Materials Literature
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The vibrational states, absorption energies, and diffusions of H in Pd and ${\mathrm{Pd}}_{1\ensuremath{-}x}{\mathrm{Ag}}_{x}(0<~x<~1)$ have been studied by first-principle calculations. All results compare favorably to experiment. The zero-point motion of H is important in the determination of the H site occupa…
The vibrational and electronic properties of ${\mathrm{Ga}}_{1\ensuremath{-}x}{\mathrm{Mn}}_{x}\mathrm{As}$ layers with Mn fractions $0<~x<~2.8%,$ grown on GaAs(001) substrates by low-temperature molecular-beam epitaxy, are investigated by micro-Raman spectroscopy and far-infrared (FIR) reflectance spectroscopy.…
Surface chemistries that prevent protein adsorption and render surfaces nonadhesive have emerged as promising biomaterial modifications for minimizing host-implant inflammatory responses and providing a nonspecific background for the presentation of bioactive motifs to elicit directed cellular responses. Oligo(ethylen…
Industrial recycling is a practice of growing importance while impending 'Take Back' European legislation and economic pressures are increasing. Landfill sites are becoming exhausted and the industry could benefit from a novel approach to recycling pre and post consumer waste. Cost constraints limit the number of diff…
The paper deals with Gaussian modeling of harmonic vectors in power systems. Starting from the bivariate Gaussian distribution of the vector resolved components, the univariate magnitude and phase densities are presented both in closed form solutions, which apply when opportune hypotheses are verified, and by more gen…
In the paper, two control methods of a four-leg three-phase invertor for UPS and active filter applications are discussed. The inverter output voltage is represented as a three-dimensional space vector. Two PWM schemes are investigated: open loop sinusoidal PWM; and feedback multilevel hysteresis PWM current control.…
Photoinduced magnetic phase transition of $\mathrm{RbMnFe}(\mathrm{CN}{)}_{6}$ has been investigated by means of x-ray-absorption fine structure spectroscopy. Upon visible-light (532 nm) irradiation at 30 K, the material undergoes the photoinduced tautomeric spin transition. Mn and Fe K-edge x-ray-absorption near-edge…
A palladium-mediated assembling strategy was developed to construct organized, three-dimensional multiporphyrin arrays, wherein layers of multiporphyrin arrays can be embedded via a Py−Pd−Py coordination unit directly on solid substrates. Multilayers of the multiporphyrin arrays were characterized by use of X-ray phot…
The double-layer capacitor (DLC) for power applications is a new device. A simple resistive capacitive equivalent circuit is insufficient to characterize its terminal behaviour. Based on physical reasoning, an equivalent circuit is proposed to provide the power electronics engineer with a model for the terminal behavi…
The magnetization reversal has been examined by the temperature dependence of the coercivity, the initial magnetization curve, minor hysteresis loops, and thermal activation in isotropic nanocrystalline Pr-Fe-B ribbons. The coercivity mechanism is found to vary with temperature. At 20 K, the coercivity is mainly deter…
1 H NMR T 2 relaxation has proved to be a successful technique for the study of rubber−filler interactions in carbon black filled rubbers. For the present study, the interactions between NR and pure silica as well as silicas grafted with various coupling agents were investigated using 1 H NMR T 2 relaxation. Monodispe…
A previous study of the desorption of straight-chain alkanes [H(CH 2 ) N H, N = 5−60] from the surface of graphite has revealed that the measured desorption barriers,, have a nonlinear dependence on the chain length (Paserba, K. R.; Gellman, A. J. Phys. Rev. Lett. 2001, 86 (19), 4338). A model is proposed for the mech…
Insoluble films of trisilanolisobutyl-POSS and octaisobutyl-POSS at the air/water interface are investigated by means of surface pressure - area per molecule isotherm (Pi - A) and Brewster angle microscopy (BAM). Analysis of the experimental results shows the partial cage molecule, trisilanolisobutyl-POSS, is a surfac…
Dimeric [Mn(salpn)NCS](2)(1) and polymeric [Mn(salpn)NCS](n)(2) are formed by the reaction of Mn(CH(3)CO(2))(2).4H(2)O, the schiff base, and thiocyanate. The formation of the two polymorphic forms is solvent and temperature dependent. 1: orthorhombic, space group Pbca, with a = 12.573(2) A, b = 13.970(7) A, c = 18.891…
The nature of the D band in the Raman spectrum of graphite has been the subject of considerable discussion. We examine the relationship between the depolarization characteristics of the D, ${D}^{\ensuremath{'}},$ and G fundamentals and their corresponding overtones and combinations on the basal and damaged edge planes…
Different ferrites (CoFe 2 O 4, ZnFe 2 O 4, MnFe 2 O 4 ) and magnetite were synthesized from corresponding salts exclusively inside poly(styrenesulfonate)/poly(allylamine hydrochloride) polyelectrolyte capsules of 10 μm diameter. Polyelectrolyte capsules with synthesized ferrite (magnetite) particles possess enough ma…
A series of rich premixed flames are used to realize a post-flame gas mixture for optimum carbon nanotube (CNT) growth using inexpensive hydrocarbon fuels. The mixture of CO, CO 2, H 2, and H 2 O is varied through use of hydrocarbon fuels with different H/C ratio in flames with different fuel/air ratios. Both SEM and…
Suspended bridges of individual multiwalled carbon nanotubes were fabricated inside a scanning electron microscope by soldering the nanotube onto microelectrodes with highly conducting gold−carbon material. By the decomposition of organometallic vapor with the electron beam, metal-containing solder bonds were formed a…
We calculate the quasiparticle band structure of ZnS and ZnSe using the plane-wave pseudopotential method and the GW approximation for the self-energy. The Zn semicore $3d$ states are treated as valence states. A systematic study of the role of various approximations is presented, including the local density approxima…
We investigate the phase behavior of a single-component system in three dimensions with spherically-symmetric, pairwise-additive, soft-core interactions with an attractive well at a long distance, a repulsive soft-core shoulder at an intermediate distance, and a hard-core repulsion at a short distance, similar to pote…