Hamiltonians of the form $H=-{\bf \nabla}^2+v(\rr)$, with $v(\rr)$ periodic along the $z$ direction, $v(x,y,z+b)=v(x,y,z)$. The wavefunctions of $H$ are the well known Bloch functions $ψ_{n,λ}(\rr)$, with the fundamental property $ψ_{n,λ}(x,y,z+b)=λψ_{n,λ}(x,y,z)$ and $\partial_zψ_{n,λ}(x,y,z+b)=…
The piezoelectric and ferroelectric properties of [Bi0.5(Na1−x−yKxLiy)0.5]TiO3 (BNKLT-x∕y) lead-free piezoelectric ceramics were studied. The ceramics show excellent piezoelectric and ferroelectric properties, and the optimum properties measured are as follows: piezoelectric constant d33=231pC∕N, planar and thickness…
Nanoporous carbon (NPC) exhibits unexplained chemical properties, making it distinct from other graphenelike materials, such as graphite, fullerenes, or nanotubes. In this Letter, we analyze the properties of NPC in terms of its structural motifs, which are derived from defects in distorted graphene sheets. Our densit…
The performance of photovoltaic and photochemical devices is directly linked to the efficiency with which absorbed photons are converted into electron-hole pairs (excitons). A usual assumption is that one photon produces a single exciton, while the photon energy in the excess of the material's energy gap (the gap that…
The seed-mediated approach to making gold nanorods in aqueous surfactant solutions has become tremendously popular in recent years. Unlike the use of strong chemical reductants to make spherical gold nanoparticles, the growth of gold nanorods requires weak reducing conditions, leading to an unknown degree of gold redu…
Abrasion is responsible for many surface changes that occur on garments. For this reason, the evaluation of its effects becomes very important for the textile industry. In particular, pilling formation is a phenomenon that results of the abrasion process and affects fabrics more significantly altering their surface se…
Abstract Lateral control of template synthesis in nanoporous alumina membranes (NAMs) was previously shown by us to enable preparation of graded composite materials. Formation of thickness gradients of Cu was demonstrated using electrodeposition (or electrodissolution) of Cu in the NAM template under a lateral voltage…
The development of a high-yield and low environmental impact synthesis able to deliver highly pure pergolide mesylate 1 is described. The process [seven chemical steps (four telescoped), three steps of isolation of intermediate, and only one drying] affords pergolide mesylate 1 in 75−81% overall yield from dihydrolyse…
We have studied the electronic structure of the oxygen-deficient type perovskite ${\mathrm{TbBaCo}}_{2}{\mathrm{O}}_{5.5}$, ${\mathrm{NdBaCo}}_{2}{\mathrm{O}}_{5.5}$, and ${\mathrm{NdBaCo}}_{2}{\mathrm{O}}_{5}$ using x-ray photoemission spectroscopy. The valence-band photoemission spectrum of ${\mathrm{TbBaCo}}_{2}{\m…
Abstract In this paper, deformation and breakup under simple shear of single molten polymer drops in a polymer matrix were investigated. Flow visualization was carried out in a Couette‐Flow apparatus under relatively high shear rates and temperatures up to 230°C. Drop/Matrix combinations were composed of polystyrene d…
Abstract Differential scanning calorimetry (DSC) was used to evaluate the thermal behavior and isothermal crystallization kinetics of poly(ethylene terephthalate) (PET) copolymers containing 2‐methyl‐1,3‐propanediol as a comonomer unit. The addition of comonomer reduces the melting temperature and decreases the range…
Charge-carrier transport in the columnar phase of the discotic liquid crystal, hexapentyloxytriphenylene, has been investigated by the time-of-flight technique over a range of temperatures and electric fields. The hole mobility was found to be temperature and electric-field-dependent with a maximum value of $2\ifmmode…
Abstract The iron mixed‐valence complex, ( n ‐C 3 H 7 ) 4 N[Fe II Fe III (dto) 3 ] (dto = dithiooxalato) shows a charge‐transfer (CT) phase transition at T CT = 122.4 K. In the vicinity of T CT , the spin state changes from Fe II ( S = 2) – Fe III ( S = 1/2) (high‐temperature phase: HTP) to Fe II ( S = 0) – Fe III ( S…